Recent developments in deep eutectic solvents in chemical sciences

Are deep eutectic solvents benign or toxic?

Hayyan, M., Hashim, M. A., Hayyan, A., Al-Saadi, M. A., AlNashef, I. M., Mirghani, M. E. S., & Saheed, O. K. (2013) · Chemosphere · doi:10.1016/j.chemosphere.2012.11.004 · Cited by 675 · see citing works

Deep eutectic solvents: A review of fundamentals and applications

Hansen, B. B., Spittle, S., Chen, B., Poe, D., Zhang, Y., Klein, J. M., Horton, A., Adhikari, L., Zelovich, T., Doherty, B. W., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00385 · Cited by 3,422 · see citing works

Basics and properties of deep eutectic solvents: a review

El Achkar, T., Greige-Gerges, H., & Fourmentin, S. (2021) · Environmental Chemistry Letters · doi:10.1007/s10311-021-01225-8 · Cited by 1,106 · see citing works

Evaluation of toxicity and biodegradability of choline chloride based deep eutectic solvents

Radošević, K., Cvjetko Bubalo, M., Gaurina Srček, V., Grgas, D., Landeka Dragičević, T., & Radojčić Redovniković, I. (2015) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2014.09.034 · Cited by 770 · see citing works

Extraction techniques with deep eutectic solvents

Cunha, S. C., & Fernandes, J. O. (2018) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2018.05.001 · Cited by 760 · see citing works

Application of deep eutectic solvents in analytical chemistry. A review

Shishov, A., Bulatov, A., Locatelli, M., Carradori, S., & Andruch, V. (2017) · Microchemical Journal · doi:10.1016/j.microc.2017.07.015 · Cited by 561 · see citing works

Application of deep eutectic solvents in the extraction and separation of target compounds from various samples

Tang, B., Zhang, H., & Row, K. H. (2015) · Journal of Separation Science · doi:10.1002/jssc.201401347 · Cited by 522 · see citing works

Green and Sustainable Solvents of the Future: Deep Eutectic Solvents

Prabhune, A., & Dey, R. (2023) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2023.121676 · Cited by 500 · see citing works

Enhanced extraction of bioactive natural products using tailor-made deep eutectic solvents: Application to flavonoid extraction from Flos sophorae

Nam, M. W., Zhao, J., Lee, M. S., Jeong, J. H., & Lee, J. (2015) · Green Chemistry · doi:10.1039/c4gc01556h · Cited by 467 · see citing works

Selected issues related to the toxicity of ionic liquids and deep eutectic solvents—a review

Kudłak, B., Owczarek, K., & Namieśnik, J. (2015) · Environmental Science and Pollution Research · doi:10.1007/s11356-015-4794-y · Cited by 379 · see citing works

Deep Eutectic Solvents for Pretreatment, Extraction, and Catalysis of Biomass and Food Waste

Kalhor, P., & Ghandi, K. (2019) · Molecules · doi:10.3390/molecules24224012 · Cited by 305 · see citing works

Natural deep eutectic solvents: cytotoxic profile

Hayyan, M., Mbous, Y. P., Looi, C. Y., Wong, W. F., Hayyan, A., Salleh, Z., & Mohd-Ali, O. (2016) · SpringerPlus · doi:10.1186/s40064-016-2575-9 · Cited by 301 · see citing works

Evaluation of toxicity and biodegradability for cholinium-based deep eutectic solvents

Juneidi, I., Hayyan, M., & Hashim, M. A. (2015) · RSC Advances · doi:10.1039/c5ra12425e · Cited by 286 · see citing works

Design, synthesis and properties of acidic deep eutectic solvents based on choline chloride

Cui, Y., Li, C., Yin, J., Li, S., Jia, Y., & Bao, M. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.04.052 · Cited by 238 · see citing works

Tailoring and recycling of deep eutectic solvents as sustainable and efficient extraction media

Jeong, K. M., Lee, M. S., Nam, M. W., Zhao, J., Jin, Y., Lee, D.-K., Kwon, S. W., Jeong, J. H., & Lee, J. (2015) · Journal of Chromatography A · doi:10.1016/j.chroma.2015.10.083 · Cited by 219 · see citing works

Deep eutectic liquid organic salt as a new solvent for liquid-phase microextraction and its application in ligandless extraction and preconcentraion of lead and cadmium in edible oils

Karimi, M., Dadfarnia, S., Shabani, A. M. H., Tamaddon, F., & Azadi, D. (2015) · Talanta · doi:10.1016/j.talanta.2015.07.021 · Cited by 182 · see citing works

Novel zwitterionic deep eutectic solvents from trimethylglycine and carboxylic acids: characterization of their properties and their toxicity

Cardellini, F., Tiecco, M., Germani, R., Cardinali, G., Corte, L., Roscini, L., & Spreti, N. (2014) · RSC Adv. · doi:10.1039/c4ra10628h · Cited by 140 · see citing works

Synthesis and application of magnetic deep eutectic solvents: novel solvents for ultrasound assisted liquid-liquid microextraction of thiophene

Khezeli, T., & Daneshfar, A. (2017) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2016.08.023 · Cited by 137 · see citing works

Air assisted emulsification liquid-liquid microextraction based on deep eutectic solvent for preconcentration of methadone in water and biological samples

Lamei, N., Ezoddin, M., & Abdi, K. (2017) · Talanta · doi:10.1016/j.talanta.2016.11.036 · Cited by 123 · see citing works

Deep eutectic solvent-based ultrasound-assisted dispersive liquid-liquid microextraction coupled with high-performance liquid chromatography for the determination of ultraviolet filters in water samples

Wang, H., Hu, L., Liu, X., Yin, S., Lu, R., Zhang, S., Zhou, W., & Gao, H. (2017) · Journal of Chromatography A · doi:10.1016/j.chroma.2017.07.073 · Cited by 118 · see citing works

New low viscous hydrophobic deep eutectic solvents in vortex-assisted liquid-liquid microextraction for the determination of phthalate esters from food-contacted plastics

Li, T., Song, Y., Li, J., Zhang, M., Shi, Y., & Fan, J. (2020) · Food Chemistry · doi:10.1016/j.foodchem.2019.125752 · Cited by 96 · see citing works

In situ decomposition of deep eutectic solvent as a novel approach in liquid-liquid microextraction

Shishov, A., Chromá, R., Vakh, C., Kuchár, J., Simon, A., Andruch, V., & Bulatov, A. (2019) · Analytica Chimica Acta · doi:10.1016/j.aca.2019.03.038 · Cited by 97 · see citing works

Deep eutectic solvent-mediated extraction for ligand-less preconcentration of lead and cadmium from environmental samples using magnetic nanoparticles

Karimi, M., Shabani, A. M. H., & Dadfarnia, S. (2016) · Microchimica Acta · doi:10.1007/s00604-015-1671-9 · Cited by 94 · see citing works

Ultrasound assisted deep eutectic solvent based on dispersive liquid liquid microextraction of arsenic speciation in water and environmental samples by electrothermal atomic absorption spectrometry

Zounr, R. A., Tuzen, M., & Khuhawar, M. Y. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.07.053 · Cited by 84 · see citing works

Deep eutectic solvent–based headspace single-drop microextraction for the quantification of terpenes in spices

Triaux, Z., Petitjean, H., Marchioni, E., Boltoeva, M., & Marcic, C. (2020) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-019-02317-9 · Cited by 77 · see citing works

Speciation of mercury in water and biological samples by eco-friendly ultrasound-assisted deep eutectic solvent based on liquid phase microextraction with electrothermal atomic absorption spectrometry

Thongsaw, A., Udnan, Y., Ross, G. M., & Chaiyasith, W. C. (2019) · Talanta · doi:10.1016/j.talanta.2019.01.018 · Cited by 73 · see citing works

A New Robust, Deep Eutectic-Based Floating Organic Droplets Microextraction Method for Determination of Lead in a Portable Syringe System Directly Couple with FAAS

Naeemullah, & Tuzen, M. (2019) · Talanta · doi:10.1016/j.talanta.2018.12.027 · Cited by 70 · see citing works

Deep eutectic solvent based magnetic nanofluid in the development of stir bar sorptive dispersive microextraction: an efficient hyphenated sample preparation for ultra-trace nitroaromatic explosives extraction in wastewater

Zarei, A. R., Nedaei, M., & Ghorbanian, S. A. (2017) · Journal of Separation Science · doi:10.1002/jssc.201700915 · Cited by 56 · see citing works

Are Deep Eutectic Solvents Useful in Chromatography? A Short Review

Płotka-Wasylka, J., Rutkowska, M., & de la Guardia, M. (2021) · Journal of Chromatography A · doi:10.1016/j.chroma.2021.461918 · Cited by 51 · see citing works

Purification of antibiotics from the millet extract using hybrid molecularly imprinted polymers based on deep eutectic solvents

Li, X., & Row, K. H. (2017) · RSC Advances · doi:10.1039/c7ra01059a · Cited by 48 · see citing works

Applications of Deep Eutectic Solvents in Sample Preparation and Extraction of Organic Molecules

Plastiras, O.-E., & Samanidou, V. (2022) · Molecules · doi:10.3390/molecules27227699 · Cited by 45 · see citing works

Deep eutectic solvents as green media for efficient extraction of terpene trilactones from <i>Ginkgo biloba</i> leaves

Su, E., Yang, M., Cao, J., Lu, C., Wang, J., & Cao, F. (2017) · Journal of Liquid Chromatography &amp; Related Technologies · doi:10.1080/10826076.2017.1309661 · Cited by 44 · see citing works

Application of deep eutectic solvent based magnetic colloidal gel for dispersive solid phase extraction of ultra-trace amounts of some nitroaromatic compounds in water samples

Zarei, A. R., Nedaei, M., & Ghorbanian, S. A. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.09.039 · Cited by 42 · see citing works

Preparation of chlorocholine chloride/urea deep eutectic solvent-modified silica and an examination of the ion exchange properties of modified silica as a Lewis adduct

Tang, B., Park, H. E., & Row, K. H. (2014) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-014-7817-5 · Cited by 37 · see citing works

Magnetic deep eutectic solvent-based ultrasound-assisted liquid-liquid microextraction for determination of hexanal and heptanal in edible oils followed by gas chromatography-flame ionization detection

Babaee, S., & Daneshfar, A. (2018) · Analytical Methods · doi:10.1039/c8ay01058g · Cited by 34 · see citing works

Molecular Dynamics Simulations, Solvatochromic Parameters, and Preferential Solvation in Aqueous Solutions of Ethaline, Ethylene Glycol, and Choline Chloride

Aryafard, M., Karimi, A., Harifi-Mood, A. R., & Minofar, B. (2020) · Journal of Chemical &amp; Engineering Data · doi:10.1021/acs.jced.0c00381 · Cited by 29 · see citing works