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Approaches Toward the Origin of Homochirality Using the Synthetic Organic Chemistry ^|^mdash;Asymmetric Autocatalysis with Amplification of Enantiomeric Excess^|^mdash;

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Asymmetric Autocatalysis of Pyrimidyl Alkanol

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Fortschritte bei der asymmetrischen Autokatalyse nach Soai

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Asymmetric Autocatalysis: Triggered by Chiral Isotopomer Arising from Oxygen Isotope Substitution

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Achiral Nucleobase Cytosine Acts as an Origin of Homochirality of Biomolecules in Conjunction with Asymmetric Autocatalysis

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The First Density Functional Study on the [4 + 2]-Cycloaddition Reactions of 1,2-Diaza-1,3-butadiene with Alkenes

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The Solid‐State Structures of Dimethylzinc and Diethylzinc

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Diisopropyl(N,N,N′,N′-tetramethylethylenediamine)zinc(II), the first crystal structure of a diisopropylzinc complex

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Asymmetric Autocatalysis Induced by Cinnabar: Observation of the Enantioselective Adsorption of a 5‐Pyrimidyl Alkanol on the Crystal Surface

Shindo, H., Shirota, Y., Niki, K., Kawasaki, T., Suzuki, K., Araki, Y., Matsumoto, A., & Soai, K. (2013) · Angewandte Chemie · doi:10.1002/ange.201304284 · Cited by 11 · see citing works

Inhibierung der Angiogenese in vivo durchets-1-Antisense-Oligonucleotide – Hemmung der Expression des Ets-1-Transkriptionsfaktors durch das Antibiotikum Fumagillin

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Chemisch modifizierte Antisense-Oligonucleotide: neue Fortschritte auf dem Gebiet der Bindung von RNA und der Aktivierung der Ribonuclease H

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Absolute Asymmetric Synthesis: The Origin, Control, and Amplification of Chirality

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The Macromolecular Route to Chiral Amplification

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Spontaneous Deracemizations

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The Origin of Biological Homochirality

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Possible chemical and physical scenarios towards biological homochirality

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Energy threshold for chiral symmetry breaking in molecular self-replication

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Asymmetric autocatalysis. Chiral symmetry breaking and the origins of homochirality of organic molecules

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Catalysts Supported by Homochiral Molecular Helices: A New Concept to Implement Asymmetric Amplification in Catalytic Science

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In Situ Mass Spectrometric and Kinetic Investigations of Soai's Asymmetric Autocatalysis

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Soai, K., Kawasaki, T., & Matsumoto, A. (2018) · Tetrahedron · doi:10.1016/j.tet.2018.02.040 · Cited by 47 · see citing works

Reversal of the sense of enantioselectivity between 1- and 2-aza[6]helicenes used as chiral inducers of asymmetric autocatalysis

Matsumoto, A., Yonemitsu, K., Ozaki, H., Míšek, J., Starý, I., Stará, I. G., & Soai, K. (2017) · Organic &amp; Biomolecular Chemistry · doi:10.1039/c6ob02745h · Cited by 45 · see citing works

Role of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds

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Structural Contributions to Autocatalysis and Asymmetric Amplification in the Soai Reaction

Athavale, S. V., Simon, A., Houk, K. N., & Denmark, S. E. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c05994 · Cited by 36 · see citing works

One Soai reaction, two mechanisms?

Geiger, Y. (2022) · Chemical Society Reviews · doi:10.1039/d1cs01038g · Cited by 30 · see citing works

Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid–vapor phase conditions

Kaimori, Y., Hiyoshi, Y., Kawasaki, T., Matsumoto, A., & Soai, K. (2019) · Chemical Communications · doi:10.1039/c9cc01875a · Cited by 28 · see citing works

Achiral amino acid glycine acts as an origin of homochirality in asymmetric autocatalysis

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Homochiral nanotubes from heterochiral lipid mixtures: a shorter alkyl chain dominated chiral self-assembly

Zhu, X., Jiang, Y., Yang, D., Zhang, L., Li, Y., & Liu, M. (2019) · Chemical Science · doi:10.1039/c9sc00215d · Cited by 28 · see citing works

A Quantification of the Soai Reaction

Noble‐Terán, M. E., Cruz, J., Micheau, J., & Buhse, T. (2018) · ChemCatChem · doi:10.1002/cctc.201701554 · Cited by 27 · see citing works

Unusual reversal of enantioselectivity in the asymmetric autocatalysis of pyrimidyl alkanol triggered by chiral aromatic alkanols and amines

Matusmoto, A., Fujiwara, S., Hiyoshi, Y., Zawatzky, K., Makarov, A. A., Welch, C. J., & Soai, K. (2017) · Organic &amp; Biomolecular Chemistry · doi:10.1039/c6ob02415g · Cited by 27 · see citing works

Elucidation of the Structures of Asymmetric Autocatalyst Based on X-ray Crystallography

Matsumoto, A., Fujiwara, S., Abe, T., Hara, A., Tobita, T., Sasagawa, T., Kawasaki, T., & Soai, K. (2016) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20160160 · Cited by 24 · see citing works

Origin of Chirality in the Molecules of Life

Cowan, J. A., & Furnstahl, R. J. (2022) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.2c00032 · Cited by 24 · see citing works

Chiral Inactivation: An Old Phenomenon with a New Twist

Raskatov, J. A. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201703869 · Cited by 23 · see citing works

Natural Abundance Isotopic Chirality in the Reagents of the Soai Reaction

Barabás, B., Kurdi, R., & Pályi, G. (2016) · Symmetry · doi:10.3390/sym8010002 · Cited by 18 · see citing works

Asymmetric Autocatalysis as a Link Between Crystal Chirality and Highly Enantioenriched Organic Compounds

Soai, K., Matsumoto, A., & Kawasaki, T. (2021) · Israel Journal of Chemistry · doi:10.1002/ijch.202100047 · Cited by 16 · see citing works

Absolute Structure Determination of Chiral Crystals Consisting of Achiral Benzophenone with Single-crystal X-ray Diffraction and Its Correlation with Solid-state Circular Dichroism

Matsumoto, A., Tsuchiya, S., Hagiwara, Y., Ishikawa, K., Koshima, H., Asahi, T., & Soai, K. (2016) · Chemistry Letters · doi:10.1246/cl.160114 · Cited by 16 · see citing works

Determination of the absolute structure of the chiral crystal consisting of achiral dibutylhydroxytoluene and asymmetric autocatalysis triggered by this chiral crystal

Matsumoto, A., Takeda, S., Harada, S., & Soai, K. (2016) · Tetrahedron Asymmetry · doi:10.1016/j.tetasy.2016.07.013 · Cited by 14 · see citing works

Role of Association in Chiral Catalysis: From Asymmetric Synthesis to Spin Selectivity

Ageeva, A. A., Khramtsova, E. A., Magin, I. M., Purtov, P. A., Miranda, M. A., & Leshina, T. V. (2018) · Chemistry - A European Journal · doi:10.1002/chem.201801625 · Cited by 13 · see citing works

Autoamplification‐Enhanced Oxidative Kinetic Resolution of sec‐Alcohols and Alkyl Mandelates, and its Kinetic Model

Talsi, E. P., & Bryliakov, K. P. (2018) · ChemCatChem · doi:10.1002/cctc.201800180 · Cited by 13 · see citing works

Can the analyte-triggered asymmetric autocatalytic Soai reaction serve as a universal analytical tool for measuring enantiopurity and assigning absolute configuration?

Welch, C. J., Zawatzky, K., Makarov, A. A., Fujiwara, S., Matsumoto, A., & Soai, K. (2016) · Organic & Biomolecular Chemistry · doi:10.1039/c6ob01939k · Cited by 11 · see citing works

Isotope chirality in long‐armed multifunctional organosilicon (“<scp>Cephalopod</scp>”) molecules

Barabás, B., Kurdi, R., Zucchi, C., & Pályi, G. (2018) · Chirality · doi:10.1002/chir.22865 · Cited by 10 · see citing works

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Kaur, J., & Barham, J. P. (2025) · Chemistry - A European Journal · doi:10.1002/chem.202502075 · Cited by 11 · see citing works

Circular dichroism spectroscopy of catalyst preequilibrium in asymmetric autocatalysis of pyrimidyl alkanol

Matsumoto, A., Tanaka, A., Kaimori, Y., Hara, N., Mikata, Y., & Soai, K. (2021) · Chemical Communications · doi:10.1039/d1cc04206h · Cited by 10 · see citing works

Point‐to‐Point Ultra‐Remote Asymmetric Control with Flexible Linker

Kawasaki, T., Ishikawa, Y., Minato, Y., Otsuka, T., Yonekubo, S., Sato, I., Shibata, T., Matsumoto, A., & Soai, K. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201605076 · Cited by 10 · see citing works

Asymmetric Autocatalysis as an Efficient Link Between the Origin of Homochirality and Highly Enantioenriched Compounds

Soai, K., Kawasaki, T., & Matsumoto, A. (2022) · Origins of Life and Evolution of Biospheres · doi:10.1007/s11084-022-09626-7 · Cited by 9 · see citing works

Asymmetric Autocatalysis and the Origins of Homochirality of Organic Compounds. An Overview

Soai, K., Matsumoto, A., & Kawasaki, T. (2017) · Elsevier eBooks · doi:10.1016/b978-0-12-812824-4.00001-0 · Cited by 8 · see citing works

Mechanism Change of (+)-Nonlinear Effect in a Phase Separation System in a CuII-Catalyzed Asymmetric Friedel-Crafts Reaction Using a C2-Chiral Dioxolane-Containing-Bisamidine Ligand, Naph-diPIM-dioxo-iPr

Le, T. P., Tanaka, S., Yoshimura, M., & Kitamura, M. (2020) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20200172 · Cited by 8 · see citing works

Mechanistic analysis and kinetic profiling of Soai’s asymmetric autocatalysis for pyridyl and pyrimidyl substrates

Möhler, P., Betzenbichler, G., Huber, L., Siegle, A. F., & Trapp, O. (2025) · Nature Communications · doi:10.1038/s41467-025-62591-3 · Cited by 10 · see citing works

Kinetic relationship in parallel autocatalytic amplifications of pyridyl alkanol and chiral trigger pyrimidyl alkanol

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A green and efficient method for one-step synthesis of novel oxazolo[3,2-c]pyrimidine derivatives in lactic acid

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Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis

Matsumoto, A., Kaimori, Y., Uchida, M., Omori, H., Kawasaki, T., & Soai, K. (2016) · Angewandte Chemie · doi:10.1002/ange.201610099 · Cited by 8 · see citing works

Asymmetric Autocatalysis and the Origin of Homochirality

Soai, K., & Matsumoto, A. (2017) · ACS symposium series · doi:10.1021/bk-2017-1258.ch003 · Cited by 6 · see citing works

Asymmetric Induction by a Nitrogen 14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis

Matsumoto, A., Ozaki, H., Harada, S., Tada, K., Ayugase, T., Ozawa, H., Kawasaki, T., & Soai, K. (2016) · Angewandte Chemie · doi:10.1002/ange.201608955 · Cited by 6 · see citing works

Symmetry Breaking and Autocatalytic Amplification in Soai Reaction Confined within UiO‐MOFs under Heterogenous Conditions.

Rotunno, G., Kaur, G., Lazzarini, A., Buono, C., & Amedjkouh, M. (2021) · Chemistry - An Asian Journal · doi:10.1002/asia.202100419 · Cited by 6 · see citing works

Asymmetric Autocatalysis Initiated by Crystal Chirality of Achiral Compounds

Matsumoto, A., Kaimori, Y., Kawasaki, T., & Soai, K. (2017) · Elsevier eBooks · doi:10.1016/b978-0-12-812824-4.00018-6 · Cited by 6 · see citing works

Autocatalytic Models for the Origin of Biological HomochiralityPreprint

Blackmond, D. G. (2019) · ChemRxiv · doi:10.26434/chemrxiv.9916235 · Cited by 6 · see citing works

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Mutually antagonistic molecular clips: symmetry-breaking non-covalent bonds at the chiral–nonchiral interface

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Synthesis of Pyrimidine-Terminated Chiral Large Molecular Architectures with Functions of Self-Replication and Self-Improvement by Asymmetric Autocatalysis

Kawasaki, T., Matsumoto, A., Sato, I., & Soai, K. (2017) · Elsevier eBooks · doi:10.1016/b978-0-12-812824-4.00008-3 · Cited by 5 · see citing works

Efficient Circular Polarizer Using a Two-Layer Nanoparticle Dimer Array with Designed Chirality

Zhou, Y., Zhao, Y., Reed, J. M., Gomez, P., & Zou, S. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b02113 · Cited by 5 · see citing works

Non-chiral Polymer-induced Chirality Enhancement in Lipidic Nanotube-based Hydrogel System

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Asymmetric Autocatalysis: The Soai Reaction, an Overview

Soai, K., Kawasaki, T., & Matsumoto, A. (2022) · Royal Society of Chemistry eBooks · doi:10.1039/9781839166273-00001 · Cited by 4 · see citing works

Achiral 2‐pyridone and 4‐aminopyridine act as chiral inducers of asymmetric autocatalysis with amplification of enantiomeric excess via the formation of chiral crystals

Matsumoto, A., Tateishi, D., Nakajima, T., Kurosaki, S., Ogawa, T., Kawasaki, T., & Soai, K. (2023) · Chirality · doi:10.1002/chir.23617 · Cited by 4 · see citing works

Ethylzinc‐ and Zinc–bis–fluoroalkoxides

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Kinetic and Structural Aspects of Mirror-Image Symmetry Breaking in the Soai Reaction

Buhse, T., Noble‐Terán, M. E., Cruz, J., Micheau, J. C., & Coudret, C. (2017) · Elsevier eBooks · doi:10.1016/b978-0-12-812824-4.00004-6 · Cited by 4 · see citing works

Enhanced photo-responsiveness in a photoswitchable system model: emergent hormetic catalysis

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Isotope Chirality in the Reagents and Intermediates of the Soai Reaction * *Some parts of this paper were presented at a Symposium [1] and published in an article [2].

Barabás, B., Kurdi, R., & Pályi, G. (2017) · Elsevier eBooks · doi:10.1016/b978-0-12-812824-4.00014-9 · Cited by 2 · see citing works

Asymmetric autocatalysis with amplification of enantiomeric excess utilizing chiral crystals of achiral o-terphenyls as chiral triggers

Kawasaki, T., Tateishi, D., Matsumoto, A., & Soai, K. (2024) · Tetrahedron · doi:10.1016/j.tet.2024.133835 · Cited by 2 · see citing works

Structural Study of Asymmetric Autocatalysis by X-Ray Crystallography

Matsumoto, A., Kawasaki, T., & Soai, K. (2017) · Elsevier eBooks · doi:10.1016/b978-0-12-812824-4.00010-1 · Cited by 2 · see citing works

Reaction Mechanism in the Study of Amplifying Asymmetric Autocatalysis

Brown, J. M. (2022) · Royal Society of Chemistry eBooks · doi:10.1039/9781839166273-00097 · Cited by 1 · see citing works

Unusual Aspects of Asymmetric Induction and Amplification Observed in the Soai Reaction

Kawasaki, T., Matsumoto, A., & Soai, K. (2022) · Royal Society of Chemistry eBooks · doi:10.1039/9781839166273-00317 · Cited by 1 · see citing works

Asymmetric autoamplification in the Soai reaction

Mikhaylov, O. A., & Gridnev, I. D. (2026) · Russian Chemical Reviews · doi:10.59761/rcr5219 · Cited by 1 · see citing works

Model Equivalency in Interpreting the Stochastic Enantiomer Distribution in the Soai Reaction

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Synthesis and stereodynamics of intramolecular hemiacetals in biaryl aldehyde‐alcohols

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Prospective synthesis of pyridine and pyrimidine derived trifluoromethyl ketones

Vassilakis, M. S. (2020) · NORA - Norwegian Open Research Archives

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