The Influence of Blend Morphology (Co-Continuous or Sub-Micrometer Droplets Dispersions) on the Nucleation and Crystallization Kinetics of Double Crystalline Polyethylene/Polyamide Blends Prepared by Reactive Extrusion
Abstract
Abstract Reactive blending of functionalized polyethylenes (PE) and polyamides (PA) is performed by carefully choosing extrusion conditions and polymeric materials in order to obtain two types of stable morphologies. The first blend type yields a co‐continuous morphology and the second type a dispersion of sub‐micron droplets of the PA phase in a PE matrix. The crystallization kinetics of the PA change from a sigmoidal classical type (for the co‐continuous blend) to first‐order kinetics in the case of the sub‐micron PA droplets. The results demonstrate an intimate relationship between blend morphology and nucleation and crystallization kinetics of the blend components. magnified image
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In reactively compatibilized PE/PA6 blends, dispersed phase morphology gives an Avrami exponent close to 1, while co-continuous morphology gives n=3.
“For the dispersed phase morphology an exponent close to 1 is found, while the co-continuous blend presents a value of 3 [33] .”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [33]
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- Authors
- Córdova, M. E., Lorenzo, A. T., Müller, A. J., Gani, L., Tencé‐Girault, S., & Leibler, L.
- Affiliations
- Universidad Simón Bolívar (VE)
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Müller, Alejandro J.
- Venue
- Macromolecular Chemistry and Physics
- Publisher
- Wiley
- Published
- 2011-04-13
- Volume
- 212
- Issue
- 13
- Pages
- 1335-1350
- ISSN
- 1022-1352 (ISSN-L)
- 1521-3935
- OpenAlex
- W2093311194
- Cited by
- 50
- References
- 65
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 6 · 2023: 2 · 2022: 3 · 2021: 1 · 2020: 5 · 2019: 4 · 2018: 5 · 2017: 2 · 2016: 2 · 2015: 7 · 2014: 1 · 2013: 6 · 2012: 4
- FWCI
- 3.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Chemistry and Physics (publishedVersion)
- HAL (submittedVersion)
- Funders
- Decanato de Investigación y Desarrollo (DID-GID-G02)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Foaming and Composites
- Keywords
- blend morphology, co-continuous morphology, nucleation kinetics, crystallization kinetics, reactive extrusion, reactive blending, functionalized polyethylene, polymer blends
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