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Chain-end scission in acid catalyzed hydrolysis of poly (d,l-lactide) in solution
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“Although the two mechanisms operate simultaneously during hydrolysis, several studies have found that the chainend scission is significantly faster than the random backbone cleavage.424,426,427”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [426]
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Metadata
- Authors
- Shih, C.
- Affiliations
- Merck & Co., Inc., Rahway, NJ, USA (United States) (US)
- Corresponding author
- Shih, Chung
- Venue
- Journal of Controlled Release
- Publisher
- Elsevier BV
- Published
- 1995-04
- Volume
- 34
- Issue
- 1
- Pages
- 9-15
- ISSN
- 0168-3659 (ISSN-L)
- OpenAlex
- W2038798099
- Cited by
- 159
- References
- 13
- Citations by year
- 2026: 5 · 2025: 8 · 2024: 7 · 2023: 2 · 2022: 11 · 2021: 8 · 2020: 4 · 2019: 5 · 2018: 2 · 2017: 6 · 2016: 3 · 2015: 5 · 2014: 6 · 2013: 6 · 2012: 6
- FWCI
- 3.92
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Controlled Release (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Biomaterials › Hydrogels: synthesis, properties, applications
- Life Sciences › Pharmacology, Toxicology and Pharmaceutics › Pharmaceutical Science › Advanced Drug Delivery Systems
- Keywords
- poly(D,L-lactide), acid hydrolysis, polymer degradation kinetics, polycaprolactone, deuterium labeling, autocatalysis
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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