Cited by 184biodegradable polymer synthesis and propertiesThermal and Kinetic AnalysisPolymer Science and PVC

Kinetics of the hydrolytic degradation of poly(lactic acid)

Codari, F., Lazzari, S., Soos, M., Storti, G., Morbidelli, M., Moscatelli, D.·2012·Polymer Degradation and Stability

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Crossref · 10.1016/j.polymdegradstab.2012.06.026

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31 of 31 references verified0 citation errors · 0 not checkable

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  • Although the two mechanisms operate simultaneously during hydrolysis, several studies have found that the chain-end scission is significantly faster than the random backbone cleavage.

    “Although the two mechanisms operate simultaneously during hydrolysis, several studies have found that the chainend scission is significantly faster than the random backbone cleavage.424,426,427”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [424]

  • At acidic pH the hydrolysis proceeds through a preferential scission of the end groups and spits out one lactic acid unit at a time, while the base catalyzed hydrolysis proceeds preferentially via a backbiting process from the OH chain end leading to the formation of lactide, which is eventually hydrolyzed to lactate.

    “While at acidic pH the hydrolysis proceeds through a preferential scission of the end groups and spits out one lactic acid unit at a time, the base catalyzed hydrolysis proceeds preferentially via a backbiting process from the OH chain end leading to the formation of lactide, which is eventually hydrolyzed to lactate.”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [424]

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Authors
Codari, F., Lazzari, S., Soos, M., Storti, G., Morbidelli, M., & Moscatelli, D.
Affiliations
  • ETH Zurich (CH)
  • Politecnico di Milano (IT)
Corresponding author
Moscatelli, D.
Venue
Polymer Degradation and Stability
Publisher
Elsevier BV
Published
2012-11
Volume
97
Issue
11
Pages
2460-2466
ISSN
0141-3910 (ISSN-L)
OpenAlex
W1987117221
Cited by
184
References
32
Citations by year
2026: 24 · 2025: 21 · 2024: 12 · 2023: 11 · 2022: 17 · 2021: 17 · 2020: 18 · 2019: 10 · 2018: 12 · 2017: 10 · 2016: 12 · 2015: 3 · 2014: 12 · 2013: 5
FWCI
2.59
Type
journal article
Language
en
Open access
closed
Locations
Polymer Degradation and Stability (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer Science and PVC
Keywords
polylactic acid, hydrolytic degradation, hydrolysis kinetics, kinetic model, activation energy, steric effects, crystallinity, water diffusion

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