Designing Low Impedance Interface Films Simultaneously on Anode and Cathode for High Energy Batteries
Abstract
High energy batteries urgently required to power electric vehicles are restricted by a number of challenges, one of which is the sluggish kinetics of cell reactions under low temperatures. A novel approach is reported to improve the low temperature performance of high energy batteries through rational construction of low impedance anode and cathode interface films. Such films are simultaneously formed on both electrodes via the reduction and oxidation of a salt, lithium difluorobis(oxalato) phosphate. The formation mechanisms of these interface films and their contributions to the improved low temperature performances of high energy batteries are demonstrated using various physical and electrochemical techniques on a graphite/LiNi 0.5 Co 0.2 Mn 0.3 O 2 battery using 1 m LiPF 6 ‐ethylene carbonate/ethyl methyl carbonate (1/2, in weight) baseline electrolyte. It is found that the interface impedances, especially the one on the anode, constitute the main obstacle to capacity delivery of high energy batteries at low temperatures, while the salt containing fluorine and oxalate substructures used as additives can effectively suppress them.
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LiDFBOP is electrochemically reduced prior to carbonate solvents.
“According to the electron affinity calculation and experimental results, LiDFBOP is electrochemically reduced prior to carbonate solvents 19a.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [143]
Capacity retention after 200 cycles at 0 °C and C/5 increased from 57% to 94% after adding LiDFBOP.
“The capacity retention after 200 cycles was increased from 57% to 94% at 0 °C and C/5 rate after adding LiDFBOP (Fig. 19c).”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [143]
Discharge capacity retention at -30 °C was 14% for baseline electrolyte and 49% for cell with 1% LiDFBOP additive.
“The discharge capacity retention at -30 °C for the baseline electrolyte was quite low at only 14%, in strong contrast with the capacity retention of 49% at -30 °C from the cell with 1% LiDFBOP additive.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [143]
LiDFBOP additive decreased interface resistance of graphite anodes at 0 °C from 1935 to 820 Ω.
“resulting in the decreased interface resistance (the sum of R sei and R ct ) of graphite anodes at 0 °C [from 1 935 to 820 Ω after adding 0.5% LiDFBOP in the baseline electrolyte (1 M LiPF 6 in PC:EMC, 1:1 in weight ratio)] (Fig. 19b).”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [143]
LiDFBOP additive improved charge/discharge performance at low temperatures by increasing ionic conductivity on both sides.
“Therefore, with the increased ionic conductivity on both sides, the charge/discharge performance at LTs was significantly improved by introducing LiDFBOP additive.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [143]
LiDFBOP reduction leads to C-O bond breakage, radical self-polymerization, and construction of SEI on graphite by polymer anion and lithium cation.
“After one-electron reduction, one of the C-O bonds is broken, the resulted radicals are then self-polymerized, and the combination of this polymer anion and lithium cation constructed the SEI on graphite.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [143]
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Self-citation
- Authors
- Liao, B., Li, H., Xu, M., Xing, L., Liao, Y., Ren, X., Fan, W., Yu, L., Xu, K., & Li, W.
- Affiliations
- South China Normal University (CN)
- Guangzhou Tinci Material Technology Co., Ltd Guangzhou 510760 China
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Xu, Kang
- Li, Weishan
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2018-05-29
- Volume
- 8
- Issue
- 22
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2806069969
- Cited by
- 292
- References
- 0
- Citations by year
- 2026: 13 · 2025: 27 · 2024: 43 · 2023: 47 · 2022: 44 · 2021: 34 · 2020: 46 · 2019: 34 · 2018: 4
- FWCI
- 11.27
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Energy Materials (publishedVersion)
- Funders
- National Natural Science Foundation of China (21573081)
- Natural Science Foundation of Guangdong Province (2017B030306013)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- low impedance, low-temperature performance, high energy density batteries, electrolyte additives, anode interface, cathode interface, interface impedance, LiPF6 electrolyte, electric vehicles
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