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Engineering the Coordination Environment of Single‐Atom Platinum Anchored on Graphdiyne for Optimizing Electrocatalytic Hydrogen Evolution
Abstract
Abstract Two Pt single‐atom catalysts (SACs) of Pt‐GDY1 and Pt‐GDY2 were prepared on graphdiyne (GDY)supports. The isolated Pt atoms are dispersed on GDY through the coordination interactions between Pt atoms and alkynyl C atoms in GDY, with the formation of five‐coordinated C 1 ‐Pt‐Cl 4 species in Pt‐GDY1 and four‐coordinated C 2 ‐Pt‐Cl 2 species in Pt‐GDY2. Pt‐GDY2 shows exceptionally high catalytic activity for the hydrogen evolution reaction (HER), with a mass activity up to 3.3 and 26.9 times more active than Pt‐GDY1 and the state‐of‐the‐art commercial Pt/C catalysts, respectively. Pt‐GDY2 possesses higher total unoccupied density of states of Pt 5d orbital and close to zero value of Gibbs free energy of the hydrogen adsorption (|Δ |) at the Pt active sites, which are responsible for its excellent catalytic performance. This work can help better understand the structure–catalytic activity relationship in Pt SACs.
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“Despite these challenges, several studies have successfully developed highly stable electrocatalysts with Pt loadings of less than 5 wt%.[27–32]”
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Metadata
- Authors
- Yin, X., Wang, H., Tang, S., Lu, X., Shu, M., Si, R., & Lu, T.
- Affiliations
- Institute for New Energy Materials & Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology Tianjin 300384 China
- Chinese Academy of Sciences (CN)
- Tianjin University of Technology (CN)
- Corresponding author
- Si, Rui
- Lu, Tong‐Bu
- ORCID
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-06-28
- Volume
- 57
- Issue
- 30
- Pages
- 9382-9386
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2805542846
- Cited by
- 594
- References
- 49
- Citations by year
- 2026: 36 · 2025: 48 · 2024: 65 · 2023: 78 · 2022: 91 · 2021: 114 · 2020: 103 · 2019: 47 · 2018: 12
- FWCI
- 15.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21790052 , 21331007 and 21773288)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- single-atom catalysts, platinum, graphdiyne, hydrogen evolution reaction, electrocatalysis, coordination environment, structure-activity relationship, hydrogen adsorption Gibbs free energy, mass activity
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