Anodic Hydrazine Oxidation Assists Energy‐Efficient Hydrogen Evolution over a Bifunctional Cobalt Perselenide Nanosheet Electrode

Zhang, Jun‐Ye; Wang, Hongming; Tian, Yifan; Yan, Ya; Xue, Qi; He, Ting; Liu, Hongfang; Wang, Chundong; Chen, Yu; Xia, Bao Yu

doi:10.1002/anie.201803543

Cited by 439

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Anodic Hydrazine Oxidation Assists Energy‐Efficient Hydrogen Evolution over a Bifunctional Cobalt Perselenide Nanosheet Electrode

Zhang, Jun‐Ye, Wang, Hongming, Tian, Yifan, Yan, Ya, Xue, Qi, He, Ting, Liu, Hongfang, Wang, Chundong, Chen, Yu, Xia, Bao Yu·2018·Angewandte Chemie International Edition

DOI 10.1002/anie.201803543

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Abstract

Water electrolysis is a promising source of hydrogen; however, technological challenges remain. Intensive efforts have focused on developing highly efficient and earth‐abundant electrocatalysts for water splitting. An effective strategy is proposed, using a bifunctional tubular cobalt perselenide nanosheet electrode, in which the sluggish oxygen evolution reaction is substituted with anodic hydrazine oxidation so as to assist energy‐efficient hydrogen production. Specifically, this electrode produces a current density of 10 mA cm−2 at −84 mV for hydrogen evolution and −17 mV for hydrazine oxidation in 1.0 m KOH and 0.5 m hydrazine electrolyte. An ultralow cell voltage of only 164 mV is required to generate a current density of 10 mA cm−2 for 14 hours of stable water electrolysis.

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Authors: Zhang, J., Wang, H., Tian, Y., Yan, Y., Xue, Q., He, T., Liu, H., Wang, C., Chen, Y., & Xia, B. Y.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2018-05-23
Volume: 57
Issue: 26
Pages: 7649-7653
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201803543
OpenAlex: W2800498045
Cited by: 439
References: 9
FWCI: 12.44
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Funders: National Natural Science Foundation of China (51702213)

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This page: CoChat. (2026). Citation check: Anodic Hydrazine Oxidation Assists Energy‐Efficient Hydrogen Evolution over a Bifunctional Cobalt Perselenide Nanosheet Electrode. https://app.cochat.ai/papers/10.1002/anie.201803543
The paper: Zhang, J., Wang, H., Tian, Y., Yan, Y., Xue, Q., He, T., Liu, H., Wang, C., Chen, Y., & Xia, B. Y. (2018). Anodic Hydrazine Oxidation Assists Energy‐Efficient Hydrogen Evolution over a Bifunctional Cobalt Perselenide Nanosheet Electrode. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201803543

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Anodic Hydrazine Oxidation Assists Energy‐Efficient Hydrogen Evolution over a Bifunctional Cobalt Perselenide Nanosheet Electrode

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