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Engineering the Coordination Environment of Single‐Atom Platinum Anchored on Graphdiyne for Optimizing Electrocatalytic Hydrogen Evolution
Abstract
Abstract Two Pt single‐atom catalysts (SACs) of Pt‐GDY1 and Pt‐GDY2 were prepared on graphdiyne (GDY)supports. The isolated Pt atoms are dispersed on GDY through the coordination interactions between Pt atoms and alkynyl C atoms in GDY, with the formation of five‐coordinated C 1 ‐Pt‐Cl 4 species in Pt‐GDY1 and four‐coordinated C 2 ‐Pt‐Cl 2 species in Pt‐GDY2. Pt‐GDY2 shows exceptionally high catalytic activity for the hydrogen evolution reaction (HER), with a mass activity up to 3.3 and 26.9 times more active than Pt‐GDY1 and the state‐of‐the‐art commercial Pt/C catalysts, respectively. Pt‐GDY2 possesses higher total unoccupied density of states of Pt 5d orbital and close to zero value of Gibbs free energy of the hydrogen adsorption (|Δ |) at the Pt active sites, which are responsible for its excellent catalytic performance. This work can help better understand the structure–catalytic activity relationship in Pt SACs.
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“Despite these challenges, several studies have successfully developed highly stable electrocatalysts with Pt loadings of less than 5 wt%.[27–32]”
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Cites
Trends in the exchange current for hydrogen evolution
Nørskov, J. K., Bligaard, T., Logadottir, A., Kitchin, J. R., Chen, J. G., Pandelov, S., & Stimming, U. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1856988 · Cited by 6,121
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Architecture of graphdiyne nanoscale films
Li, G., Li, Y., Liu, H., Guo, Y., Li, Y., & Zhu, D. (2010) · Chemical Communications · doi:10.1039/b922733d · Cited by 2,836
Xie, J., Zhang, J., Li, S., Grote, F., Zhang, X., Zhang, H., Wang, R., Lei, Y., Pan, B., & Xie, Y. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408329q · Cited by 2,350
Hydrogen evolution by a metal-free electrocatalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Du, A., Jaroniec, M., & Qiao, S. Z. (2014) · Nature Communications · doi:10.1038/ncomms4783 · Cited by 2,236
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
Cheng, N., Stambula, S., Wang, D., Banis, M. N., Liu, J., Riese, A., Xiao, B., Li, R., Sham, T.-K., Liu, L.-M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13638 · Cited by 2,072
Chen, Y., Ji, S., Wang, Y., Dong, J., Chen, W., Li, Z., Shen, R., Zheng, L., Zhuang, Z., Wang, D. S., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702473 · Cited by 1,992
Fei, H., Dong, J., Feng, Y., Allen, C. S., Wan, C., Volosskiy, B., Li, M., Zhao, Z., Wang, Y., Sun, H., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0008-y · Cited by 1,973
Single‐Atom Pt as Co‐Catalyst for Enhanced Photocatalytic H 2 Evolution
Li, X., Bi, W., Zhang, L., Tao, S., Chu, W., Zhang, Q., Luo, Y., Wu, C., & Xie, Y. (2016) · Advanced Materials · doi:10.1002/adma.201505281 · Cited by 1,429
Deng, J., Li, H., Xiao, J., Tu, Y., Deng, D., Yang, H., Tian, H., Li, J., Ren, P., & Bao, X. (2015) · Energy & Environmental Science · doi:10.1039/c5ee00751h · Cited by 1,343
Wang, X., Zhao, C., Zhao, X., Yao, T., Chen, W., You, R., Zhao, C., Wu, G., Wang, J., Huang, W., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201712451 · Cited by 1,123
High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Jaroniec, M., & Qiao, S.-Z. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11291 · Cited by 1,110
Wei, H., Liu, X., Wang, A., Zhang, L., Qiao, B., Yang, X., Huang, Y., Miao, S., Liu, J., & Zhang, T. (2014) · Nature Communications · doi:10.1038/ncomms6634 · Cited by 1,102
Zheng, Y., Jiao, Y., Li, L. H., Xing, T., Chen, Y. I., Jaroniec, M., & Qiao, S. (2014) · ACS Nano · doi:10.1021/nn501434a · Cited by 1,068
Jia, Y. A., Zhang, L., Gao, G., Chen, H., Wang, B., Zhou, J., Soo, M. T., Hong, M., Yan, X., Qian, G., et al. (2017) · Advanced Materials · doi:10.1002/adma.201700017 · Cited by 1,025
Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution
Xue, Y., Huang, B., Yi, Y., Guo, Y., Zuo, Z., Li, Y., Jia, Z., Liu, H., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03896-4 · Cited by 1,011
Liu, W., Zhang, L., Liu, X., Liu, X., Yang, X., Miao, S., Wang, W., Wang, A., & Zhang, T. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05130 · Cited by 982
Yin, H., Zhao, S., Zhao, K., Muqsit, A., Tang, H., Chang, L., Zhao, H., Gao, Y., & Tang, Z. (2015) · Nature Communications · doi:10.1038/ncomms7430 · Cited by 974
Single-atom Catalysis Using Pt/Graphene Achieved through Atomic Layer Deposition
Sun, S., Zhang, G., Gauquelin, N., Chen, N., Zhou, J., Yang, S., Chen, W., Meng, X., Geng, D., Banis, M. N., et al. (2013) · Scientific Reports · doi:10.1038/srep01775 · Cited by 915
Yang, S., Kim, J., Tak, Y. J., Soon, A., & Lee, H. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509241 · Cited by 899
Huang, X., Zeng, Z., Bao, S., Wang, M., Qi, X., Fan, Z., & Zhang, H. (2013) · Nature Communications · doi:10.1038/ncomms2472 · Cited by 849
High performance platinum single atom electrocatalyst for oxygen reduction reaction
Liu, J., Jiao, M., Lu, L., Barkholtz, H. M., Li, Y., Wang, Y., Jiang, L., Wu, Z., Liu, D.-J., Zhuang, L., et al. (2017) · Nature Communications · doi:10.1038/ncomms15938 · Cited by 772
Qiu, H. ‐., Ito, Y., Cong, W., Tan, Y., Liu, P., Hirata, A., Fujita, T., Tang, Z., & Chen, M. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201507381 · Cited by 756
Fan, L., Liu, P. F., Yan, X., Gu, L., Yang, Z. Z., Yang, H. G., Qiu, S., & Yao, X. (2016) · Nature Communications · doi:10.1038/ncomms10667 · Cited by 748
Wang, X., Chen, W., Zhang, L., Yao, T., Liu, W., Lin, Y., Ju, H., Dong, J., Zheng, L., Yan, W., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01686 · Cited by 699
Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction
Zhou, J., Gao, X., Liu, R., Xie, Z., Yang, J., Zhang, S., Zhang, G., Liu, H., Li, Y., Zhang, J., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04057 · Cited by 600
Crystalline Graphdiyne Nanosheets Produced at a Gas/Liquid or Liquid/Liquid Interface
Matsuoka, R., Sakamoto, R. L., Hoshiko, K., Sasaki, S., Masunaga, H., Nagashio, K., & Nishihara, H. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12776 · Cited by 560
Low‐Cost Hydrogen‐Evolution Catalysts Based on Monolayer Platinum on Tungsten Monocarbide Substrates
Esposito, D. V., Hunt, S. T., Stottlemyer, A. L., Dobson, K. D., McCandless, B. E., Birkmire, R. W., & Chen, J. G. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004718 · Cited by 554
Zhang, L., Han, L., Liu, H., Liu, X., & Luo, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201706921 · Cited by 532
Mallouk, T. E. (2013) · Nature Chemistry · doi:10.1038/nchem.1634 · Cited by 383
Li, J., Gao, X., Liu, B., Feng, Q., Li, X., Huang, M., Liu, Z., Zhang, J., Tung, C., & Wu, L. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12758 · Cited by 375
Chen, Y., Ji, S., Wang, Y., Dong, J., Chen, W., Li, Z., Shen, R., Zheng, L., Zhuang, Z., Wang, D. S., et al. (2017) · Angewandte Chemie · doi:10.1002/ange.201702473 · Cited by 357
Tavakkoli, M., Holmberg, N., Kronberg, R., Jiang, H., Sainio, J., Kauppinen, E. I., Kallio, T. M., & Laasonen, K. E. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00199 · Cited by 338
Wang, X., Chen, Z., Zhao, X., Yao, T., Chen, W., You, R., Zhao, C., Wu, G., Wang, J., Huang, W., et al. (2017) · Angewandte Chemie · doi:10.1002/ange.201712451 · Cited by 311
Advances in Energy and Environmental Materials
(2018) · Springer proceedings in energy · doi:10.1007/978-981-13-0158-2 · Cited by 306
Gao, X., Li, J., Du, R., Zhou, J., Huang, M., Liu, R., Li, J., Xie, Z., Wu, L., Liu, Z., et al. (2016) · Advanced Materials · doi:10.1002/adma.201605308 · Cited by 252
Ren, H., Shao, H., Zhang, L., Guo, D., Jin, Q. L., Yu, R., Wang, L., Li, Y., Wang, Y., Zhao, H., et al. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500296 · Cited by 209
Wang, S., Gao, X., Hang, X., Zhu, X., Han, H., Liao, W., & Chen, W. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11218 · Cited by 203
Direct imaging and determination of the crystal structure of six-layered graphdiyne
Li, C., Lu, X., Han, Y., Tang, S., Ding, Y., Liu, R., Bao, H., Li, Y., Luo, J., & Lu, T. (2017) · Nano Research · doi:10.1007/s12274-017-1789-7 · Cited by 125
Self-citationYang, S., Kim, J., Tak, Y. J., Soon, A., & Lee, H. (2015) · Angewandte Chemie · doi:10.1002/ange.201509241 · Cited by 103
Lu, Z., Li, S., Lv, P. F., He, C., Ma, D., & Yang, Z. (2015) · Applied Surface Science · doi:10.1016/j.apsusc.2015.10.219 · Cited by 100
Qiu, H. ‐., Ito, Y., Cong, W., Tan, Y., Liu, P., Hirata, A., Fujita, T., Tang, Z., & Chen, M. (2015) · Angewandte Chemie · doi:10.1002/ange.201507381 · Cited by 87
Low‐Cost Hydrogen‐Evolution Catalysts Based on Monolayer Platinum on Tungsten Monocarbide Substrates
Esposito, D. V., Hunt, S. T., Stottlemyer, A. L., Dobson, K. D., McCandless, B. E., Birkmire, R. W., & Chen, J. G. (2010) · Angewandte Chemie · doi:10.1002/ange.201004718 · Cited by 78
Zhang, L., Han, L., Liu, H., Liu, X., & Luo, J. (2017) · Angewandte Chemie · doi:10.1002/ange.201706921 · Cited by 75
Redox-Active On-Surface Assembly of Metal–Organic Chains with Single-Site Pt(II)
Skomski, D., Tempas, C. D., Smith, K. A., & Tait, S. L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja504850f · Cited by 70
Qiu, Z., Huang, H., Du, J., Tao, X., Xia, Y., Feng, T., Gan, Y., & Zhang, W. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta00277f · Cited by 60
Chemical Modification and Functionalization of Graphdiyne
Li, Y., & Li, Y. (2018) · Acta Physico-Chimica Sinica · doi:10.3866/pku.whxb201801302 · Cited by 44
Lu, X., Yingying, H. A. N., & Lu, T. (2018) · Acta Physico-Chimica Sinica · doi:10.3866/pku.whxb201801171 · Cited by 23
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
Liu, D., Li, X., Chen, S., Yan, H., Wang, C., Wu, C., Haleem, Y. A., Duan, S., Lu, J., Ge, B., et al. (2019) · Nature Energy · doi:10.1038/s41560-019-0402-6 · Cited by 1,166
Li, Y., Sun, Y., Qin, Y., Zhang, W., Wang, L., Luo, M., Yang, H., & Guo, S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903120 · Cited by 1,065
Advanced Electrocatalysts with Single-Metal-Atom Active Sites
Wang, Y., Su, H., He, Y., Li, L., Zhu, S., Shen, H. F., Xie, P., Fu, X., Zhou, G., Feng, C., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00594 · Cited by 1,009
Progress in Research into 2D Graphdiyne-Based Materials
Huang, C., Li, Y., Wang, N., Xue, Y., Zuo, Z., Li, Y., & Li, Y. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00288 · Cited by 979
Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation
Zhao, D., Zhuang, Z., Cao, X., Zhang, C., Peng, Q., Chen, C., & Li, Y. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00869a · Cited by 858
Metadata
- Authors
- Yin, X., Wang, H., Tang, S., Lu, X., Shu, M., Si, R., & Lu, T.
- Affiliations
- Institute for New Energy Materials & Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology Tianjin 300384 China
- Chinese Academy of Sciences (CN)
- Tianjin University of Technology (CN)
- Corresponding author
- Si, Rui
- Lu, Tong‐Bu
- ORCID
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-06-28
- Volume
- 57
- Issue
- 30
- Pages
- 9382-9386
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2805542846
- Cited by
- 594
- References
- 49
- Citations by year
- 2026: 36 · 2025: 48 · 2024: 65 · 2023: 78 · 2022: 91 · 2021: 114 · 2020: 103 · 2019: 47 · 2018: 12
- FWCI
- 15.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21790052 , 21331007 and 21773288)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- single-atom catalysts, platinum, graphdiyne, hydrogen evolution reaction, electrocatalysis, coordination environment, structure-activity relationship, hydrogen adsorption Gibbs free energy, mass activity
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