Effect of Fluoroethylene Carbonate Additive on Low Temperature Performance of Li-Ion Batteries
Open accessAbstract
The effects of Fluoroethylene carbonate (FEC) on the low temperature performance of Li-ion batteries were evaluated. By addition of 2 v% FEC into a commercial ternary electrolyte, the initial lithium intercalation capacity (graphite/Li model cell) was remarkably improved by approximately 50% and the voltage plateau of the cell was lowered by about 0.2 V at −20°C. This is maybe attributed to a reduced charge transfer resistance and a lowered SEI film resistance with a richer LiF phase formed on the graphite electrode by Tafel polarization, AC impedance and X-ray photoelectron spectroscopy (XPS) analysis.
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In contrast, only about 175 mAh g-1 was obtained at the same condition for a cell using the electrolyte without FEC.
“In contrast, only ~ 175 mAh g -1 was obtained at the same condition for a cell using the electrolyte without FEC (Fig. 14a) [125].”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [125]
The Results and Discussion section reports that a cell without FEC had a lower first-cycle discharge capacity at −20 °C than a cell with 2% FEC. It does not give an absolute capacity of approximately 175 mAh g⁻¹, so the cited text supports the comparison but not the claimed number. (LLM, conf=0.83)
Experimental — accuracy not yet measuredBy using conventional carbonate electrolyte with FEC as additive, a capacity of about 320 mAh g-1 was delivered when a Li/graphite cell was discharged at -20 °C at a 1/15C rate.
“By using conventional carbonate electrolyte with FEC as the additive, it was reported that a capacity of ~ 320 mAh g -1 was delivered when a Li/graphite cell was discharged at -20 °C (a 1/15C rate).”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [125]
The Experimental section (page unavailable) describes Li/graphite cells using a carbonate electrolyte with FEC and discharge at −20 °C at 1/15C. Results and Discussion (page unavailable) reports increased discharge capacity with FEC, but our copy gives no value of approximately 320 mAh g⁻¹; a search for 320 did not find it. (LLM, conf=0.86)
Experimental — accuracy not yet measuredThe benefit of using FEC decreased rapidly during cycling and became insignificant after 25 cycles at -20 °C.
“Unfortunately, the benefit of using FEC decreased rapidly during cycling and became insignificant after 25 cycles at -20”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [125]
The difference in capacity with and without FEC was attributed to decreased charge transfer and SEI impedance after forming LiF-rich SEIs with FEC.
“This difference was attributed to the decreased charge transfer and the SEI impedance after forming LiF-rich SEIs with FEC.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [125]
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- Authors
- Liu, B., Li, B., & Guan, S.
- Affiliations
- East China University of Science and Technology (CN)
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2012
- Volume
- 15
- Issue
- 6
- Pages
- A77
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2068358703
- Cited by
- 79
- References
- 0
- Citations by year
- 2026: 3 · 2025: 7 · 2024: 3 · 2023: 9 · 2022: 9 · 2021: 7 · 2020: 8 · 2019: 5 · 2018: 5 · 2017: 4 · 2016: 6 · 2015: 5 · 2014: 4 · 2013: 3 · 2012: 1
- FWCI
- 2.66
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Electrochemical and Solid-State Letters (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- fluoroethylene carbonate, electrolyte additives, low-temperature performance, lithium-ion batteries, ternary electrolyte solutions, graphite electrodes, solid electrolyte interphase, charge transfer resistance, voltage plateau
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Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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