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Hierarchical NiCo2O4 Hollow Microcuboids as Bifunctional Electrocatalysts for Overall Water‐Splitting

Gao, Xuehui, Zhang, Hongxiu, Li, Quanguo, Yu, Xuegong, Hong, Zhanglian, Zhang, Xingwang, Liang, Chengdu, Lin, Zhan·2016·Angewandte Chemie

Abstract

Bifunctional electrocatalysts for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in alkaline electrolyte may improve the efficiency of overall water splitting. Nickel cobaltite (NiCo 2 O 4) has been considered a promising electrode material for the OER. However, NiCo 2 O 4 that can be used as an electrocatalyst in HER has not been studied yet. Herein, we report self‐assembled hierarchical NiCo 2 O 4 hollow microcuboids for overall water splitting including both the HER and OER reactions. The NiCo 2 O 4 electrode shows excellent activity toward overall water splitting, with 10 mA cm−2 water‐splitting current reached by applying just 1.65 V and 20 mA cm−2 by applying just 1.74 V across the two electrodes. The synthesis of NiCo 2 O 4 microflowers confirms the importance of structural features for high‐performance overall water splitting.

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Research works printed but not linked: 29

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Metadata

Authors
Gao, X., Zhang, H., Li, Q., Yu, X., Hong, Z., Zhang, X., Liang, C., & Lin, Z.
Venue
Angewandte Chemie
Publisher
Wiley
Published
2016-04-08
Volume
128
Issue
21
Pages
6398-6402
ISSN
  • 0044-8249 (ISSN-L)
  • 1521-3757
OpenAlex
W4245900438
Cited by
631
References
8
FWCI
34.68
Type
journal article
Language
en
Open access
closed
Funders
  • Chinese government
  • Zhejiang Province Science Fund for Distinguished Young Scholars (LR16B060001)
  • Natural Science Foundation of China (21522606)
  • Fundamental Research Funds for the Central Universities

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Gao, X., Zhang, H., Li, Q., Yu, X., Hong, Z., Zhang, X., Liang, C., & Lin, Z. (2016). Hierarchical NiCo2O4 Hollow Microcuboids as Bifunctional Electrocatalysts for Overall Water‐Splitting. Angewandte Chemie. https://doi.org/10.1002/ange.201600525

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