High-Impact PLA in Compatibilized PLA/PCL Blends: Optimization of Blend Composition and Type and Content of Compatibilizer

Fernández‐Tena, Ainhoa; Otaegi, Itziar; Irusta, Lourdes; Sebastián, Victor; Guerrica‐Echevarria, Gonzalo; Müller, Alejandro Jesus; Aranburu, Nora

doi:10.1002/mame.202300213

Cited by 34biodegradable polymer synthesis and propertiesPolymer crystallization and propertiesBlock Copolymer Self-Assembly

High-Impact PLA in Compatibilized PLA/PCL Blends: Optimization of Blend Composition and Type and Content of Compatibilizer

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Fernández‐Tena, Ainhoa, Otaegi, Itziar, Irusta, Lourdes, Sebastián, Victor, Guerrica‐Echevarria, Gonzalo, Müller, Alejandro Jesus, Aranburu, Nora·2023·Macromolecular Materials and Engineering

DOI 10.1002/mame.202300213

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Abstract

Abstract In this work, the effectiveness of seven commercial compatibilizers is tested in polylactide (PLA)/poly(ε‐caprolactone) (PCL) blends with different compositions to obtain a high‐impact PLA. None of the compatibilizers is effective for 90/10 and 80/20 PLA/PCL compositions, as no improvement of the impact strength is observed. For the 70/30 composition, compatibilizers having glycidyl methacrylate (GMA) and acrylate groups in their structure are proved the most effective, as the morphological change towards co‐continuity induced by them leads to significant impact strength improvements (of ≈345% and 90% with respect to the neat PLA and the noncompatibilized PLA/PCL 70/30 blend, respectively). The 70/30 PLA/PCL composition, as it shows the best balance of properties, and the best compatibilizer (ElvaloyPTW) are chosen to carry out the optimization of the compatibilizer content. It is found that adding 6 phr to the blend results in highly toughened and ductile blends while maintaining a high modulus and yield strength values. Larger compatibilizer contents lead to even higher impact strength values, but the low‐strain mechanical properties are notably reduced. Thus, in this work, a simple and easily scalable method to produce high‐impact PLA is shown, as it implies the compounding of three commercially available components without involving any toxic solvents.

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PLA and PCL are immiscible, and this immiscibility remains a challenge for blending them.
“The combination of these polymers in blends aims to balance these properties, though the immiscibility of the two remains a challenge [4]”
From Nanocellulose-Reinforced Poly(Lactic Acid) and Poly(ε-caprolactone) Bio-Nanocomposites: A Review and Future Outlook for Poly(Lactic Acid)/Poly(ε-caprolactone) Blend Systems (2025) · cites this paper as [4]

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Poly(lactic acid) modifications
Rasal, R. M., Janorkar, A. V., & Hirt, D. E. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.12.003 · Cited by 2,204 · see citing works
Poly(lactic acid) crystallization
Saeidlou, S., Huneault, M. A., Li, H., & Park, C. B. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.07.005 · Cited by 1,606 · see citing works
Poly (lactic acid) blends: Processing, properties and applications
Nofar, M., Sacligil, D., Carreau, P. J., Kamal, M. R., & Heuzey, M.-C. (2019) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2018.12.002 · Cited by 780 · see citing works
Toughening Polylactide
Anderson, K., Schreck, K., & Hillmyer, M. (2008) · Polymer Reviews · doi:10.1080/15583720701834216 · Cited by 600 · see citing works
Improving mechanical performance of injection molded PLA by controlling crystallinity
Harris, A. M., & Lee, E. C. (2007) · Journal of Applied Polymer Science · doi:10.1002/app.27261 · Cited by 546 · see citing works
Natural fiber reinforced polylactic acid composites: A review
Siakeng, R., Jawaid, M., Ariffin, H., Sapuan, S. M., Asim, M., & Saba, N. (2018) · Polymer Composites · doi:10.1002/pc.24747 · Cited by 535 · see citing works
Super tough poly(lactic acid) blends: a comprehensive review
Zhao, X., Hu, H., Wang, X., Yu, X., Zhou, W., & Peng, S. (2020) · RSC Advances · doi:10.1039/d0ra01801e · Cited by 465 · see citing works
Design of biodegradable blends based on PLA and PCL: From morphological, thermal and mechanical studies to shape memory behavior
Navarro-Baena, I., Sessini, V., Dominici, F., Torre, L., Kenny, J. M., & Peponi, L. (2016) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2016.03.037 · Cited by 304 · see citing works
Crystallization, morphology, and mechanical behavior of polylactide/poly(ε‐caprolactone) blends
López‐Rodríguez, N., López-Arraiza, A., Meaurio, E., & Sarasua, J.-R. (2006) · Polymer Engineering and Science · doi:10.1002/pen.20609 · Cited by 288 · see citing works
Tailoring Impact Toughness of Poly(<scp>l</scp>-lactide)/Poly(ε-caprolactone) (PLLA/PCL) Blends by Controlling Crystallization of PLLA Matrix
Bai, H., Xiu, H., Gao, J., Deng, H., Zhang, Q., Yang, M., & Fu, Q. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am201564f · Cited by 260 · see citing works
Tailoring crystallization: towards high-performance poly(lactic acid)
Liu, G., Zhang, X., & Wang, D. (2014) · Advanced Materials · doi:10.1002/adma.201305413 · Cited by 249 · see citing works
Phase Structure, Compatibility, and Toughness of PLA/PCL Blends: A Review
Fortelny, I., Ujcic, A., Fambri, L., & Slouf, M. (2019) · Frontiers in Materials · doi:10.3389/fmats.2019.00206 · Cited by 238 · see citing works
Mechanical properties of poly(ε‐caprolactone) and poly(lactic acid) blends
Simões, C. L., Viana, J. C., & Cunha, A. M. (2008) · Journal of Applied Polymer Science · doi:10.1002/app.29425 · Cited by 218 · see citing works
Phase behavior and its viscoelastic response of polylactide/poly(ε-caprolactone) blend
Wu, D., Zhang, Y., Zhang, M., & Zhou, W. (2008) · European Polymer Journal · doi:10.1016/j.eurpolymj.2008.04.023 · Cited by 213 · see citing works
Recent advances in high performance poly(lactide): from “green” plasticization to super-tough materials via (reactive) compounding
Kfoury, G., Raquez, J., Hassouna, F., Odent, J., Toniazzo, V., Ruch, D., & Dúbois, P. (2013) · Frontiers in Chemistry · doi:10.3389/fchem.2013.00032 · Cited by 184 · see citing works
Melt processed PLA/PCL blends: Effect of processing method on phase structure, morphology, and mechanical properties
Urquijo, J., Guerrica‐Echevarría, G., & Eguiazábal, J. I. (2015) · Journal of Applied Polymer Science · doi:10.1002/app.42641 · Cited by 176 · see citing works
Synergistic effects in mechanical properties of PLA/PCL blends with optimized composition, processing, and morphology
Ostafinska, A., Fortelny, I., Nevoralova, M., Hodan, J., Kredatusova, J., & Slouf, M. (2015) · RSC Advances · doi:10.1039/c5ra21178f · Cited by 176 · see citing works
Toughening of poly(l-lactide) with poly(ε-caprolactone): Combined effects of matrix crystallization and impact modifier particle size
Bai, H., Huang, C., Xiu, H., Gao, Y., Zhang, Q., & Fu, Q. (2013) · Polymer · doi:10.1016/j.polymer.2013.07.051 · Cited by 153 · see citing works
Reactive compatibilization of biodegradable poly(lactic acid)/poly(ε‐caprolactone) blends with reactive processing agents
Harada, M., Iida, K., Okamoto, K., Hayashi, H., & Hirano, K. (2008) · Polymer Engineering and Science · doi:10.1002/pen.21088 · Cited by 150 · see citing works
Impact modified PLA-hydroxyapatite composites – Thermo-mechanical properties
Akindoyo, J. O., Beg, M. D. H., Ghazali, S. B., Heim, H., & Feldmann, M. (2018) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2018.01.017 · Cited by 145 · see citing works
Effect of miscibility on mechanical and thermal properties of poly(lactic acid)/polycaprolactone blends
Ferri, J. M., Fenollar, O., Jorda‐Vilaplana, A., García‐Sanoguera, D., & Balart, R. (2016) · Polymer International · doi:10.1002/pi.5079 · Cited by 141 · see citing works
Effect of glycidyl methacrylate‐grafted natural rubber on physical properties of polylactic acid and natural rubber blends
Juntuek, P., Ruksakulpiwat, Y., Chumsamrong, P., & Ruksakulpiwat, Y. (2011) · Journal of Applied Polymer Science · doi:10.1002/app.36263 · Cited by 128 · see citing works
Research progress in the heat resistance, toughening and filling modification of PLA
Yang, Y., Zhang, L., Xiong, Z., Tang, Z., Zhang, R., & Zhu, J. (2016) · Science China Chemistry · doi:10.1007/s11426-016-0222-7 · Cited by 128 · see citing works
Study on the Crystallization, Miscibility, Morphology, Properties of Poly(lactic acid)/Poly(ε-caprolactone) Blends
Yeh, J., Wu, C.-J., Tsou, C., Chai, W., Chow, J., Huang, C., Chen, K., & Wu, C.-S. (2009) · Polymer-Plastics Technology and Engineering · doi:10.1080/03602550902824390 · Cited by 127 · see citing works
Strong synergistic effects in PLA/PCL blends: impact of PLA matrix viscosity
Ostafinska, A., Fortelný, I., Hodan, J., Krejčíková, S., Nevoralová, M., Kredatusová, J., Kruliš, Z., Kotek, J., & Šlouf, M. (2017) · Journal of the Mechanical Behavior of Biomedical Materials · doi:10.1016/j.jmbbm.2017.01.015 · Cited by 118 · see citing works
Nucleation Enhancement Effect in Poly( l -lactide) (PLLA)/Poly(ϵ-caprolactone) (PCL) Blend Induced by Locally Activated Chain Mobility Resulting from Limited Miscibility
Sakai, F., Nishikawa, K., Inoue, Y., & Yazawa, K. (2009) · Macromolecules · doi:10.1021/ma901547a · Cited by 113 · see citing works
PLA maleation: an easy and effective method to modify the properties of PLA/PCL immiscible blends
Gardella, L., Calabrese, M., & Monticelli, O. (2014) · Colloid & Polymer Science · doi:10.1007/s00396-014-3328-3 · Cited by 99 · see citing works
Immiscible Poly( L ‐lactide)/Poly(ε‐caprolactone) Blends: Influence of the Addition of a Poly( L ‐lactide)‐Poly(oxyethylene) Block Copolymer on Thermal Behavior and Morphology
Maglio, G., Malinconico, M., Migliozzi, A., & Groeninckx, G. (2004) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200300150 · Cited by 89 · see citing works
Fabrication of super-tough ternary blends by melt compounding of poly(lactic acid) with poly(butylene succinate) and ethylene-methyl acrylate-glycidyl methacrylate
Xue, B., He, H., Huang, Z., Zhu, Z., Xue, F., Liu, S., & Liu, B. (2019) · Composites Part B Engineering · doi:10.1016/j.compositesb.2019.05.098 · Cited by 82 · see citing works
A new insight into morphological, thermal, and mechanical properties of melt-processed polylactide/poly( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si1.gif" overflow="scroll"> <mml:mi mathvariant="normal">ε</mml:mi> </mml:math> -caprolactone) blends
Botlhoko, O. J., Ramontja, J., & Ray, S. S. (2018) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2018.05.025 · Cited by 81 · see citing works
Silsesquioxanes: Novel compatibilizing agents for tuning the microstructure and properties of PLA/PCL immiscible blends
Monticelli, O., Calabrese, M., Gardella, L., Fina, A., & Gioffredi, E. (2014) · European Polymer Journal · doi:10.1016/j.eurpolymj.2014.06.021 · Cited by 72 · see citing works
Design of highly tough poly( l ‐lactide)‐based ternary blends for automotive applications
Bouzouita, A., Samuel, C., Notta‐Cuvier, D., Odent, J., Lauro, F., Dúbois, P., & Raquez, J. (2016) · Journal of Applied Polymer Science · doi:10.1002/app.43402 · Cited by 56 · see citing works
Improvement of microstructures and properties of biodegradable PLLA and PCL blends compatibilized with a triblock copolymer
Vilay, V., Mariatti, M., Ahmad, Z., Pasomsouk, K., & Todo, M. (2010) · Materials Science and Engineering: A · doi:10.1016/j.msea.2010.07.079 · Cited by 55 · see citing works
Polylactic Acid/Polycaprolactone Blends: On the Path to Circular Economy, Substituting Single-Use Commodity Plastic Products
Delgado‐Aguilar, M., Puig, R., Sazdovski, I., & Fullana–i–Palmer, P. (2020) · Materials · doi:10.3390/ma13112655 · Cited by 53 · see citing works
Controlling the Isothermal Crystallization of Isodimorphic PBS-ran-PCL Random Copolymers by Varying Composition and Supercooling
Safari, M., Múgica, A., Zubitur, M., de Ilarduya, A. M., Muñoz‐Guerra, S., & Müller, A. J. (2019) · Polymers · doi:10.3390/polym12010017 · Cited by 50 · see citing works
Super-Toughened Poly(lactic Acid) with Poly(ε-caprolactone) and Ethylene-Methyl Acrylate-Glycidyl Methacrylate by Reactive Melt Blending
Hou, A., & Qu, J. (2019) · Polymers · doi:10.3390/polym11050771 · Cited by 49 · see citing works
A New Approach to Supertough Poly(lactic acid): A High Temperature Reactive Blending
Yuryev, Y., Mohanty, A. K., & Misra, M. (2016) · Macromolecular Materials and Engineering · doi:10.1002/mame.201600242 · Cited by 45 · see citing works
Mechanical and thermal properties of conventional and microcellular injection molded poly (lactic acid)/poly (ε-caprolactone) blends
Zhao, H., & Zhao, G. (2015) · Journal of the mechanical behavior of biomedical materials/Journal of mechanical behavior of biomedical materials · doi:10.1016/j.jmbbm.2015.08.002 · Cited by 40 · see citing works
Highly toughened and heat resistant poly(l-lactide)/poly(ε-caprolactone) blends via engineering balance between kinetics and thermodynamics of phasic morphology with stereocomplex crystallite
Si, W., Zhang, H., Li, Y., Huang, C., Weng, Y., & Zeng, J. (2020) · Composites Part B Engineering · doi:10.1016/j.compositesb.2020.108155 · Cited by 38 · see citing works
Melt processing of maleic anhydride grafted poly(lactic acid) and its compatibilizing effect on poly(lactic acid)/poly(butylene adipate-co-terephthalate) blend and their composite
Teamsinsungvon, A., Jarapanyacheep, R., Ruksakulpiwat, Y., & Jarukumjorn, K. (2017) · Polymer Science Series A · doi:10.1134/s0965545x1703018x · Cited by 37 · see citing works
Effect of thermal annealing on crystal structure and properties of PLLA/PCL blend
Chen, J., Deng, C., Hong, R., Fu, Q., & Zhang, J. (2020) · Journal of polymer research · doi:10.1007/s10965-020-02206-1 · Cited by 36 · see citing works
Effect of epoxy functionalized compatibilizer on the mechanical properties of low‐density polyethylene/plasticized tapioca starch blends
Sailaja, R. R. N., Reddy, A. P., & Chanda, M. (2001) · Polymer International · doi:10.1002/pi.787 · Cited by 33 · see citing works
Poly(lactic acid)–layered silicate nanocomposites: The effects of modifier and compatibilizer on the morphology and mechanical properties
Açık, E., Baouz, T., & Yilmazer, Ü. (2015) · Journal of Applied Polymer Science · doi:10.1002/app.42553 · Cited by 28 · see citing works
Study on miscibility, thermal properties, degradation behaviors, and toughening mechanism of poly(lactic acid)/poly (ethylene-butylacrylate-glycidyl methacrylate) blends
Zhao, J., Pan, H., Yang, H., Bian, J., Zhang, H., Gao, G., & Dong, L. (2019) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2019.11.226 · Cited by 28 · see citing works
Effect of Ethylene/butyl methacrylate/Glycidyl Methacrylate Terpolymer on toughness and biodegradation of poly (l-lactic acid)
Jia, S., Chen, Y., Yu, Y., Han, L., Zhang, H., & Dong, L. (2019) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2019.01.068 · Cited by 27 · see citing works
Excellent impact strength of ethylene-methyl acrylate copolymer toughened polycarbonate
Bagotia, N., Singh, B. P., Choudhary, V., & Sharma, D. K. (2015) · RSC Advances · doi:10.1039/c5ra18024d · Cited by 20 · see citing works
Temperature-responsive properties of poly(acrylic acid-co-acrylamide)-graft-oligo(ethylene glycol) hydrogels
Kubota, N., Tatsumoto, N., Sano, T., & Matsukawa, Y. (2001) · Journal of Applied Polymer Science · doi:10.1002/1097-4628(20010502)80:5 · Cited by 19 · see citing works
Synergistic toughening and compatibilisation effect of poly(butylene succinate) in PLA/poly-caprolactone blends
Kassos, N., Kelly, A. L., Gough, T. D., & Gill, A. A. (2018) · Materials Research Express · doi:10.1088/2053-1591/aaf7c1 · Cited by 15 · see citing works
Influences of three different ethylene copolymers on the toughness and other properties of polylactide
Meyva, Y., & Kaynak, C. (2016) · Plastics Rubber and Composites Macromolecular Engineering · doi:10.1080/14658011.2016.1153821 · Cited by 11 · see citing works
Ethylene Methyl Acrylate Copolymer Toughened Poly(lactic acid) Blends: Phase Morphologies, Mechanical and Rheological Properties
Xu, L., Zhao, Y., Chen, R. Y., Kang, B.-H., & Peng, X. (2016) · International Polymer Processing · doi:10.3139/217.3178 · Cited by 3 · see citing works

Flagged first, then by citations

Research works printed but not linked: 51

M. Nofar, D. Sacligil, P. J. Carreau, M. R. Kamal, M.-C. Heuzey, Int. J. Biol. Macromol. 2019, 125, 307.
R. Siakeng, M. Jawaid, H. Ariffin, S. M. Sapuan, M. Asim, N. Saba, Polym. Compos. 2018, 40, 446.
R. M. Rasal, A. V. Janorkar, D. E. Hirt, Prog. Polym. Sci. 2010, 35, 338.
S. Saeidlou, M. A. Huneault, H. Li, C. B. Park, Prog. Polym. Sci. 2012, 37, 1657.
A. M. Harris, E. C. Lee, J. Appl. Polym. Sci. 2008, 107, 2246.
G. Liu, X. Zhang, D. Wang, Adv. Mater. 2014, 26, 6905.
Y. Yang, L. Zhang, Z. Xiong, Z. Tang, R. Zhang, J. Zhu, Sci China Chem 2016, 59, 1355.
K. Anderson, K. Schreck, M. Hillmyer, Polym. Rev. 2008, 48, 85.
G. Kfoury, J.-M. Raquez, F. Hassouna, J. Odent, V. Toniazzo, D. Ruch, P. Dubois, Front Chem 2013, 1, 32.
X. Zhao, H. Hu, X. Wang, X. Yu, W. Zhou, S. Peng, RSC Adv. 2020, 10, 13316.
I. Fortelny, A. Ujcic, L. Fambri, M. Slouf, Front. Mater. 2019, 6, 206.
J. Urquijo, G. Guerrica-Echevarría, J. I. Eguiazábal, J. Appl. Polym. Sci. 2015, 132, 42641.
J. M. Ferri, O. Fenollar, A. Jorda-Vilaplana, D. García-Sanoguera, R. Balart, Polym. Int. 2016, 65, 453.
N. Kassos, A. L. Kelly, T. Gough, A. A. Gill, Mater Res Express 2019, 6, 035313.
J.-T. Yeh, C.-J.u Wu, C.-H. Tsou, W.-L. Chai, J.-D. Chow, C.-Y. Huang, K.-N. Chen, C.-S. Wu, Polym. -Plast. Technol. Eng. 2009, 48, 571.
H. Zhao, G. Zhao, J. Mech. Behav. Biomed. Mater. 2016, 53, 59.
I. Navarro-Baena, V. Sessini, F. Dominici, L. Torre, J. M. Kenny, L. Peponi, Polym. Degrad. Stab. 2016, 132, 97.
P. Wongwiwattana, N. L. Thomas, Polym.-Plast. Technol. Mater. 2021, 60, 1393.
C. L. Simões, J. C. Viana, A. M. Cunha, J. Appl. Polym. Sci. 2009, 112, 345.
M. Delgado-Aguilar, R. Puig, I. Sazdovski, P. Fullana-I-Palmer, Mate- rials 2020, 13, 2655.
N. López-Rodríguez, A. López-Arraiza, E. Meaurio, J. R. Sarasua, Polym. Eng. Sci. 2006, 46, 1299.
O. Monticelli, M. Calabrese, L. Gardella, A. Fina, E. Gioffredi, Eur. Polym. J. 2014, 58, 69.
L. Gardella, M. Calabrese, O. Monticelli, Colloid Polym. Sci. 2014, 292, 2391.
H. Bai, H. Xiu, J. Gao, H. Deng, Q. Zhang, M. Yang, Q. Fu, ACS Appl Mater Interfaces 2012, 4, 897.
J. Chen, C. Deng, R. Hong, Q. Fu, J. Zhang, J. Polym. Res. 2020, 27, 221.
W.-J. Si, H. Zhang, Y.i-D. Li, C. Huang, Y.-X. Weng, J.-B. Zeng, Com- posites, Part B Eng. 2020, 197, 108155.
H. Bai, C. Huang, H. Xiu, Y. Gao, Q. Zhang, Q. Fu, Polymer 2013, 54, 5257.
A. Ostafinska, I. Fortelny, M. Nevoralova, J. Hodan, J. Kredatusova, M. Slouf, RSC Adv. 2015, 5, 98971.
A. Ostafinska, I. Fortelný, J. Hodan, S. Krejčíková, M. Nevoralová, J. Kredatusová, Z. Kruliš, J. Kotek, M. Šlouf, J. Mech. Behav. Biomed. Mater. 2017, 69, 229.
V. Vilay, M. Mariatti, Z. Ahmad, K. Pasomsouk, M. Todo, Mater. Sci. Eng., A 2010, 527, 6930.
M. Harada, K. Iida, K. Okamoto, H. Hayashi, K. Hirano, Polym. Eng. Sci. 2008, 48, 1359.
A.o-L. Hou, J.-P. Qu, Polymers 2019, 11, 771.
A. Bouzouita, C. Samuel, D. Notta-Cuvier, J. Odent, F. Lauro, P. Dubois, J.-M. Raquez, J. Appl. Polym. Sci. 2016, 133, 43402.
M. Safari, A. Mugica, M. Zubitur, A. Martínez De Ilarduya, S. Muñoz- Guerra, A. J. Müller, Polymers 2020, 12, 17.
J. O. Akindoyo, M. D. H. Beg, S. Ghazali, H. P. Heim, M. Feldmann, Composites, Part A Appl. Sci. Manuf. 2018, 107, 326.
Y. Yuryev, A. K. Mohanty, M. Misra, Macromol. Mater. Eng. 2016, 301, 1443.
O. J. Botlhoko, J. Ramontja, S. S. Ray, Polym. Degrad. Stab. 2018, 154, 84.
G. Maglio, M. Malinconico, A. Migliozzi, G. Groeninckx, Macromol. Chem. Phys. 2004, 205, 946.
F. Sakai, K. Nishikawa, Y. Inoue, K. Yazawa, Macromolecules 2009, 42, 8335.
Y. Meyva, C. Kaynak, Plast. Rubber Composites 2016, 45, 189.
L. Q. Xu, Y. Q. Zhao, R. Y. Chen, B. H. Kang, X. F. Peng, Int. Polym. Process. 2016, 31, 301.
N. Bagotia, B. P. Singh, V. Choudhary, D. K. Sharma, RSC Adv. 2015, 5, 87589.
G. Bayram, U. Yilmazer, M. Xanthos, J. Appl. Polym. Sci. 2001, 80, 790.
D. Wu, Y. Zhang, M. Zhang, W. Zhou, Eur. Polym. J. 2008, 44, 2171.
J. Zhao, H. Pan, H. Yang, J. Bian, H. Zhang, G.e Gao, L. Dong, Int. J. Biol. Macromol. 2020, 143, 443.
E. A. Cumkur, T. Baouz, U. Yilmazer, J. Appl. Polym. Sci. 2015, 132, 42553.
S. Jia, Y. Chen, Y. Yu, L. Han, H. Zhang, L. Dong, Int. J. Biol. Macromol. 2019, 127, 415.
B. Xue, H.e-Z. He, Z.-X. Huang, Z. Zhu, F. Xue, S. Liu, B. Liu, Com- posites, Part B. 2019, 172, 743.
P. Juntuek, C. Ruksakulpiwat, P. Chumsamrong, Y. Ruksakulpiwat, J. Appl. Polym. Sci. 2012, 125, 745.
A. Teamsinsungvon, R. Jarapanyacheep, Y. Ruksakulpiwat, K. Jarukumjorn, Polym. Sci. -Ser. A 2017, 59, 384.
R. R. N. Sailaja, A. P. Reddy, M. Chanda, Polym. Int. 2001, 50, 1352.

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Ngwenya, M., Gumede, T. P., Pérez Camargo, R. A., & Motloung, B. (2025) · Materials · doi:10.3390/ma18225172 · Cited by 9 · see citing works
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Duan, H., Shang, X., Wu, X., Ma, L., Chen, X., & Zhu, J. (2025) · Journal of Materials Science and Chemical Engineering · doi:10.4236/msce.2025.131003 · Cited by 9 · see citing works
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da Costa, F. A. T., Dufresne, A., & Parra, D. F. (2025) · ACS Omega · doi:10.1021/acsomega.5c06115 · Cited by 9 · see citing works
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Binley, G., & Mekonnen, T. H. (2025) · Macromolecular Rapid Communications · doi:10.1002/marc.202500276 · Cited by 6 · see citing works
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Martin-Larrañaga, N., Razquin, I., Aranburu, N., Sánz, O., González, A., & Irusta, L. (2025) · Progress in Organic Coatings · doi:10.1016/j.porgcoat.2025.109716 · Cited by 6 · see citing works
Biodegradable Nanocomposite Filament Based on <scp>PLA</scp> / <scp>PCL</scp> / <scp>CNCs</scp> for <scp>FDM 3D</scp> Printing: Production, Characterization and Printability
Ilhan, R., Gumus, O. Y., & Lekesiz, H. (2026) · Polymer Composites · doi:10.1002/pc.70459 · Cited by 5 · see citing works
Mechanical, barrier, and photodegradation properties of biodegradable PLA-based blend films
Fernández‐Tena, A., Olmedo-Martínez, J. L., Sabino, M. A., Collinson, E., López, J. V., Irusta, L., González, A., de Ilarduya, A. M., Guerrica‐Echevarría, G., Aranburu, N., et al. (2025) · RSC Sustainability · doi:10.1039/d5su00454c · Cited by 5 · see citing works
Thermal and Mechanical Performance of Maleic Anhidride/Benzoyl Peroxide-Modified PLA/PCL Biocomposites
Garay, A. U., Barragán, A. L., Bou, S. F., & Samper, M. D. (2025) · Polymers · doi:10.3390/polym17182540 · Cited by 5 · see citing works
Synergistic dual-engineering of poly (lactic acid) biodegradable plastics: Low-carbon toughening meets controlled degradation kinetics
Jing, Y., Jiang, X., Zhang, Y., Chi, W., Leng, S., Li, Y., Hao, Y., Wang, Y., Li, R., & Song, L. (2026) · Chemical Engineering Journal · doi:10.1016/j.cej.2026.173299 · Cited by 4 · see citing works
Overcoming Strength-Ductility Trade-off in Fully Biodegradable Polylactic Acid/Elastomer Composites: Synergistic in Situ Topological Fibrillation and Supercritical CO 2 -Induced Nanocrystals
Chai, J., Wang, G., Wang, S., Shao, R., & Zhao, G. (2026) · Macromolecules · doi:10.1021/acs.macromol.5c03240 · Cited by 4 · see citing works
From brittleness to toughness: tailoring PLA performance through epoxidized soybean oil in combination with controlled annealing
Serafim, C. M. M., Queiroz, J. V. S. D. A., Luna, C. B. B., Ferreira, E. D. S. B., do Nascimento, E. P., Sobrinho, V. D. S. S., Wellen, R. M. R., & Araújo, E. M. (2026) · Polymer Bulletin · doi:10.1007/s00289-026-06596-y · Cited by 3 · see citing works
Preparation of biodegradable poly(lactic acid)/poly[(butylene diglycolate)‐ co ‐furandicarboxylate] blends with excellent toughness and gas barrier performance
Yang, Y., Shen, J., Hu, E., Fang, Y., Xu, Z., & Li, J. (2024) · Polymer International · doi:10.1002/pi.6692 · Cited by 3 · see citing works
On the upcycling of PCL to produce building blocks for the development of PCL-PLA copolymers
Damonte, G., Dullaert, L., Pellis, A., Giribaldi, L., & Monticelli, O. (2026) · European Polymer Journal · doi:10.1016/j.eurpolymj.2026.114563 · Cited by 2 · see citing works
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Cheng, H., Yu, M., Zhang, Y., Shi, H., Yu, Y., Wang, L., & Han, C.-S. (2024) · Journal of Thermal Analysis and Calorimetry · doi:10.1007/s10973-024-13245-x · Cited by 2 · see citing works
Additivation of PLA/PBAT Blends to Expand Applications in the Biodegradable Packaging Sector
Agostini, N. B., da Silva, R. B., & Santana, R. M. C. (2025) · Materials Research · doi:10.1590/1980-5373-mr-2025-0123 · Cited by 2 · see citing works
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Gao, X., Yang, C., Zhu, J., Zhang, X., & Su, Y. (2025) · Macromolecular Chemistry and Physics · doi:10.1002/macp.202400438 · Cited by 1 · see citing works
A sustainable strategy for simultaneous enhancement of toughness, degradation, and optical properties in poly(lactic acid)/poly(ε-caprolactone) blends via bio-based reactive compatibilization
Xu, Z., Jing, Y., Bai, X., Leng, S., Zhang, S., Ni, Y., Li, Y., Hao, Y., Wang, Y., & Song, L. (2025) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2025.149983 · Cited by 1 · see citing works
Interfacial engineering of biodegradable poly(lactic acid)/poly(ε-caprolactone) blends via reactive compatibilization for multifunctional performance
Gao, G., Jing, Y., Xu, Z., Chi, W., Leng, S., Yao, S., Li, Y., Hao, Y., Wang, Y., & Song, L. (2026) · Materials Today Chemistry · doi:10.1016/j.mtchem.2026.103537 · Cited by 1 · see citing works
Effect of Sugarcane Bagasse-Derived Cellulose Nanocrystals on the Thermal, Structural, Morphological and Biodegradation Properties of Poly(ε-caprolactone) and Poly(lactic Acid)
Ngwenya, M., Gumede, T. P., & Motloung, B. (2026) · Polymers · doi:10.3390/polym18091132 · Cited by 1 · see citing works
Optimizing Bone Scaffold Design Using Response Surface and Artificial Neural Network-Genetic Algorithm Methods with Biocompatibility EvaluationPreprint
Srisang, N., Maikaew, J., Tambunlertchai, S., Eiangmee, O., Kamdenlek, P., Manaspon, C., Salem, A. K., Phetpan, K., Srisang, S., & Sokjabok, S. (2025) · SSRN Electronic Journal · doi:10.2139/ssrn.5340703 · Cited by 1 · see citing works
Synthetic poly (4-hydroxybutyrate) as reinforcing additive to manufacture high-performance and fully biodegradable PBAT composites for foaming applicationsPreprint
Cui, J., Wang, H., Chen, X., Kan, Z., & Li, Z. (2024) · Research Square · doi:10.21203/rs.3.rs-3901681/v1
Designing Robust, Antibacterial and Uv-Shielding Poly(Lactic Acid) Nanocomposites by Multi-Functional Nanochitin Via Surface Chemistry: Preparation and Food Packaging ApplicationPreprint
Zhang, L., Yang, T., Li, R., Ding, M., & Xie, H. (2025) · SSRN Electronic Journal · doi:10.2139/ssrn.5227069
Preparation and characterization of biodegradable blends with diverse compositions of polylactic acid, polycaprolactone, and compatibilizer
Bavaliya, K. J., Raj, M., Raj, L., & Vala, N. S. (2025) · International Journal of Polymer Analysis and Characterization · doi:10.1080/1023666x.2025.2585883
Synergistic triple-engineering of biodegradable PLA-based systems: Enhanced toughness, thermostability and degradation performance
Xu, Z., Yu, L., Gao, G., Jing, Y., Chi, W., Leng, S., Li, Y., Hao, Y., Wang, Y., & Song, L. (2026) · Sustainable materials and technologies · doi:10.1016/j.susmat.2026.e01920
Synergistic flame retardancy and mechanical reinforcement of bio-based PLA composites using polyphenol-assisted ammonium polyphosphate and sugarcane fiber
Xue, B., Wei, D., Li, J., Wang, Y., Pan, H., & Wang, W. (2026) · Journal of Thermoplastic Composite Materials · doi:10.1177/08927057261436060
Mechanochemical assembly of polymer-cyclodextrin inclusion complexes via twin-screw extrusion for large-scale production and material reinforcement
Shi, J., Mou, X., Tang, H., Gong, L., Wu, H., Wahrhaftig‐Lewis, A., Hansberg, B., Schrettl, S., Champness, N. R., Guldin, S., et al. (2026) · Chemical Communications · doi:10.1039/d6cc00830e
Designing robust, antimicrobial and UV-shielding poly(lactic acid) nanocomposites by multi-functional nanochitin via surface chemistry: Preparation and food packaging application
Yang, T., Li, R., Ding, M., Zhang, L., & Xie, H. (2026) · Composites Part B Engineering · doi:10.1016/j.compositesb.2026.114055
The Influence of the Content of Polybutylene Adipate‐Co‐Butylene Terephthalate‐Based Polyurethane Prepolymer on the Structure and Properties of PBAT ‐Based Composite Materials
Jian, K., Tang, W., Weng, F., Wu, Z., & Wu, Q. (2026) · Polymer Composites · doi:10.1002/pc.71555
Tailoring the Morphology and Properties of Stereocomplex‐Type Porous Poly(Lactic Acid) Materials via Poly(ε‐Caprolactone) Incorporation
Li, L., 王庆杰, Ma, W., Zhou, X., Chen, Y., & Wu, H. (2026) · Polymer Engineering and Science · doi:10.1002/pen.70977
Reactive Compatibilization of Bio-Based PLA/PEF Blends for Recoverable 4D-Printed Architectures
Chen, B., Wang, L., Wang, Y., Li, M., Mu, D., & Sang, L. (2026) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.6c08392

Impact behavior of PLA/PCL bioblends
Albiter, N. L., Abt, T., Hortos Llobera, M., Espino, S., Pérez, O. O. S., & Rulduà, M. L. M. (2020) · UPCommons institutional repository (Universitat Politècnica de Catalunya)
Phase Structure, Compatibility, and Toughness of PLA/PCL Blends: A Review
Fortelny, I., Ujcic, A., Fambri, L., & Slouf, M. (2019) · Frontiers in Materials · doi:10.3389/fmats.2019.00206 · Cited by 238 · see citing works
Mechanical and Morphological Behavior of Blends Obtained from Biopolymers (PLA/PLC)
Silva, T. R. D. G., da Cunha, B. B., Agrawal, P., Araújo, E. M., & de Mélo, T. J. A. (2014) · Materials science forum · doi:10.4028/www.scientific.net/msf.775-776.24 · Cited by 1 · see citing works
Improved Toughness of Polylactide by Binary Blends with Polycarbonate with Glycidyl and Maleic Anhydride‐Based Compatibilizers
Oliveros, R. T., Gómez-Caturla, J., Sánchez‐Nacher, L., Muñoz, N. M., & Quiles‐Carrillo, L. (2021) · Macromolecular Materials and Engineering · doi:10.1002/mame.202100480 · Cited by 23 · see citing works
Balanced strength and toughness improvement in polylactide (PLA)/poly(1,4-cyclohexylene dimethylene terephthalate glycol) (PCTG) blends using various compatibilizers
Song, H.-J., Chen, X.-D., Fan, J., & Xu, Q. (2019) · Iranian Polymer Journal · doi:10.1007/s13726-019-00763-x · Cited by 12 · see citing works

Authors: Fernández‐Tena, A., Otaegi, I., Irusta, L., Sebastián, V., Guerrica‐Echevarria, G., Müller, A. J., & Aranburu, N.
Affiliations: University of the Basque Country (ES)
Department of Chemical and Environmental Engineering. University of Zaragoza Campus Río Ebro‐Edificio I+D C/ Poeta Mariano Esquillor S/N Zaragoza 50018 Spain
POLYMAT and Department of Advanced Polymers and Materials: Physics Chemistry and Technology Faculty of Chemistry University of the Basque Country UPV/EHU Paseo Manuel de Lardizabal 3 Donostia‐San Sebastián 20018 Spain
Ikerbasque (ES)
Corresponding author: Aranburu, Nora
ORCID: Fernández‐Tena, Ainhoa
Otaegi, Itziar
Irusta, Lourdes
Sebastián, Victor
Guerrica‐Echevarria, Gonzalo
Müller, Alejandro Jesus
Aranburu, Nora
Venue: Macromolecular Materials and Engineering
Publisher: Wiley
Published: 2023-09-22
Volume: 308
Issue: 12
ISSN: 1438-7492 (ISSN-L)
1439-2054
DOI: 10.1002/mame.202300213
OpenAlex: W4386967143
Cited by: 34
References: 50
Citations by year: 2026: 13 · 2025: 17 · 2024: 4
FWCI: 2.18
Type: journal article
Language: en
Open access: gold
doi.org
Licence: cc-by
creativecommons.org/licenses/by/4.0/ (vor)
Locations: Macromolecular Materials and Engineering (publishedVersion, cc-by)
Zaguan (University of Zaragoza Repository) (submittedVersion, cc-by)
Communities in ADDI (University of the Basque Country) (submittedVersion, cc-by)
DIGITAL.CSIC (Spanish National Research Council (CSIC)) (submittedVersion, cc-by)
DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Hispana (submittedVersion, cc-by)
Funders: Eusko Jaurlaritza (IT1503‐22)
Ministerio de Ciencia e Innovación (PID2021‐127847OB‐I00)
Topics: Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
Keywords: polylactic acid, polycaprolactone, PLA/PCL blends, compatibilization, impact strength, glycidyl methacrylate, blend composition, toughening, ductility, biodegradable polymers

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High-Impact PLA in Compatibilized PLA/PCL Blends: Optimization of Blend Composition and Type and Content of Compatibilizer

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