Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 552

The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.

Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities

Open access
Satlewal, Alok, Agrawal, Ruchi, Bhagia, Samarthya, Sangoro, Joshua, Ragauskas, Arthur J.·2018·Biotechnology Advances
DOI 10.1016/j.biotechadv.2018.08.009
Open this paper in CoChat — free account

Abstract

Conversion of lignocellulosic biomass to fuels and chemicals has attracted immense research and development around the world. Lowering recalcitrance of biomass in a cost-effective manner is a challenge to commercialize biomass-based technologies. Deep eutectic solvents (DESs) are new 'green' solvents that have a high potential for biomass processing because of their low cost, low toxicity, biodegradability, easy recycling and reuse. This article discusses the properties of DESs and recent advances in their application for lignocellulosic biomass processing. The effectiveness of DESs in hydrolyzing lignin-carbohydrate complexes, removing lignin/hemicellulose from biomass as well as their effect on biomass deconstruction, crystallinity and enzymatic digestibility have been discussed. Moreover, this review presents recent findings on the compatibility of natural DESs with enzymes and microorganisms.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1016/j.biotechadv.2018.08.009

Cites

10 of 10 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 10 references

Research works printed but not linked: 107

  1. Abo-Hamad, 2015, Potential applications of deep eutectic solvents in nanotechnology, Chem. Eng. J., 273, 551, 10.1016/j.cej.2015.03.091 · DOI · Paper page
  2. Agrawal, 2015, Improved saccharification of pilot-scale acid pretreated wheat straw by exploiting the synergistic behavior of lignocellulose degrading enzymes, RSC Adv., 5, 71462, 10.1039/C5RA13360B · DOI
  3. Agrawal, 2015, Pilot scale pretreatment of wheat straw and comparative evaluation of commercial enzyme preparations for biomass saccharification and fermentation, Biochem. Eng. J., 102, 54, 10.1016/j.bej.2015.02.018 · DOI
  4. Agrawal, 2016, Application of nanoparticle-immobilized thermostable β-glucosidase for improving the sugarcane juice properties, Innov. Food Sci. Emerg. Technol., 33, 472, 10.1016/j.ifset.2015.11.024 · DOI
  5. Agrawal, 2017, Investigating the enzyme-lignin binding with surfactants for improved saccharification of pilot scale pretreated wheat straw, Bioresour. Technol., 224, 411, 10.1016/j.biortech.2016.11.026 · DOI
  6. Agrawal, 2017, Induction of cellulases by disaccharides or their derivatives in Penicillium janthinellum EMS-UV-8 mutant, Biofuels, 8, 615, 10.1080/17597269.2016.1242692 · DOI
  7. Akinosho, 2015, Toxicological challenges to microbial bioethanol production and strategies for improved tolerance, Ecotoxicology, 24, 2156, 10.1007/s10646-015-1543-4 · DOI
  8. Alomar, 2016, Glycerol-based deep eutectic solvents: Physical properties, J. Mol. Liq., 215, 98, 10.1016/j.molliq.2015.11.032 · DOI
  9. Alvarez-Vasco, 2016, Unique low-molecular-weight lignin with high purity extracted from wood by deep eutectic solvents (DES): a source of lignin for valorization, Green Chem., 18, 5133, 10.1039/C6GC01007E · DOI
  10. Azizi, 2012, Highly efficient deep eutectic solvent catalyzed ring opening of epoxides, Catal. Sci. Technol., 2, 2445, 10.1039/c2cy20456h · DOI
  11. Azizi, 2012, A highly efficient synthesis of dithiocarbamates in green reaction media, RSC Adv., 2, 7413, 10.1039/c2ra20615c · DOI
  12. Azizi, 2012, Eutectic salts promote green synthesis of bis(indolyl) methanes, Res. Chem. Intermed., 38, 1495, 10.1007/s11164-011-0479-4 · DOI
  13. Azizi, 2012, Deep eutectic solvent promoted highly efficient synthesis of N, N'-diarylamidines and formamides, Compt. Rend. Chim., 15, 768, 10.1016/j.crci.2012.06.011 · DOI
  14. Azizi, 2013, A sustainable approach to the Ugi reaction in deep eutectic solvent, Compt. Rend. Chim., 16, 1098, 10.1016/j.crci.2013.05.013 · DOI
  15. Azizi, 2014, Greener synthesis of spirooxindole in deep eutectic solvent, J. Mol. Liq., 194, 62, 10.1016/j.molliq.2014.01.009 · DOI
  16. Bhagia, 2016, Flowthrough pretreatment with very dilute acid provides insights into high lignin contribution to biomass recalcitrance, Biotechnol. Biofuels, 9, 245, 10.1186/s13068-016-0660-5 · DOI
  17. Calderon Morales, 2004, The regiospecific Fischer indole reaction in choline chloride.2ZnCl2 with product isolation by direct sublimation from the ionic liquid, Chem. Commun. (Camb), 158, 10.1039/B313655H · DOI
  18. Capolupo, 2016, Green methods of lignocellulose pretreatment for biorefinery development, Appl. Microbiol. Biotechnol., 100, 9451, 10.1007/s00253-016-7884-y · DOI · Paper page
  19. Chen, 2017, Mixing cations with different alkyl chain lengths markedly depresses the melting point in deep eutectic solvents formed from alkylammonium bromide salts and urea, Chem. Commun., 53, 2375, 10.1039/C7CC00201G · DOI
  20. De Santi, 2012, Novel Brønsted acidic deep eutectic solvent as reaction media for esterification of carboxylic acid with alcohols, Tetrahedron Lett., 53, 5151, 10.1016/j.tetlet.2012.07.063 · DOI
  21. Den, 2018, Lignocellulosic biomass transformations via greener oxidative pretreatment processes: access to energy and value-added chemicals, Front. Chem., 6
  22. Disale, 2012, Choline chloride·2ZnCl2 ionic liquid: an efficient and reusable catalyst for the solvent free Kabachnik–Fields reaction, Tetrahedron Lett., 53, 2277, 10.1016/j.tetlet.2012.02.054 · DOI
  23. Domínguez De María, 2014, Recent trends in (ligno)cellulose dissolution using neoteric solvents: switchable, distillable and bio-based ionic liquids, J. Chem. Technol. Biotechnol., 89, 11, 10.1002/jctb.4201 · DOI
  24. Duan, 2006, Green and moisture-stable Lewis acidic ionic liquids (choline chloride·xZnCl2) catalyzed protection of carbonyls at room temperature under solvent-free conditions, Catal. Commun., 7, 651, 10.1016/j.catcom.2006.02.008 · DOI
  25. Dumitrache, 2017, Cellulose and lignin colocalization at the plant cell wall surface limits microbial hydrolysis of Populus biomass, Green Chem., 19, 2275, 10.1039/C7GC00346C · DOI
  26. Dutta, 2018, Characterization of lignin streams during bionic liquid-based pretreatment from grass, hardwood, and softwood, ACS Sustain. Chem. Eng., 6, 3079, 10.1021/acssuschemeng.7b02991 · DOI
  27. Fang, 2017, Reviving pretreatment effectiveness of deep eutectic solvents on lignocellulosic date palm residues by prior recalcitrance reduction, Ind. Eng. Chem. Res., 56, 3167, 10.1021/acs.iecr.6b04733 · DOI
  28. Fu, 2010, Lignin extraction from straw by ionic liquids and enzymatic hydrolysis of the cellulosic residues, J. Agric. Food Chem., 58, 10.1021/jf903616y · DOI · Paper page
  29. Gore, 2012, Fischer indole synthesis in low melting mixtures, Org. Lett., 14, 4568, 10.1021/ol302034r · DOI
  30. Gorke, 2008, Hydrolase-catalyzed biotransformations in deep eutectic solvents, Chem. Commun., 10.1039/b716317g · DOI
  31. Griffin, 2014, Charge transport and structural dynamics in carboxylic-acid-based deep eutectic mixtures, J. Phys. Chem. B, 118, 9378, 10.1021/jp503105g · DOI
  32. Gunny, 2015, Applicability evaluation of Deep Eutectic Solvents–Cellulase system for lignocellulose hydrolysis, Bioresour. Technol., 181, 297, 10.1016/j.biortech.2015.01.057 · DOI
  33. Haerens, 2010, Challenges for recycling ionic liquids by using pressure driven membrane processes, Green Chem., 12, 2182, 10.1039/c0gc00406e · DOI
  34. Handy, 2013, Organic synthesis in deep eutectic solvents: Paal–Knorr reactions, Tetrahedron Lett., 54, 4377, 10.1016/j.tetlet.2013.05.122 · DOI
  35. Handy, 2014, A mild synthesis of bis(indolyl)methanes using a deep eutectic solvent, Tetrahedron Lett., 55, 4969, 10.1016/j.tetlet.2014.07.024 · DOI
  36. Handy, 2014, An acid-free Pictet–Spengler reaction using deep eutectic solvents (DES), Tetrahedron Lett., 55, 3440, 10.1016/j.tetlet.2014.04.077 · DOI
  37. Hashmi, 2017, Comparison of autohydrolysis and ionic liquid 1-butyl-3-methylimidazolium acetate pretreatment to enhance enzymatic hydrolysis of sugarcane bagasse, Bioresour. Technol., 224, 714, 10.1016/j.biortech.2016.10.089 · DOI
  38. Hayyan, 2013, Glucose-based deep eutectic solvents: Physical properties, J. Mol. Liq., 178, 137, 10.1016/j.molliq.2012.11.025 · DOI
  39. Hayyan, 2013, Assessment of cytotoxicity and toxicity for phosphonium-based deep eutectic solvents, Chemosphere, 93, 455, 10.1016/j.chemosphere.2013.05.013 · DOI · Paper page
  40. Hou, 2012, Novel renewable ionic liquids as highly effective solvents for pretreatment of rice straw biomass by selective removal of lignin, Biotechnol. Bioeng., 109, 2484, 10.1002/bit.24522 · DOI · Paper page
  41. Hou, 2013, Facile and simple Pretreatment of Sugar Cane Bagasse without size Reduction using Renewable Ionic Liquids–Water Mixtures, ACS Sustain. Chem. Eng., 1, 519, 10.1021/sc300172v · DOI
  42. Hou, 2017, Significantly enhanced enzymatic hydrolysis of rice straw via a high-performance two-stage deep eutectic solvents synergistic pretreatment, Bioresour. Technol., 238, 139, 10.1016/j.biortech.2017.04.027 · DOI
  43. Hou, 2017, Significantly enhanced enzymatic hydrolysis of rice straw via a high-performance two-stage deep eutectic solvents synergistic pretreatment, Bioresour. Technol., 238, 139, 10.1016/j.biortech.2017.04.027 · DOI
  44. Hu, 2009, Direct conversion of inulin to 5-hydroxymethylfurfural in biorenewable ionic liquids, Green Chem., 11, 873, 10.1039/b822328a · DOI
  45. Imperato, 2005, Low-melting sugar-urea-salt mixtures as solvents for Diels-Alder reactions, Chem. Commun., 1170, 10.1039/B414515A · DOI
  46. Imperato, 2006, Low melting sugar-urea-salt mixtures as solvents for organic reactions-estimation of polarity and use in catalysis, Green Chem., 8, 1051, 10.1039/B603660K · DOI
  47. Jeong, 2015, Tailoring and recycling of deep eutectic solvents as sustainable and efficient extraction media, J. Chromatogr. A, 1424, 10, 10.1016/j.chroma.2015.10.083 · DOI · Paper page
  48. Karimi, 2016, A critical review of analytical methods in pretreatment of lignocelluloses: composition, imaging, and crystallinity, Bioresour. Technol., 200, 1008, 10.1016/j.biortech.2015.11.022 · DOI
  49. Lehmann, 2012, Reengineering CelA2 cellulase for hydrolysis in aqueous solutions of deep eutectic solvents and concentrated seawater, Green Chem., 14, 2719, 10.1039/c2gc35790a · DOI
  50. Lehmann, 2014, Ionic liquid and deep eutectic solvent-activated CelA2 variants generated by directed evolution, Appl. Microbiol. Biotechnol., 98, 5775, 10.1007/s00253-014-5771-y · DOI
  51. Li, 2013, Extraction desulfurization process of fuels with ammonium-based deep eutectic solvents, Green Chem., 15, 2793, 10.1039/c3gc41067f · DOI · Paper page
  52. Li, 2013, Highly efficient low melting mixture catalyzed synthesis of 1,8-dioxo-dodecahydroxanthene derivatives, Chin. J. Chem., 31, 757, 10.1002/cjoc.201300152 · DOI
  53. Li, 2016, Current understanding of the correlation of lignin structure with biomass recalcitrance, Front. Chem., 4, 45, 10.3389/fchem.2016.00045 · DOI · Paper page
  54. Li, 2018, The effect of ionic liquids pretreatment on the distribution and structure of alkali-soluble hemicelluloses from Eucalyptus, Sep. Purif. Technol., 191, 364, 10.1016/j.seppur.2017.08.058 · DOI
  55. Liszka, 2016, Switchable ionic liquids based on di-carboxylic acids for one-pot conversion of biomass to an advanced biofuel, Green Chem., 18, 4012, 10.1039/C6GC00657D · DOI
  56. Lobo, 2012, Bio-compatible eutectic mixture for multi-component synthesis: a valuable acidic catalyst for synthesis of novel 2,3-dihydroquinazolin-4(1H)-one derivatives, Catal. Commun., 27, 179, 10.1016/j.catcom.2012.07.020 · DOI
  57. Lobo, 2012, Deep eutectic solvents and glycerol: a simple, environmentally benign and efficient catalyst/reaction media for synthesis of N-aryl phthalimide derivatives, Green. Chem. Lett. Rev., 5, 487, 10.1080/17518253.2012.669500 · DOI
  58. Lobo, 2012, Lipase and deep eutectic mixture catalyzed efficient synthesis of thiazoles in water at room temperature, Catal. Lett., 142, 1369, 10.1007/s10562-012-0902-5 · DOI
  59. Loow, 2017, Potential use of deep eutectic solvents to facilitate lignocellulosic biomass utilization and conversion, Cellulose, 24, 3591, 10.1007/s10570-017-1358-y · DOI · Paper page
  60. Loow, 2018, Deep eutectic solvent and inorganic salt pretreatment of lignocellulosic biomass for improving xylose recovery, Bioresour. Technol., 249, 818, 10.1016/j.biortech.2017.07.165 · DOI
  61. Lores, 2017, Natural deep eutectic solvents in combination with ultrasonic energy as a green approach for solubilisation of proteins: application to gluten determination by immunoassay, Talanta, 162, 453, 10.1016/j.talanta.2016.10.078 · DOI · Paper page
  62. Lynam, 2017, Deep eutectic solvents' ability to solubilize lignin, cellulose, and hemicellulose; thermal stability; and density, Bioresour. Technol., 238, 684, 10.1016/j.biortech.2017.04.079 · DOI · Paper page
  63. Lynd, 2017, The grand challenge of cellulosic biofuels, Nat. Biotechnol., 35, 912, 10.1038/nbt.3976 · DOI
  64. Maugeri, 2014, Whole-cell biocatalysis in deep-eutectic-solvents/aqueous mixtures, ChemCatChem, 6, 1535, 10.1002/cctc.201400077 · DOI
  65. Mbous, 2017, Applications of deep eutectic solvents in biotechnology and bioengineering—promises and challenges, Biotechnol. Adv., 35, 105, 10.1016/j.biotechadv.2016.11.006 · DOI
  66. N., H.H., M., M.K., C., K.K.H., D., S.N, 2011, A facile, choline chloride/urea catalyzed solid phase synthesis of coumarins via Knoevenagel condensation, Org. Commun., 4, 26
  67. Nor, 2016, Deep Eutectic Solvent (DES) as a Pretreatment for Oil Palm empty Fruit Bunch (OPEFB) in sugar production, Procedia Chem., 18, 147, 10.1016/j.proche.2016.01.023 · DOI
  68. Oliveira, 2015, Contribution of deep eutectic solvents for biomass processing: opportunities, challenges, and limitations, ChemCatChem, 7, 1250, 10.1002/cctc.201500134 · DOI
  69. Pandey, 2017, Hydrogen bond donor/acceptor cosolvent-modified choline chloride-based deep eutectic solvents, J. Phys. Chem. B, 121, 4202, 10.1021/acs.jpcb.7b01724 · DOI
  70. Pawar, 2011, Environmentally benign and energy efficient methodology for condensation: an interesting facet to the classical Perkin reaction, Green Chem., 13, 2130, 10.1039/c0gc00712a · DOI
  71. Phadtare, 2010, Halogenation reactions in biodegradable solvent: efficient bromination of substituted 1-aminoanthra-9,10-quinone in deep eutectic solvent (choline chloride: urea), Green Chem., 12, 458, 10.1039/b923589b · DOI
  72. Phadtare, 2013, Greener protocol for one pot synthesis of coumarin styryl dyes, Dyes Pigments, 97, 105, 10.1016/j.dyepig.2012.12.001 · DOI
  73. Procentese, 2015, Deep eutectic solvent pretreatment and subsequent saccharification of corncob, Bioresour. Technol., 192, 31, 10.1016/j.biortech.2015.05.053 · DOI · Paper page
  74. Procentese, 2018, Deep eutectic solvents pretreatment of agro-industrial food waste, Biotechnol. Biofuels, 11, 37, 10.1186/s13068-018-1034-y · DOI
  75. Raj, 2016, Ionic liquid pretreatment of biomass for sugars production: driving factors with a plausible mechanism for higher enzymatic digestibility, Carbohydr. Polym., 149, 369, 10.1016/j.carbpol.2016.04.129 · DOI
  76. Ren, 2016, Synthesis of a novel allyl-functionalized deep eutectic solvent to promote dissolution of cellulose, Bioresources, 11, 8457, 10.15376/biores.11.4.8457-8469 · DOI
  77. Ren, 2016, The properties of choline chloride-based deep eutectic solvents and their performance in the dissolution of cellulose, Bioresources, 11, 5435, 10.15376/biores.11.2.5435-5451 · DOI
  78. Sanap, 2014, Eco-friendly and recyclable media for rapid synthesis of tricyanovinylated aromatics using biocatalyst and deep eutectic solvent, Catal. Commun., 49, 58, 10.1016/j.catcom.2014.01.031 · DOI
  79. Sarmad, 2017, Screening of deep eutectic solvents (DESs) as green CO2 sorbents: from solubility to viscosity, New J. Chem., 41, 290, 10.1039/C6NJ03140D · DOI
  80. Satlewal, 2018, Rice straw as a feedstock for biofuels: availability, recalcitrance, and chemical properties, Biofuels Bioprod. Biorefin., 12, 83, 10.1002/bbb.1818 · DOI
  81. Seidl, 2016, Pretreatment processes for lignocellulosic biomass conversion to biofuels and bioproducts, Curr. Opin. Green Sustain. Chem., 2, 48, 10.1016/j.cogsc.2016.09.003 · DOI
  82. Shahbaz, 2011, Prediction of deep eutectic solvents densities at different temperatures, Thermochim. Acta, 515, 67, 10.1016/j.tca.2010.12.022 · DOI
  83. Singh, 2011, Selective N-alkylation of aromatic primary amines catalyzed by bio-catalyst or deep eutectic solvent, Catal. Lett., 141, 178, 10.1007/s10562-010-0479-9 · DOI
  84. Singh, 2013, Ultrasound and deep eutectic solvent (DES): a novel blend of techniques for rapid and energy efficient synthesis of oxazoles, Ultrason. Sonochem., 20, 287, 10.1016/j.ultsonch.2012.06.003 · DOI
  85. Singh, 2015, Comparison of different biomass pretreatment techniques and their impact on chemistry and structure, Front. Energy. Res., 2
  86. Tang, 2013, Recent developments in deep eutectic solvents in chemical sciences, Monatsh. Chem., 144, 1427, 10.1007/s00706-013-1050-3 · DOI · Paper page
  87. Tian, 2017, A comparison of various lignin-extraction methods to enhance the accessibility and ease of enzymatic hydrolysis of the cellulosic component of steam-pretreated poplar, Biotechnol. Biofuels, 10, 157, 10.1186/s13068-017-0846-5 · DOI
  88. van Osch, 2017, Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation, PCCP, 19, 2636, 10.1039/C6CP07499E · DOI · Paper page
  89. Vidal, 2014, Introducing deep eutectic solvents to polar organometallic chemistry: chemoselective addition of organolithium and grignard reagents to ketones in air, Angew. Chem. Int. Ed., 53, 5969, 10.1002/anie.201400889 · DOI
  90. Vigier, 2015, Contribution of deep eutectic solvents for biomass processing: opportunities, challenges, and limitations, ChemCatChem, 7, 1250, 10.1002/cctc.201500134 · DOI
  91. Wahlstrom, 2016, Comparison of three deep eutectic solvents and 1-ethyl-3-methylimidazolium acetate in the pretreatment of lignocellulose: effect on enzyme stability, lignocellulose digestibility and one-pot hydrolysis, RSC Adv., 6, 68100, 10.1039/C6RA11719H · DOI
  92. Wang, 2016, Genetic modification of plant cell walls to enhance biomass yield and biofuel production in bioenergy crops, Biotechnol. Adv., 34, 997, 10.1016/j.biotechadv.2016.06.001 · DOI
  93. Xing, 2017, Green processing of lignocellulosic biomass and its derivatives in deep eutectic solvents, ChemSusChem, 10, 2696, 10.1002/cssc.201700457 · DOI · Paper page
  94. Xu, 2016, Transforming biomass conversion with ionic liquids: process intensification and the development of a high-gravity, one-pot process for the production of cellulosic ethanol, Energy Environ. Sci., 9, 1042, 10.1039/C5EE02940F · DOI
  95. Xu, 2016, Enhancing cellulose accessibility of corn stover by deep eutectic solvent pretreatment for butanol fermentation, Bioresour. Technol., 203, 364, 10.1016/j.biortech.2015.11.002 · DOI
  96. Xu, 2017, Recent progress on deep eutectic solvents in biocatalysis, Bioresour. Bioprocess., 4, 34, 10.1186/s40643-017-0165-5 · DOI
  97. Yadav, 2014, Room temperature ionic liquid choline chloride–oxalic acid: a versatile catalyst for acid-catalyzed transformation in organic reactions, J. Mol. Liq., 191, 137, 10.1016/j.molliq.2013.11.036 · DOI
  98. Yin, 2005, High regioselective diels-alder reaction of myrcene with acrolein catalyzed by zinc-containing ionic liquids, Adv. Synth. Catal., 347, 137, 10.1002/adsc.200404154 · DOI
  99. Yongzhuang, 2017, Efficient cleavage of lignin–carbohydrate complexes and ultrafast extraction of lignin oligomers from wood biomass by microwave-assisted treatment with deep eutectic solvent, ChemSusChem, 10, 1692, 10.1002/cssc.201601795 · DOI
  100. Yoo, 2017, Ionic liquids: Promising green solvents for lignocellulosic biomass utilization, Curr. Opin. Green. Sustain. Chem., 5, 5, 10.1016/j.cogsc.2017.03.003 · DOI · Paper page
  101. Zahn, 2017, Deep eutectic solvents: similia similibus solvuntur?, PCCP, 19, 4041, 10.1039/C6CP08017K · DOI
  102. Zhang, 2012, Green and Inexpensive Choline-Derived Solvents for Cellulose Decrystallization, Chem. Eur. J., 18, 1043, 10.1002/chem.201103271 · DOI
  103. Zhang, 2016, Facile pretreatment of lignocellulosic biomass using deep eutectic solvents, Bioresour. Technol., 219, 1, 10.1016/j.biortech.2016.07.026 · DOI · Paper page
  104. Zhu, 2007, Supported choline chloride/urea as a heterogeneous catalyst for chemical fixation of carbon dioxide to cyclic carbonates, Green Chem., 9, 169, 10.1039/B612164K · DOI
  105. Zhu, 2011, Direct nucleophilic substitution reaction of alcohols mediated by a zinc-based ionic liquid, Green Chem., 13, 1244, 10.1039/c0gc00763c · DOI
  106. Zulkefli, 2017, Pretreatment of oil palm trunk in deep eutectic solvent and optimization of enzymatic hydrolysis of pretreated oil palm trunk, Renew. Energy, 107, 36, 10.1016/j.renene.2017.01.037 · DOI
  107. Zuo, 2017, Green process for production of 5-hydroxymethylfurfural from carbohydrates with high purity in deep eutectic solvents, Ind. Crop. Prod., 99, 1, 10.1016/j.indcrop.2017.01.027 · DOI

Cited by

See all 552

Metadata

Authors
Satlewal, A., Agrawal, R., Bhagia, S., Sangoro, J., & Ragauskas, A. J.
Venue
Biotechnology Advances
Publisher
Elsevier BV
Published
2018-12
Volume
36
Issue
8
Pages
2032-2050
ISSN
0734-9750 (ISSN-L)
DOI
10.1016/j.biotechadv.2018.08.009
OpenAlex
W2892148100
Cited by
552
References
10
FWCI
15.95
Type
journal article
Language
en
Open access
bronze
Licence
Funders
  • Indian Oil R&D Centre
  • Department of Biotechnology
  • Indo-U.S. Science and Technology Forum
  • UT (DE-AC05-00OR22725)
  • U.S. Department of Energy (FWP ERKP752)
  • Biological and Environmental Research
  • National Science Foundation
  • Division of Chemistry (CHE-1753282)

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities. https://app.cochat.ai/papers/10.1016/j.biotechadv.2018.08.009
The paper
Satlewal, A., Agrawal, R., Bhagia, S., Sangoro, J., & Ragauskas, A. J. (2018). Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities. Biotechnology Advances. https://doi.org/10.1016/j.biotechadv.2018.08.009

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.