A simulation method to analyze chemo-mechanical behavior of swelling-induced shape-memory polymer in response to solvent
Abstract
Abstract A network of thermally responsive shape‐memory polymers (SMPs) could imbibe a quantity of solvent molecules to swell, and subsequently induces a chemical potential change in polymer. When an equilibrium is reached between the mechanical load and the chemical potential of polymer network and solvent, the SMP polymer usually swells with a field of inhomogeneous and anisotropic deformation, which is considered to be equivalent to a hyperelastic field. We implement this theory in the free‐energy function equation, and analyze examples of swelling‐induced deformation and shape recovery behavior. This work may provide a powerful tool to study complex swelling‐induced shape‐memory behavior of SMPs in response to the immersing solvents. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
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Chemo-responsive SMPs (pH-, redox-, moisture- and solvent-induced) are one of the barely studied systems in the literature.
“Chemo-responsive SMPs, pH-, redox- and moisture- and solvent-induced, are one of the barely studied systems in the literature [57-59].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [57]
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- Authors
- Lu, H.
- Affiliations
- Harbin Institute of Technology (CN)
- Corresponding author
- Lu, Haibao
- ORCID
- Lu, Haibao
- Venue
- Journal of Applied Polymer Science
- Publisher
- Wiley
- Published
- 2011-08-09
- Volume
- 123
- Issue
- 2
- Pages
- 1137-1146
- ISSN
- 0021-8995 (ISSN-L)
- 1097-4628
- OpenAlex
- W2017185988
- Cited by
- 43
- References
- 23
- Citations by year
- 2026: 2 · 2025: 2 · 2022: 1 · 2021: 2 · 2020: 1 · 2019: 1 · 2018: 1 · 2017: 4 · 2016: 8 · 2015: 3 · 2014: 9 · 2013: 8 · 2012: 1
- FWCI
- 10.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Applied Polymer Science (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Medicine › Hydrogels: synthesis, properties, applications
- Keywords
- shape memory polymers, swelling, thermoresponsive polymers, chemical potential, free energy function, shape recovery
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