Electromagnetic activation of shape memory polymer networks containing magnetic nanoparticles
Abstract
Abstract Summary: By incorporation of surface‐modified superparamagnetic nanoparticles into shape memory polymer matrices, remote actuation of complex shape transitions by electromagnetic fields is possible. The composite thermosets of oligo( ε ‐caprolactone)dimethacrylate/butyl acrylate contain between 2 and 12 wt.‐% magnetite nanoparticles serving as nanoantennas for magnetic heating. It is shown that the particles are dispersed homogenously within the matrix and that the basic thermal and mechanical properties of the polymer matrix are maintained. The specific loss power of the particles is determined to be 30 W · g −1 at 300 kHz and 5.0 W. During the shape transition at 43 °C, no further temperature increase is observed. magnified image
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Schmidt et al. incorporated oligo(e-caprolactone)-grafted Fe3O4 superparamagnetic NPs into thermosets of oligo(e-caprolactone)dimethacrylate/butyl acrylate.
“For instance, Schmidt et al. incorporated oligo( e -caprolactone)-grafted Fe3O4 superparamagnetic NPs into thermosets of oligo( e -caprolactone)dimethacrylate/butyl acrylate [165].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [165]
Homogenous dispersion and enhanced compatibility of the nanofiller within the polymer matrix could be achieved by grafting oligomers on the NPs surface.
“Homogenous dispersion and enhanced compatibility of the nanofiller within the polymer matrix could be also achieved by grafting oligomers on the NPs surface.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [165]
The biocompatible material recovered its original straight shape in 20 s when magnetic field with frequency of 300 kHz and power of 5.0 kW are applied.
“It was shown that the biocompatible material recovered its original straight shape in 20 s when magnetic field with frequency of 300 kHz and power of 5.0 kW are applied.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [165]
Cites
Wayman, C. M., & 大塚, 和. (1998) · Cambridge University Press eBooks · Cited by 3,134 · see citing works
Lendlein, A., Kelch, S., Kratz, K., Schulte, J., & Schauer, S. (2002) · Wiley eBooks · doi:10.1002/0471238961.1908011612051404.a01 · Cited by 2,616 · see citing works
Biodegradable, Elastic Shape-Memory Polymers for Potential Biomedical Applications
Lendlein, A., & Langer, R. (2002) · Science · doi:10.1126/science.1066102 · Cited by 2,146 · see citing works
Static and dynamic magnetic properties of spherical magnetite nanoparticles
Goya, G. F., Berquó, T. S., Fonseca, F. C. C., & Morales, M. P. (2003) · Journal of Applied Physics · doi:10.1063/1.1599959 · Cited by 1,393 · see citing works
Superparamagnetic iron oxide: pharmacokinetics and toxicity
Weissleder, R., Stark, D., Engelstad, B. L., Bacon, B., Compton, C. C., White, D., Jacobs, P. M., & Lewis, J. M. (1989) · American Journal of Roentgenology · doi:10.2214/ajr.152.1.167 · Cited by 1,045 · see citing works
Scientific and Clinical Applications of Magnetic Carriers
Häfeli, U. O., Schütt, W., Teller, J., & Zborowski, M. (1997) · Springer eBooks · doi:10.1007/978-1-4757-6482-6 · Cited by 1,037 · see citing works
Koerner, H., Price, G., Pearce, N. A., Alexander, M., & Vaia, R. A. (2004) · Nature Materials · doi:10.1038/nmat1059 · Cited by 1,034 · see citing works
Fast liquid-crystal elastomer swims into the dark
Camacho-Lopez, M. A., Finkelmann, H., Palffy‐Muhoray, P., & Shelley, M. (2004) · Nature Materials · doi:10.1038/nmat1118 · Cited by 1,009 · see citing works
Mohr, R., Kratz, K., Weigel, T., Lucka-Gabor, M., Moneke, M., & Lendlein, A. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0600079103 · Cited by 819 · see citing works
Behl, M., & Lendlein, A. (2011) · Wiley eBooks · doi:10.1002/0471238961.1908011612051404.a01.pub2 · Cited by 664 · see citing works
Physical limits of hyperthermia using magnetite fine particles
Hergt, R., Andrä, W., D'ambly, C. G., Hilger, I., Kaiser, W. A., Richter, U., & Schmidt, H.-G. (1998) · IEEE Transactions on Magnetics · doi:10.1109/20.718537 · Cited by 659 · see citing works
Electroactive shape-memory polyurethane composites incorporating carbon nanotubes
Cho, J. W., Kim, J. W., Jung, Y. C., & Goo, N. S. (2005) · Macromolecular Rapid Communications · doi:10.1002/marc.200400492 · Cited by 603 · see citing works
Magnetic Fluids and Applications Handbook
Berkovsky, B. M., & Bashtovoy, V. (1996) · doi:10.1615/978-1-56700-062-7.0 · Cited by 539 · see citing works
Giant lateral electrostriction in ferroelectric liquid-crystalline elastomers
Lehmann, W., Skupin, H., Tolksdorf, C., Gebhard, E., Zentel, R., Krüger, P., Lösche, M., & Kremer, F. (2001) · Nature · doi:10.1038/35068522 · Cited by 465 · see citing works
Shape memory polymer nanocomposites
Gall, K. (2002) · Acta Materialia · doi:10.1016/s1359-6454(02)00368-3 · Cited by 429 · see citing works
Photomechanical actuation in polymer–nanotube composites
Ahir, S. V., & Terentjev, E. M. (2005) · Nature Materials · doi:10.1038/nmat1391 · Cited by 423 · see citing works
Magnetic field sensitive functional elastomers with tuneable elastic modulus
Varga, Z., Filipcsei, G., & Zrínyi, M. (2006) · Polymer · doi:10.1016/j.polymer.2005.10.139 · Cited by 410 · see citing works
AB-polymer networks based on oligo(ɛ-caprolactone) segments showing shape-memory properties
Lendlein, A., Schmidt, A. M., & Langer, R. (2001) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.98.3.842 · Cited by 303 · see citing works
Self-citationIntelligent polymer gels controlled by magnetic fields
Zrı́nyi, M. (2000) · Colloid & Polymer Science · doi:10.1007/s003960050017 · Cited by 289 · see citing works
Single Wall Carbon Nanotube−Nafion Composite Actuators
Landi, B. J., Raffaelle, R. P., Heben, M. J., et al. (2002) · Nano Letters · doi:10.1021/nl025800h · Cited by 279 · see citing works
Self‐Assembled Shape‐Memory Fibers of Triblock Liquid‐Crystal Polymers
Ahir, S. V., Tajbakhsh, A. R., & Terentjev, E. M. (2006) · Advanced Functional Materials · doi:10.1002/adfm.200500692 · Cited by 271 · see citing works
Relaxational Behavior of Fine Magnetic Particles
Brown, W. F. (1959) · Journal of Applied Physics · doi:10.1063/1.2185851 · Cited by 267 · see citing works
Massart, R., & Cabuil, V. (1987) · Journal de Chimie Physique · doi:10.1051/jcp/1987840967 · Cited by 241 · see citing works
Shape Transition of Magnetic Field Sensitive Polymer Gels
Szabó, D., Szeghy, G., & Zrı́nyi, M. (1998) · Macromolecules · doi:10.1021/ma980284w · Cited by 224 · see citing works
Hilger, I., Andrä, W., Hergt, R., et al. (2001) · Radiology · doi:10.1148/radiology.218.2.r01fe19570 · Cited by 224 · see citing works
Shape‐memory polymer networks from oligo(ϵ‐caprolactone)dimethacrylates
Lendlein, A., Schmidt, A. M., Schroeter, M., & Langer, R. (2005) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.20598 · Cited by 220 · see citing works
Self-citationElectroactive Polymers as Artificial Muscles: A Review
Bar‐Cohen, Y. (2002) · Journal of Spacecraft and Rockets · doi:10.2514/2.3902 · Cited by 195 · see citing works
Nematic elastomers with aligned carbon nanotubes: New electromechanical actuators
Courty, S., Miné-Hattab, J., Tajbakhsh, A. R., & Terentjev, E. M. (2003) · Europhysics Letters (EPL) · doi:10.1209/epl/i2003-00277-9 · Cited by 192 · see citing works
Shape memory polyurethane containing amorphous reversible phase
Jeong, H. M., Lee, S., & Kim, B. K. (2000) · Journal of Materials Science · doi:10.1023/a:1004761206709 · Cited by 132 · see citing works
Schmidt, A. M. (2005) · Macromolecular Rapid Communications · doi:10.1002/marc.200400426 · Cited by 79 · see citing works
Self-citationRickert, D., Lendlein, A., Schmidt, A. M., Kelch, S., Roehlke, W., Fuhrmann, R., & Franke, R. P. (2003) · Journal of Biomedical Materials Research Part B: Applied Biomaterials · doi:10.1002/jbm.b.10069 · Cited by 66 · see citing works
Self-citationMagnetic Fluid Hyperthermia (MFH)
Jordan, A., Wust, P., Scholz, R., et al. (1997) · Springer eBooks · doi:10.1007/978-1-4757-6482-6_43 · Cited by 55 · see citing works
Induction heating of novel thermoresponsive ferrofluids
Schmidt, A. M. (2004) · Journal of Magnetism and Magnetic Materials · doi:10.1016/j.jmmm.2004.11.003 · Cited by 49 · see citing works
Self-citationRagazzo, J. L., Ozaki, M. E., Karlsson, L., et al. (2000) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.98.1.241 · Cited by 45 · see citing works
Guerra, C. F., & Bickelhaupt, F. M. (2002) · Angewandte Chemie · doi:10.1002/1521-3757(20020617)114:12 · Cited by 21 · see citing works
Reactivity of Sm(II) compounds as ring-opening polymerization initiators for lactones
Agarwal, S., Brandukova-Szmikowski, N. E., & Greiner, A. (1999) · Macromolecular Rapid Communications · doi:10.1002/(sici)1521-3927(19990501)20:5 · Cited by 18 · see citing works
Persistent current for interacting electrons: a simple Hartree-Fock picturePreprint
Montambaux, G. (1995) · Cited by 16 · see citing works
Persistent Current of Interacting Electrons: a Simple Hartree-Fock Picture
Montambaux, G. (1996) · Journal de Physique I · doi:10.1051/jp1:1996128 · Cited by 14 · see citing works
Szilágyi, A., Fetter, G., & Zrı́nyi, M. (2005) · Journal of Thermal Analysis and Calorimetry · doi:10.1007/s10973-005-0927-8 · Cited by 11 · see citing works
Léger, J. (2002) · HAL (Le Centre pour la Communication Scientifique Directe) · doi:10.3917/lcdm1.011.0037 · Cited by 3 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Review of progress in shape-memory polymers
Liu, C., Qin, H., & Mather, P. T. (2007) · Journal of Materials Chemistry · doi:10.1039/b615954k · Cited by 1,942 · see citing works
Shape-memory polymers and their composites: stimulus methods and applications
Leng, J., Lan, X., Liu, Y., & Du, S. (2011) · Progress in Materials Science · doi:10.1016/j.pmatsci.2011.03.001 · Cited by 1,495 · see citing works
A review of stimuli-responsive shape memory polymer composites
Meng, H., & Li, G. (2013) · Polymer · doi:10.1016/j.polymer.2013.02.023 · Cited by 1,190 · see citing works
Recent advances in shape memory polymers and composites: a review
Ratna, D., & Karger-Kocsis, J. (2008) · Journal of Materials Science · doi:10.1007/s10853-007-2176-7 · Cited by 942 · see citing works
Mather, P. T., Luo, X., & Rousseau, I. A. (2009) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-082908-145419 · Cited by 911 · see citing works
Review of electro-active shape-memory polymer composite
Liu, Y., Lv, H., Lan, X., Leng, J., & Du, S. (2009) · Composites Science and Technology · doi:10.1016/j.compscitech.2008.08.016 · Cited by 548 · see citing works
Fiber reinforced shape-memory polymer composite and its application in a deployable hinge
Lan, X., Liu, Y., Lv, H., Wang, X., Leng, J., & Du, S. (2009) · Smart Materials and Structures · doi:10.1088/0964-1726/18/2/024002 · Cited by 496 · see citing works
Multi-shape active composites by 3D printing of digital shape memory polymers
Wu, J., Yuan, C., Ding, Z., Isakov, M., Mao, Y., Wang, T., Dunn, M. L., & Qi, H. J. (2016) · Scientific Reports · doi:10.1038/srep24224 · Cited by 399 · see citing works
Shape-memory polymers for multiple applications in the materials world
Pilate, F., Toncheva, A., Dubois, P., & Raquez, J.-M. (2016) · European Polymer Journal · doi:10.1016/j.eurpolymj.2016.05.004 · Cited by 332 · see citing works
Bioinspired mechanically adaptive polymer nanocomposites with water-activated shape-memory effect
Mendez, J., Annamalai, P. K., Eichhorn, S. J., Rusli, R., Rowan, S. J., Foster, E. J., & Weder, C. (2011) · Macromolecules · doi:10.1021/ma201502k · Cited by 319 · see citing works
Various shape memory effects of stimuli-responsive shape memory polymers
Meng, H., Mohamadian, H., Stubblefield, M., Jerro, D., Ibekwe, S., Pang, S.-S., & Li, G. (2013) · Smart Materials and Structures · doi:10.1088/0964-1726/22/9/093001 · Cited by 257 · see citing works
Multiple and two-way reversible shape memory polymers: Design strategies and applications
Wang, K., Jia, Y.-G., Zhao, C., & Zhu, X. X. (2019) · Progress in Materials Science · doi:10.1016/j.pmatsci.2019.100572 · Cited by 208 · see citing works
Rapidly switchable water-sensitive shape-memory cellulose/elastomer nano-composites
Zhu, Y., Hu, J., Luo, H., Young, R. J., Deng, L., Zhang, S., Fan, Y., & Ye, G. (2012) · Soft Matter · doi:10.1039/c2sm07035a · Cited by 208 · see citing works
Recent developments in shape memory polymer nanocomposites: Actuation methods and mechanisms
Wang, W., Liu, Y., & Leng, J. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2016.03.007 · Cited by 182 · see citing works
Research Progress of Shape Memory Polymer and 4D Printing in Biomedical Application
Zhao, W., Yue, C., Liu, L., Liu, Y., & Leng, J. (2023) · Advanced Healthcare Materials · doi:10.1002/adhm.202201975 · Cited by 183 · see citing works
Xiao, Y., Zhou, S., Wang, L., & Gong, T. (2010) · ACS Applied Materials & Interfaces · doi:10.1021/am100692n · Cited by 153 · see citing works
Stretchable supramolecular hydrogels with triple shape memory effect
Le, X., Lu, W., Zheng, J., Tong, D., Zhao, N., Ma, C., Xiao, H., Zhang, J., Huang, Y., & Chen, T. (2016) · Chemical Science · doi:10.1039/c6sc02354a · Cited by 152 · see citing works
Synthesis and characterization of PCL–PLLA polyurethane with shape memory behavior
Peponi, L., Navarro-Baena, I., Sonseca, A., Gimenez, E., Marcos-Fernandez, A., & Kenny, J. M. (2013) · European Polymer Journal · doi:10.1016/j.eurpolymj.2012.11.001 · Cited by 149 · see citing works
Shape‐memory polymer networks with Fe<sub>3</sub>O<sub>4</sub> nanoparticles for remote activation
Yakacki, C. M., Satarkar, N. S., Gall, K., Likos, R., & Hilt, J. Z. (2009) · Journal of Applied Polymer Science · doi:10.1002/app.29845 · Cited by 144 · see citing works
Review on the Functional Determinants and Durability of Shape Memory Polymers
Pretsch, T. (2010) · Polymers · doi:10.3390/polym2030120 · Cited by 138 · see citing works
Leng, J., Lv, H., Liu, Y., & Du, S. (2008) · Journal of Applied Physics · doi:10.1063/1.3026724 · Cited by 135 · see citing works
Photogenerating work from polymers
Koerner, H., White, T. J., Tabiryan, N. V., Bunning, T. J., & Vaia, R. A. (2008) · Materials Today · doi:10.1016/s1369-7021(08)70147-0 · Cited by 130 · see citing works
Polyolefin thermoplastics for multiple shape and reversible shape memory
Gao, Y., Liu, W., & Zhu, S. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b14728 · Cited by 99 · see citing works
Lu, H., Liu, Y., Leng, J., & Du, S. (2009) · Smart Materials and Structures · doi:10.1088/0964-1726/18/8/085003 · Cited by 98 · see citing works
Study on the activation of styrene-based shape memory polymer by medium-infrared laser light
Leng, J., Zhang, D., Liu, Y., Yu, K., & Lan, X. (2010) · Applied Physics Letters · doi:10.1063/1.3353970 · Cited by 86 · see citing works
Lu, H., & Min Huang, W. (2013) · Applied Physics Letters · doi:10.1063/1.4811134 · Cited by 86 · see citing works
4D printing of polyurethane paint-based composites
Su, J.-W., Gao, W., Trinh, K., Kenderes, S. M., Tekin Pulatsu, E., Zhang, C., Whittington, A., Lin, M., & Lin, J. (2019) · International Journal of Smart and Nano Materials · doi:10.1080/19475411.2019.1618409 · Cited by 81 · see citing works
Digital manufacture of shape changing components
Yu, K., Dunn, M. L., & Qi, H. J. (2015) · Extreme Mechanics Letters · doi:10.1016/j.eml.2015.07.005 · Cited by 76 · see citing works
Reversible Bidirectional Shape Memory Effect in Polyurethanes through Molecular Flipping
Biswas, A., Aswal, V. K., Sastry, P. U., Rana, D., & Maiti, P. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b00536 · Cited by 78 · see citing works
Fei, G., Li, G., Wu, L., & Xia, H. (2012) · Soft Matter · doi:10.1039/c2sm07357a · Cited by 65 · see citing works
Cuevas, J. M., Alonso, J., German, L., Iturrondobeitia, M., Laza, J. M., Vilas, J. L., & León, L. M. (2009) · Smart Materials and Structures · doi:10.1088/0964-1726/18/7/075003 · Cited by 58 · see citing works
Remote activation of nanomagnetite reinforced shape memory polymer foam
Vialle, G., Di Prima, M., Hocking, E., Gall, K., Garmestani, H., Sanderson, T., & Arzberger, S. C. (2009) · Smart Materials and Structures · doi:10.1088/0964-1726/18/11/115014 · Cited by 59 · see citing works
‘Two way’ shape memory composites based on electroactive polymer and thermoplastic membrane
Yao, Y., Zhou, T., Wang, J., Li, Z., Lu, H., Liu, Y., & Leng, J. (2016) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2016.08.019 · Cited by 53 · see citing works
Kim, M. S., Jun, J. K., & Jeong, H. M. (2008) · Composites Science and Technology · doi:10.1016/j.compscitech.2007.12.015 · Cited by 51 · see citing works
Lu, H., & Gou, J. (2012) · Polymers for Advanced Technologies · doi:10.1002/pat.2074 · Cited by 45 · see citing works
Lu, H. (2012) · Journal of Applied Polymer Science · doi:10.1002/app.34597 · Cited by 43 · see citing works
Shape-memory polymer networks from sol–gel cross-linked alkoxysilane-terminated poly(ε-caprolactone)
Paderni, K., Pandini, S., Passera, S., Pilati, F., Toselli, M., & Messori, M. (2012) · Journal of Materials Science · doi:10.1007/s10853-012-6289-2 · Cited by 44 · see citing works
Gopinath, S., Adarsh, N. N., Nair, P. R., & Mathew, S. (2021) · ACS Omega · doi:10.1021/acsomega.0c05839 · Cited by 39 · see citing works
Hyperbranched polyurethane/Fe3O4 thermosetting nanocomposites as shape memory materials
Kalita, H., & Karak, N. (2013) · Polymer Bulletin · doi:10.1007/s00289-013-0999-8 · Cited by 31 · see citing works
Xia, S., Li, X., Wang, Y., Pan, Y., Zheng, Z., Ding, X., & Peng, Y. (2014) · Smart Materials and Structures · doi:10.1088/0964-1726/23/8/085005 · Cited by 25 · see citing works
- Authors
- Schmidt, A. M.
- Affiliations
- Heinrich Heine University Düsseldorf (DE)
- Corresponding author
- Schmidt, Annette M.
- ORCID
- Schmidt, Annette M.
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2006-07-20
- Volume
- 27
- Issue
- 14
- Pages
- 1168-1172
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W1988418731
- Cited by
- 518
- References
- 40
- Citations by year
- 2026: 8 · 2025: 22 · 2024: 24 · 2023: 25 · 2022: 24 · 2021: 32 · 2020: 38 · 2019: 36 · 2018: 19 · 2017: 30 · 2016: 38 · 2015: 26 · 2014: 31 · 2013: 46 · 2012: 23
- FWCI
- 32.57
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Rapid Communications (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Biomedical Engineering › Dielectric materials and actuators
- Keywords
- shape memory polymers, magnetic nanoparticles, superparamagnetic nanoparticles, magnetite, electromagnetic actuation, magnetic heating, nanoantennas, thermoset composites, butyl acrylate, specific loss power, remote actuation, shape transition
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