Extraction and determination of heavy metals in soil and vegetables irrigated with treated municipal wastewater using new mode of dispersive liquid-liquid microextraction based on the solidified deep eutectic solvent followed by GFAAS

Habibollahi, Mohammad Hossein; Karimyan, Kamaleddin; Arfaeinia, Hossein; Mirzaei, Nezam; Safari, Yahya; Akramipour, Reza; Sharafi, Hooshmand; Fattahi, Nazir

doi:10.1002/jsfa.9230

Cited by 133Analytical chemistry methods developmentHeavy metals in environmentEnvironmental and Analytical Chemistry Studies

Extraction and determination of heavy metals in soil and vegetables irrigated with treated municipal wastewater using new mode of dispersive liquid-liquid microextraction based on the solidified deep eutectic solvent followed by GFAAS

Habibollahi, Mohammad Hossein, Karimyan, Kamaleddin, Arfaeinia, Hossein, Mirzaei, Nezam, Safari, Yahya, Akramipour, Reza, Sharafi, Hooshmand, Fattahi, Nazir·2019·Journal of the Science of Food and Agriculture

DOI 10.1002/jsfa.9230

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Abstract

BACKGROUND: In this research, a new extraction method based on dispersive liquid–liquid microextraction and the solidification of deep eutectic solvent has been developed for the determination of heavy metals in soil and vegetables prior to their analysis by graphite furnace atomic absorption spectrometry (GFAAS). In this method, a green solvent consisting of 1‐decyl‐3‐methylimidazolium chloride and 1‐undecanol was used as an extraction solvent, yielding the advantages of material stability, low density and a suitable freezing point near room temperature. RESULTS: Under optimal conditions, enrichment factors are in the range of 114–172. The calibration graphs are linear in the range of 0.02–200 µg kg−1 and limits of detection are in the range of 0.01–0.03 µg kg−1. Repeatability and reproducibility of the method based on seven replicate measurements of 0.80 µg kg−1 of Hg and 0.20 µg kg−1 of Pb and Cd in analyzed samples were in the range of 2.3–4.1% and 3.7–6.6%, respectively. CONCLUSION: A new deep eutectic solvent consists of two parts: 1‐decyl‐3‐methylimidazolium chloride and 1‐undecanol in a molar ratio of 1:2. The accuracy of the proposed procedure was also assessed by determining the concentration of the studied metal ions in a polluted farmland soil standard reference material. © 2018 Society of Chemical Industry

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DESs have been used as extracting solvents for determination of polycyclic aromatic hydrocarbons, metals, methadone, ultraviolet filters, benzoylureas, aromatic amines and other organic and inorganic contaminants in water samples.
“They are used as extracting solvents for determination of polycyclic aromatic hydrocarbons [26,27], metals [28,29], methadone [30], ultraviolet filters [31], benzoylureas [32,33], aromatic amines [34] and other organic and inorganic contaminants in water samples.”
From Deep eutectic solvent as a novel disperser in dispersive liquid-liquid microextraction based on solidification of floating organic droplet (DLLME-SFOD) for preconcentration of steroids in water samples: Assessment of the method deleterious impact on the environment using Analytical Eco-Scale and Green Analytical Procedure Index (2019) · cites this paper as [29]
DES-DLLME-SFOD was applied for the extraction of heavy metals (Pb, Cd, Hg) from soil and vegetables that had been irrigated with treated municipal wastewater [75].
“DES-DLLME-SFOD was applied for the extraction of heavy metals (Pb, Cd, Hg) from soil and vegetables that had been irrigated with treated municipal wastewater [75].”
From Deep Eutectic Solvents as Promising Green Solvents in Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Droplet: Recent Applications, Challenges and Future Perspectives (2021) · cites this paper as [75]
High EFs (up to 1142) were achieved.
“High EFs (up to 1142) were achieved.”
From Deep Eutectic Solvents as Promising Green Solvents in Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Droplet: Recent Applications, Challenges and Future Perspectives (2021) · cites this paper as [75]
Lead is the only metal from column 14 in the Periodic Table of Elements that has been studied [17,74,75].
“Lead is the only metal from column 14 in the Periodic Table of Elements that has been studied [17,74,75].”
From Deep Eutectic Solvents as Promising Green Solvents in Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Droplet: Recent Applications, Challenges and Future Perspectives (2021) · cites this paper as [75]

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Authors: Habibollahi, M. H., Karimyan, K., Arfaeinia, H., Mirzaei, N., Safari, Y., Akramipour, R., Sharafi, H., & Fattahi, N.
Affiliations: Islamic Azad University, Zahedan Branch (IR)
Environmental Health Research Center Kurdistan University of Medical Sciences Sanandaj Iran
Iran University of Medical Sciences (IR)
Kashan University of Medical Sciences (IR)
Kermanshah University of Medical Sciences (IR)
Corresponding author: Fattahi, Nazir
ORCID: Habibollahi, Mohammad Hossein
Arfaeinia, Hossein
Mirzaei, Nezam
Safari, Yahya
Akramipour, Reza
Fattahi, Nazir
Venue: Journal of the Science of Food and Agriculture
Publisher: Wiley
Published: 2018-08-21
Volume: 99
Issue: 2
Pages: 656-665
ISSN: 0022-5142 (ISSN-L)
1097-0010
DOI: 10.1002/jsfa.9230
OpenAlex: W2810316299
Cited by: 133
References: 43
Citations by year: 2026: 3 · 2025: 10 · 2024: 20 · 2023: 17 · 2022: 23 · 2021: 21 · 2020: 27 · 2019: 10 · 2018: 2
FWCI: 9.36
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Journal of the Science of Food and Agriculture (publishedVersion)
PubMed (publishedVersion)
Funders: Kerman University of Medical Sciences
Topics: Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
Keywords: heavy metals, soil contamination, vegetables, dispersive liquid-liquid microextraction, 1-undecanol, graphite furnace atomic absorption spectrometry, mercury, lead, cadmium, agricultural soil contamination
MeSH terms: Soil, Mass Spectrometry, Vegetables, Water Pollutants, Chemical, Metals, Heavy, Limit of Detection, Agricultural Irrigation, Liquid Phase Microextraction, Wastewater

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Extraction and determination of heavy metals in soil and vegetables irrigated with treated municipal wastewater using new mode of dispersive liquid-liquid microextraction based on the solidified deep eutectic solvent followed by GFAAS

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