The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.
Engineering the Coordination Environment of Single‐Atom Platinum Anchored on Graphdiyne for Optimizing Electrocatalytic Hydrogen Evolution
Abstract
Abstract Two Pt single‐atom catalysts (SACs) of Pt‐GDY1 and Pt‐GDY2 were prepared on graphdiyne (GDY)supports. The isolated Pt atoms are dispersed on GDY through the coordination interactions between Pt atoms and alkynyl C atoms in GDY, with the formation of five‐coordinated C 1 ‐Pt‐Cl 4 species in Pt‐GDY1 and four‐coordinated C 2 ‐Pt‐Cl 2 species in Pt‐GDY2. Pt‐GDY2 shows exceptionally high catalytic activity for the hydrogen evolution reaction (HER), with a mass activity up to 3.3 and 26.9 times more active than Pt‐GDY1 and the state‐of‐the‐art commercial Pt/C catalysts, respectively. Pt‐GDY2 possesses higher total unoccupied density of states of Pt 5d orbital and close to zero value of Gibbs free energy of the hydrogen adsorption (|Δ |) at the Pt active sites, which are responsible for its excellent catalytic performance. This work can help better understand the structure–catalytic activity relationship in Pt SACs.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“Despite these challenges, several studies have successfully developed highly stable electrocatalysts with Pt loadings of less than 5 wt%.[27–32]”
Citations
Cites
Trends in the exchange current for hydrogen evolution
Nørskov, J. K., Bligaard, T., Logadottir, A., Kitchin, J. R., Chen, J. G., Pandelov, S., & Stimming, U. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1856988 · Cited by 6,121
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Architecture of graphdiyne nanoscale films
Li, G., Li, Y., Liu, H., Guo, Y., Li, Y., & Zhu, D. (2010) · Chemical Communications · doi:10.1039/b922733d · Cited by 2,836
Xie, J., Zhang, J., Li, S., Grote, F., Zhang, X., Zhang, H., Wang, R., Lei, Y., Pan, B., & Xie, Y. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408329q · Cited by 2,350
Hydrogen evolution by a metal-free electrocatalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Du, A., Jaroniec, M., & Qiao, S. Z. (2014) · Nature Communications · doi:10.1038/ncomms4783 · Cited by 2,236
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
Cheng, N., Stambula, S., Wang, D., Banis, M. N., Liu, J., Riese, A., Xiao, B., Li, R., Sham, T.-K., Liu, L.-M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13638 · Cited by 2,072
Chen, Y., Ji, S., Wang, Y., Dong, J., Chen, W., Li, Z., Shen, R., Zheng, L., Zhuang, Z., Wang, D. S., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702473 · Cited by 1,992
Fei, H., Dong, J., Feng, Y., Allen, C. S., Wan, C., Volosskiy, B., Li, M., Zhao, Z., Wang, Y., Sun, H., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0008-y · Cited by 1,973
Single‐Atom Pt as Co‐Catalyst for Enhanced Photocatalytic H 2 Evolution
Li, X., Bi, W., Zhang, L., Tao, S., Chu, W., Zhang, Q., Luo, Y., Wu, C., & Xie, Y. (2016) · Advanced Materials · doi:10.1002/adma.201505281 · Cited by 1,429
Flagged first, then by citations
Cited by
Sorted by citations
Liu, D., Li, X., Chen, S., Yan, H., Wang, C., Wu, C., Haleem, Y. A., Duan, S., Lu, J., Ge, B., et al. (2019) · Nature Energy · doi:10.1038/s41560-019-0402-6 · Cited by 1,166
Li, Y., Sun, Y., Qin, Y., Zhang, W., Wang, L., Luo, M., Yang, H., & Guo, S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903120 · Cited by 1,065
Advanced Electrocatalysts with Single-Metal-Atom Active Sites
Wang, Y., Su, H., He, Y., Li, L., Zhu, S., Shen, H. F., Xie, P., Fu, X., Zhou, G., Feng, C., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00594 · Cited by 1,009
Progress in Research into 2D Graphdiyne-Based Materials
Huang, C., Li, Y., Wang, N., Xue, Y., Zuo, Z., Li, Y., & Li, Y. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00288 · Cited by 979
Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation
Zhao, D., Zhuang, Z., Cao, X., Zhang, C., Peng, Q., Chen, C., & Li, Y. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00869a · Cited by 858
Metadata
- Authors
- Yin, X., Wang, H., Tang, S., Lu, X., Shu, M., Si, R., & Lu, T.
- Affiliations
- Institute for New Energy Materials & Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology Tianjin 300384 China
- Chinese Academy of Sciences (CN)
- Tianjin University of Technology (CN)
- Corresponding author
- Si, Rui
- Lu, Tong‐Bu
- ORCID
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-06-28
- Volume
- 57
- Issue
- 30
- Pages
- 9382-9386
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2805542846
- Cited by
- 594
- References
- 49
- Citations by year
- 2026: 36 · 2025: 48 · 2024: 65 · 2023: 78 · 2022: 91 · 2021: 114 · 2020: 103 · 2019: 47 · 2018: 12
- FWCI
- 15.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21790052 , 21331007 and 21773288)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- single-atom catalysts, platinum, graphdiyne, hydrogen evolution reaction, electrocatalysis, coordination environment, structure-activity relationship, hydrogen adsorption Gibbs free energy, mass activity
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
