Qualitative separation of the effect of the solubility parameter on the recovery behavior of shape-memory polymer
Open accessAbstract
For the thermal response of shape-memory polymer (SMP) it has been experimentally demonstrated that the actuation can be achieved using interactive solvent. In this paper, the effect of the solubility parameter of the interactive solvent on the shape recovery behavior and glass transition temperature of polystyrene SMP was investigated experimentally. The effect of the solubility parameter on the activation energy was separated and qualitatively identified, as expected from the relaxation theory and Eyring equation. This approach should be applicable to other SMPs and their composites and many extension applications and achievements could be based on this outcome.
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For styrene-based SM thermosetting resin, faster Tg decreases (shorter recovery times) occurred for solvents with higher solubility parameters.
“A clear tendency towards faster T g decreases, tantamount to shorter recovery times, for solvents with higher solubility parameters was found.”
From Review on the Functional Determinants and Durability of Shape Memory Polymers (2010) · cites this paper as [221]
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- Authors
- Lu, H., Liu, Y., Leng, J., & Du, S.
- Affiliations
- Harbin Institute of Technology (CN)
- Corresponding author
- Leng, Jinsong
- Venue
- Smart Materials and Structures
- Publisher
- IOP Publishing
- Published
- 2009-06-03
- Volume
- 18
- Issue
- 8
- Pages
- 085003
- ISSN
- 0964-1726 (ISSN-L)
- 1361-665X
- OpenAlex
- W2147359040
- Cited by
- 98
- References
- 18
- Citations by year
- 2025: 5 · 2024: 1 · 2023: 3 · 2022: 7 · 2021: 4 · 2020: 5 · 2019: 6 · 2018: 3 · 2017: 9 · 2016: 6 · 2015: 5 · 2014: 3 · 2013: 9 · 2012: 5
- FWCI
- 21.38
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Smart Materials and Structures (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Materials Chemistry › Shape Memory Alloy Transformations
- Keywords
- shape memory polymers, solubility parameter, shape recovery, polystyrene, glass transition temperature, activation energy, Eyring equation, relaxation theory, thermal actuation
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