The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation
Abstract
Nickel phosphide is an emerging low‐cost, earth‐abundant catalyst that can efficiently reduce water to generate hydrogen. However, the synthesis of nickel phosphide catalysts usually involves multiple steps and is laborious. Herein, a convenient and straightforward approach to the synthesis of a three‐dimensional (3D) self‐supported biphasic Ni 5 P 4‐Ni 2 P nanosheet (NS) array cathode is presented, which is obtained by direct phosphorization of commercially available nickel foam using phosphorus vapor. The synthesized 3D Ni 5 P 4‐Ni 2 P‐NS array cathode exhibits outstanding electrocatalytic activity and long‐term durability toward the hydrogen evolution reaction (HER) in acidic medium. The fabrication procedure reported here is scalable, showing substantial promise for use in water electrolysis. More importantly, the approach can be readily extended to synthesize other self‐supported transition metal phosphide HER cathodes.
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“The Ni5P4−Ni2P nanosheet11 supported on nickel foam (NF) exhibited good durability for 72 h at a current density of 10 mA cm−2”
From Silver Nanowire Aerogel Support Promotes Stable Hydrogen Evolution Reaction at High Current Density (2024) · cites this paper as [11]
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Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution
Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D. C. B., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., et al. (2013) · Nature Materials · doi:10.1038/nmat3700 · Cited by 2,641
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Pan, Y., Liu, Y., Zhao, J., Yang, K., Liang, J., Liu, D., Hu, W., Liu, D., Liu, Y., & Liu, C. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04867a · Cited by 652
Wang, T., Liu, L., Zhu, Z., Papakonstantinou, P., Hu, J., Liu, H., & Li, M. (2013) · Energy Environ. Sci. · doi:10.1039/c2ee23513g · Cited by 393
Self-citationKucernak, A. R. J., & Naranammalpuram Sundaram, V. N. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta03468f · Cited by 379
High-Efficiency Electrochemical Hydrogen Evolution Catalyzed by Tungsten Phosphide Submicroparticles
Xing, Z., Liu, Q., Asiri, A. M., & Sun, X. (2015) · ACS Catalysis · doi:10.1021/cs5014943 · Cited by 238
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Research works printed but not linked: 47
- 10.1021/cr1002326 · DOI · Paper page
- 10.1023/B:JACH.0000031161.26544.6a · DOI
- 10.1002/adma.201302685 · DOI · Paper page
- 10.1016/j.jpowsour.2014.04.066 · DOI
- 10.1016/j.ijhydene.2013.07.021 · DOI
- 10.1039/C3EE42441C · DOI
- 10.1039/C1SC00117E · DOI
- 10.1039/c3cc41945b · DOI · Paper page
- 10.1002/anie.201402998 · DOI
- 10.1002/ange.201402998 · DOI
- 10.1016/j.apcatb.2009.01.003 · DOI
- 10.1039/c4cp00482e · DOI
- 10.1021/nn5022204 · DOI
- 10.1039/C4NR03037K · DOI
- 10.1016/j.ijhydene.2014.09.104 · DOI
- 10.1039/C4NR04866K · DOI
- 10.1039/C4NR05862C · DOI
- 10.1039/C5CC00370A · DOI
- 10.1002/ange.201402646 · DOI
- 10.1021/cm501273s · DOI
- 10.1039/C4TA02368D · DOI
- 10.1016/j.nanoen.2014.08.013 · DOI · Paper page
- 10.1002/anie.201404161 · DOI
- 10.1002/ange.201404161 · DOI
- 10.1002/anie.201406848 · DOI · Paper page
- 10.1002/ange.201406848 · DOI
- 10.1021/nn5048553 · DOI
- 10.1016/j.nanoen.2015.01.027 · DOI
- 10.1039/c3cc43107j · DOI
- 10.1039/C4EE00957F · DOI · Paper page
- 10.1002/adma.201401692 · DOI · Paper page
- 10.1021/cm502035s · DOI
- 10.1039/C4CC04709E · DOI
- 10.1002/anie.201403842 · DOI
- 10.1002/ange.201403842 · DOI
- 10.1021/cr00083a012 · DOI
- 10.1002/1521-3773(20000717)39:14<2508::AID-ANIE2508>3.0.CO;2-O · DOI
- 10.1002/1521-3757(20000717)112:14<2561::AID-ANGE2561>3.0.CO;2-B · DOI
- 10.3891/acta.chem.scand.19-1694 · DOI
- 10.1002/anie.200462170 · DOI
- 10.1002/ange.200462170 · DOI
- 10.1006/jssc.1999.8499 · DOI
- 10.1016/j.jssc.2006.08.012 · DOI
- 10.1016/j.jssc.2008.12.007 · DOI
- 10.1039/C4TA00577E · DOI
- 10.1039/C3TA13584E · DOI · Paper page
- 10.1039/c3cc45416a · DOI · Paper page
Cited by
Sorted by citations
Shi, Y., & Zhang, B. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00434a · Cited by 3,253
Anantharaj, S., Ede, S. R., Sakthikumar, K., Karthick, K., Mishra, S., & Kundu, S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02479 · Cited by 2,503
Anantharaj, S., Ede, S. R., Karthick, K., Sam Sankar, S., Sangeetha, K., Karthik, P. E., & Kundu, S. (2018) · Energy & Environmental Science · doi:10.1039/c7ee03457a · Cited by 1,632
Self‐Supported Transition‐Metal‐Based Electrocatalysts for Hydrogen and Oxygen Evolution
Sun, H., Yan, Z., Liu, F., Xu, W., Cheng, F., & Chen, J. (2019) · Advanced Materials · doi:10.1002/adma.201806326 · Cited by 1,728
Heterostructures for Electrochemical Hydrogen Evolution Reaction: A Review
Zhao, G., Rui, K., Dou, S. X., & Sun, W. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201803291 · Cited by 1,422
Metadata
- Authors
- Wang, X., Kolen'ko, Y. V., Bao, X., Kovnir, K., & Liu, L.
- Affiliations
- International Iberian Nanotechnology Laboratory (PT)
- University of California, Davis (US)
- Corresponding author
- Liu, Lifeng
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-06
- Volume
- 54
- Issue
- 28
- Pages
- 8188-8192
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2097730964
- Cited by
- 554
- References
- 0
- Citations by year
- 2026: 6 · 2025: 13 · 2024: 29 · 2023: 17 · 2022: 52 · 2021: 41 · 2020: 55 · 2019: 76 · 2018: 82 · 2017: 93 · 2016: 77 · 2015: 12
- FWCI
- 26.05
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
- Keywords
- nickel phosphide, nanosheet arrays, self-supported catalysts, hydrogen evolution reaction, electrocatalysis, phosphorization, nickel foam, phosphorus vapor, water electrolysis, acidic media, transition metal phosphides, three-dimensional nanostructures
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