The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Enhanced Electrochemical Kinetics on Conductive Polar Mediators for Lithium–Sulfur Batteries
Abstract
Lithium–sulfur (Li–S) batteries have been recognized as promising substitutes for current energy‐storage technologies owing to their exceptional advantage in energy density. The main challenge in developing highly efficient and long‐life Li–S batteries is simultaneously suppressing the shuttle effect and improving the redox kinetics. Polar host materials have desirable chemisorptive properties to localize the mobile polysulfide intermediates; however, the role of their electrical conductivity in the redox kinetics of subsequent electrochemical reactions is not fully understood. Conductive polar titanium carbides (TiC) are shown to increase the intrinsic activity towards liquid–liquid polysulfide interconversion and liquid–solid precipitation of lithium sulfides more than non‐polar carbon and semiconducting titanium dioxides. The enhanced electrochemical kinetics on a polar conductor guided the design of novel hybrid host materials of TiC nanoparticles grown within a porous graphene framework (TiC@G). With a high sulfur loading of 3.5 mg cm−2, the TiC@G/sulfur composite cathode exhibited a substantially enhanced electrochemical performance.
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Cites
Li-O2 and Li-S batteries with high energy storage
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Lithium–Sulfur Batteries: Electrochemistry, Materials, and Prospects
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A highly efficient polysulfide mediator for lithium–sulfur batteries
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Lithium–Sulfur Batteries: Progress and Prospects
Manthiram, A., Chung, S., & Zu, C. (2015) · Advanced Materials · doi:10.1002/adma.201405115 · Cited by 1,620
Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions
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Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells
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Powering Lithium–Sulfur Battery Performance by Propelling Polysulfide Redox at Sulfiphilic Hosts
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Self-citationTao, X., Wang, J., Liu, C., Wang, H., Yao, H., Zheng, G., Seh, Z. W., Cai, Q., Li, W., Zhou, G., et al. (2016) · Nature Communications · doi:10.1038/ncomms11203 · Cited by 1,391
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Cited by
Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries
Peng, H., Huang, J., Cheng, X., & Zhang, Q. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700260 · Cited by 1,746
Self-citationNanostructured Metal Oxides and Sulfides for Lithium–Sulfur Batteries
Liu, X., Huang, J., Zhang, Q., & Mai, L. (2017) · Advanced Materials · doi:10.1002/adma.201601759 · Cited by 1,616
Self-citationAdvances in Lithium–Sulfur Batteries: From Academic Research to Commercial Viability
Chen, Y., Wang, T., Tian, H., Su, D., Zhang, Q., & Wang, G. (2021) · Advanced Materials · doi:10.1002/adma.202003666 · Cited by 870
Self-citationBao, W., Liu, L., Wang, C., Choi, S., Wang, D., & Wang, G. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702485 · Cited by 745
Porous Carbons: Structure‐Oriented Design and Versatile Applications
Tian, W., Zhang, H., Duan, X., Sun, H., Shao, G., & Wang, S. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201909265 · Cited by 657
Metadata
- Authors
- Peng, H., Zhang, G., Chen, X., Zhang, Z., Xu, W., Huang, J., & Zhang, Q.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-10-06
- Volume
- 55
- Issue
- 42
- Pages
- 12990-12995
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2517573024
- Cited by
- 649
- References
- 43
- FWCI
- 33.84
- Type
- journal article
- Language
- en
- Open access
- closed
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