The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Tailoring the Grain Boundary Chemistry of Polymeric Carbon Nitride for Enhanced Solar Hydrogen Production and CO2 Reduction
Open accessAbstract
Photocatalytic water splitting is a promising and clean way to mimic plant photosynthesis in a sustainable manner. Improvements of the quantum efficiency and optical absorption in the relevant range are necessary steps to approach practicality. Herein, we reported that these issues can be readily addressed when 5‐aminotetrazole, a monomer with high nitrogen content, is used for the synthesis of carbon nitride. The molten salt mixture NaCl/KCl is used as a high‐temperature solvent to tailor the grain boundary structure and chemistry. Visible light quantum efficiency for H 2 production of 0.65 could be obtained in the presence of K 2 HPO 4 as a double layer modifier. This value is very high, considering that this number depends on light to charge couple conversion, charge localization, as well as a successful oxidation and reduction reaction.
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Cites
A metal-free polymeric photocatalyst for hydrogen production from water under visible light
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Self-citationWalter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting
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Ionothermal Synthesis of Crystalline, Condensed, Graphitic Carbon Nitride
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Self-citationGao, G., Jiao, Y., Waclawik, E. R., & Du, A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b02692 · Cited by 1,196
Bridging the g-C3N4 Interlayers for Enhanced Photocatalysis
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Iodine Modified Carbon Nitride Semiconductors as Visible Light Photocatalysts for Hydrogen Evolution
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Cited by
Li, A., Cao, Q., Zhou, G., Schmidt, B. V. K. J., Zhu, W., Yuan, X., Huo, H., Gong, J., & Antonietti, M. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908058 · Cited by 403
Self-citationFu, J., Liu, K., Jiang, K., Li, H., An, P., Li, W., Zhang, N., Li, H., Xu, X., Zhou, H., et al. (2019) · Advanced Science · doi:10.1002/advs.201900796 · Cited by 355
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Metadata
- Authors
- Zhang, G., Li, G., Heil, T., Zafeiratos, S., Lai, F., Savateev, A., Antonietti, M., & Wang, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-02-12
- Volume
- 58
- Issue
- 11
- Pages
- 3433-3437
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2910820311
- Cited by
- 391
- References
- 37
- FWCI
- 12.68
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhang, G., Li, G., Heil, T., Zafeiratos, S., Lai, F., Savateev, A., Antonietti, M., & Wang, X. (2019). Tailoring the Grain Boundary Chemistry of Polymeric Carbon Nitride for Enhanced Solar Hydrogen Production and CO2 Reduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201811938
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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