Electrocatalytic conversion of carbon dioxide to fuels: a review on the interaction between CO2 and the liquid electrolyte
Abstract
The electrochemical reduction of carbon dioxide using renewable energy resources can potentially accomplish the carbon‐neutral energy cycle while synthesizing fuels simultaneously. CO 2 electrocatalysis typically requires the presence of protons in a liquid electrolyte, which acts as a possible cocatalyst for CO 2 conversion to fuels. However, the following fundamental questions remain: (1) How does the interaction between CO 2 and liquid electrolyte influence CO 2 electrocatalysis? (2) How does the selectivity toward products from CO 2 reduction depend upon the choice of electrolyte? In this review article, we emphasize on the interaction between CO 2 and the liquid electrolyte, in order to find answers to these questions. Specifically, the nature of interactions along with the structures of solvated molecules for CO 2 in water, organic solvents and ionic liquids are discussed. Finally, relevant questions are proposed which need to be studied carefully in order to gain a deeper understanding of CO 2 electrocatalysis. WIREs Energy Environ 2017, 6:e239. doi: 10.1002/wene.239 This article is categorized under: Fuel Cells and Hydrogen > Climate and Environment
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Larger cations Cs+ and K+ can greatly increase the total current density in CO2RR.
“Studies have demonstrated that larger cations, Cs + and K + , can greatly increase the total current density, [209,210]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [210]
Larger cation concentrations can greatly reduce charge transfer resistances by helping to stabilize the *CO2- anion radical and leading to higher current densities at the same applied potentials.
“Moreover, larger cation concentrations can greatly reduce charge transfer resistances by helping to stabilize the *CO2 -anion radical and leading to higher current densities at the same applied potentials.[190,210,211]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [210]
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- Authors
- Sharma, P. P., & Zhou, X.
- Affiliations
- University of South Carolina (US)
- Corresponding author
- Zhou, Xiao‐Dong
- ORCID
- Zhou, Xiao‐Dong
- Venue
- WIREs Energy and Environment
- Publisher
- Wiley
- Published
- 2017-02
- Volume
- 6
- Issue
- 4
- ISSN
- 2041-8396 (ISSN-L)
- 2041-840X
- OpenAlex
- W2584529048
- Cited by
- 28
- References
- 114
- Citations by year
- 2024: 1 · 2023: 1 · 2022: 4 · 2021: 3 · 2020: 6 · 2019: 8 · 2018: 4 · 2017: 1
- FWCI
- 1.39
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Wiley Interdisciplinary Reviews Energy and Environment (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, CO2 electrocatalysis, liquid electrolytes, product selectivity, ionic liquids, organic solvents, water, renewable energy
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