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Cited by 391

The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.

Tailoring the Grain Boundary Chemistry of Polymeric Carbon Nitride for Enhanced Solar Hydrogen Production and CO2 Reduction

Open access
Zhang, Guigang, Li, Guosheng, Heil, Tobias, Zafeiratos, Spiros, Lai, Feili, Savateev, Aleksandr, Antonietti, Markus, Wang, Xinchen·2019·Angewandte Chemie International Edition

Abstract

Photocatalytic water splitting is a promising and clean way to mimic plant photosynthesis in a sustainable manner. Improvements of the quantum efficiency and optical absorption in the relevant range are necessary steps to approach practicality. Herein, we reported that these issues can be readily addressed when 5‐aminotetrazole, a monomer with high nitrogen content, is used for the synthesis of carbon nitride. The molten salt mixture NaCl/KCl is used as a high‐temperature solvent to tailor the grain boundary structure and chemistry. Visible light quantum efficiency for H 2 production of 0.65 could be obtained in the presence of K 2 HPO 4 as a double layer modifier. This value is very high, considering that this number depends on light to charge couple conversion, charge localization, as well as a successful oxidation and reduction reaction.

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Crossref · 10.1002/anie.201811938

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Metadata

Authors
Zhang, G., Li, G., Heil, T., Zafeiratos, S., Lai, F., Savateev, A., Antonietti, M., & Wang, X.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-02-12
Volume
58
Issue
11
Pages
3433-3437
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2910820311
Cited by
391
References
37
FWCI
12.68
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Tailoring the Grain Boundary Chemistry of Polymeric Carbon Nitride for Enhanced Solar Hydrogen Production and CO2 Reduction. https://app.cochat.ai/papers/10.1002/anie.201811938
The paper
Zhang, G., Li, G., Heil, T., Zafeiratos, S., Lai, F., Savateev, A., Antonietti, M., & Wang, X. (2019). Tailoring the Grain Boundary Chemistry of Polymeric Carbon Nitride for Enhanced Solar Hydrogen Production and CO2 Reduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201811938

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.