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Modification of bio-char derived from fast pyrolysis of biomass and its application in removal of tetracycline from aqueous solution
Abstract
In this work, bio-char, a mass productive by-product of biomass fast pyrolysis, was adopted as an adsorbent to remove tetracycline (TC) from aqueous solution. To enhance the adsorption capacity, a simple modification of bio-char with acid and alkali was carried out. Bio-char samples were characterized by Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption-desorption isotherm. The results show that the alkali treated bio-char possesses larger surface area than those of raw and acid treated bio-chars, and accordingly exhibits a more excellent adsorption performance (58.8 mg/g) than the other two bio-chars and other adsorbents reported previously. The graphite-like structure of bio-char facilitates the formation of π-π interactions between ring structure in tetracycline molecule and graphite-like sheets. The surface area showed significant effects on TC adsorption as well as O-containing functional groups, whereas the initial pH of solution has small effects on TC adsorption under the experimental conditions.
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“The effect of pH during BC removal of TC was neglect (Liu etal. 2012), and the strong π -π interaction was the main mechanism in this adsorption process.”
From Review of organic and inorganic pollutants removal by biochar and biochar-based composites (2021) · cites this paper as Liu et al. (2012)
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Luo, Y., Zheng, A., Li, J., Han, Y., Xue, M., Zhang, L., Yin, Z., Xie, C., Chen, Z., Ji, L., et al. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.141228 · Cited by 169
Metadata
- Authors
- Liu, P., Liu, W.-J., Jiang, H., Chen, J.-J., Li, W.-W., & Yu, H.-Q.
- Affiliations
- University of Science and Technology of China (CN)
- Corresponding author
- Jiang, Hong
- Venue
- Bioresource Technology
- Publisher
- Elsevier BV
- Published
- 2012-10
- Volume
- 121
- Pages
- 235-240
- ISSN
- 0960-8524 (ISSN-L)
- OpenAlex
- W2130579737
- Cited by
- 643
- References
- 36
- Citations by year
- 2026: 20 · 2025: 23 · 2024: 64 · 2023: 66 · 2022: 78 · 2021: 74 · 2020: 73 · 2019: 63 · 2018: 41 · 2017: 54 · 2016: 41 · 2015: 23 · 2014: 13 · 2013: 9 · 2012: 1
- FWCI
- 13.34
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Bioresource Technology (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China
- Fundamental Research Funds for the Central Universities
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
- Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
- Keywords
- biochar, tetracycline removal, adsorption, acid and alkali treatment, surface area, π-π stacking, graphite-like structure, antibiotic removal from water, pH effect
- MeSH terms
- Adsorption, Charcoal, Hot Temperature, Nitrogen, Tetracycline, Water Pollutants, Chemical, Spectroscopy, Fourier Transform Infrared, Water Purification, Biomass, Photoelectron Spectroscopy
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