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Cited by 19High-Temperature Coating BehaviorsHigh Temperature Alloys and CreepMetallurgical Processes and Thermodynamics

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Strategies for High-Temperature Corrosion Simulations of Fe-Based Alloys Using the Calphad Approach: Part I

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Bigdeli, Sedigheh, Kjellqvist, Lina, Naraghi, Reza, Höglund, Lars, Larsson, Henrik, Jonsson, Torbjörn·2021·Journal of Phase Equilibria and Diffusion
DOI 10.1007/s11669-021-00893-x
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Abstract

The environmental degradation of materials at high temperatures limits the useful life of different industrial components and hinders the development of more economical and environmentally friendly processes for the energy production. Despite the importance of this phenomena, a model to predict lifetime of materials that degrade due to high-temperature corrosion has up till now been lacking due to limitations of the computational possibilities and the complex nature of oxidation. In the present work we develop some strategies to model high-temperature corrosion in Fe-based alloys using the Calphad (Calculation of Phase Diagrams) approach. It is proposed that kinetic-based simulations for oxidation of Al and Cr can accurately represent the lifetime of the protective layers in FeCrAl and FeCr alloys at different temperatures in air. The oxide systems are in addition investigated by equilibrium calculations. The corrosion mechanisms of FeCr and FeCrAl alloys are discussed based on theoretical and experimental knowledge.

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  • The primary corrosion protection of FeCrAl alloys ((Al,Cr)2O3) acts similar to the Cr-rich type of oxide scale at intermediately high temperatures, e.g. 600°C.

    “The results from this study also indicate that the primary corrosion protection of FeCrAl alloys ((Al,Cr) 2 O 3 ) act similar to the Cr-rich type of oxide scale at intermediately high temperatures, e.g.600 • C, in good agreement with recent investigations [35,40].”

    From Beyond breakaway corrosion – Influence of chromium, nickel and aluminum on corrosion of iron-based alloys at 600 °C (2020) · cites this paper as [40]

    Section 2.2.3 says an oxide with properties similar to the protective Cr-rich scale forms on FeCrAl alloys at 600 °C, and proposes that Cr oxidation provides their oxidation resistance at that temperature. But Section 2.1 says the thin scale’s microstructure is not well characterized and reports only a small amount of Al in it; the paper does not establish the claimed (Al,Cr)₂O₃ composition. (LLM, conf=0.86)

    Experimental — accuracy not yet measured

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Metadata

Authors
Bigdeli, S., Kjellqvist, L., Naraghi, R., Höglund, L., Larsson, H., & Jonsson, T.
Affiliations
  • Chalmers University of Technology (SE)
  • KTH Royal Institute of Technology (SE)
Corresponding author
Bigdeli, Sedigheh
ORCID
Venue
Journal of Phase Equilibria and Diffusion
Publisher
Springer Science and Business Media LLC
Published
2021-06
Volume
42
Issue
3
Pages
403-418
ISSN
  • 1547-7037 (ISSN-L)
  • 1863-7345
DOI
10.1007/s11669-021-00893-x
OpenAlex
W3174045733
Cited by
19
References
5
Citations by year
2026: 3 · 2025: 7 · 2024: 3 · 2023: 2 · 2022: 4
FWCI
1.13
Type
journal article
Language
en
Open access
Licence
Locations
  • Journal of Phase Equilibria and Diffusion (publishedVersion, cc-by)
  • Chalmers Research (Chalmers University of Technology) (submittedVersion, cc-by)
Funders
Chalmers University of Technology
Topics
  • Physical Sciences › Materials Science › Surfaces, Coatings and Films › High-Temperature Coating Behaviors
  • Physical Sciences › Engineering › Mechanical Engineering › High Temperature Alloys and Creep
  • Physical Sciences › Materials Science › Metals and Alloys › Metallurgical Processes and Thermodynamics
Keywords
high-temperature corrosion, iron alloys, FeCrAl alloys, Fe-Cr alloys, oxidation kinetics, aluminum oxidation, chromium oxidation, protective oxide scale, lifetime prediction, corrosion mechanism

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