Cited by 28CO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysisCatalysts for Methane Reforming

Electrocatalytic conversion of carbon dioxide to fuels: a review on the interaction between CO2 and the liquid electrolyte

Sharma, Pranav P., Zhou, Xiao‐Dong·2017·WIREs Energy and Environment

Abstract

The electrochemical reduction of carbon dioxide using renewable energy resources can potentially accomplish the carbon‐neutral energy cycle while synthesizing fuels simultaneously. CO 2 electrocatalysis typically requires the presence of protons in a liquid electrolyte, which acts as a possible cocatalyst for CO 2 conversion to fuels. However, the following fundamental questions remain: (1) How does the interaction between CO 2 and liquid electrolyte influence CO 2 electrocatalysis? (2) How does the selectivity toward products from CO 2 reduction depend upon the choice of electrolyte? In this review article, we emphasize on the interaction between CO 2 and the liquid electrolyte, in order to find answers to these questions. Specifically, the nature of interactions along with the structures of solvated molecules for CO 2 in water, organic solvents and ionic liquids are discussed. Finally, relevant questions are proposed which need to be studied carefully in order to gain a deeper understanding of CO 2 electrocatalysis. WIREs Energy Environ 2017, 6:e239. doi: 10.1002/wene.239 This article is categorized under: Fuel Cells and Hydrogen > Climate and Environment

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Authors
Sharma, P. P., & Zhou, X.
Affiliations
University of South Carolina (US)
Corresponding author
Zhou, Xiao‐Dong
Venue
WIREs Energy and Environment
Publisher
Wiley
Published
2017-02
Volume
6
Issue
4
ISSN
  • 2041-8396 (ISSN-L)
  • 2041-840X
OpenAlex
W2584529048
Cited by
28
References
114
Citations by year
2024: 1 · 2023: 1 · 2022: 4 · 2021: 3 · 2020: 6 · 2019: 8 · 2018: 4 · 2017: 1
FWCI
1.39
Type
journal article
Language
en
Open access
closed
Locations
Wiley Interdisciplinary Reviews Energy and Environment (publishedVersion)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
  • Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords
electrochemical CO2 reduction, CO2 electrocatalysis, liquid electrolytes, product selectivity, ionic liquids, organic solvents, water, renewable energy

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