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Effect of cationic and anionic surfactants on the sorption and desorption of perfluorooctane sulfonate (PFOS) on natural sediments
Abstract
Sorption and desorption of PFOS at water-sediment interfaces were investigated in the presence of a cationic surfactant, cetyltrimethylammonium bromide (CTAB), and an anionic surfactant, sodium dodecylbenzene sulfonate (SDBS). CTAB remarkably enhanced the sorption of PFOS on the sediment. In contrast, the influence of SDBS to the sorption of PFOS was concentration dependent. Two contrasting factors were responsible for the phenomenon. One was the sorption of the surfactant itself to the sediment, which enhanced the sorption of PFOS. The other was the increase in solubility of PFOS caused by the adding of surfactants, which decreased the sorption of PFOS. SDBS had a much lower sorption capacity, but rather strong ability to increase the solubility of PFOS. High levels of SDBS remarkably reduced the sorption of PFOS on the sediment. These results imply that cationic and anionic surfactants may have contrast impacts on the distribution and transport of PFOS in the environment.
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Factors such as ionic strength, salt composition, pH, and presence of co-contaminants affect solid-phase adsorption of PFAS.
“This has been demonstrated for PFAS, wherein research has shown that factors such as ionic strength, salt composition, pH, and presence of co-contaminants affect solid-phase adsorption (Higgins and Luthy, 2006, Chen et al., 2009, Pan et al., 2009, Guelfo and Higgins, 2013, Zhao et al., 2014).”
From Assessing the potential contributions of additional retention processes to PFAS retardation in the subsurface (2018) · cites this paper as Pan et al., 2009
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“0 mg/L, which is within the range of 7–45 L/g (Brooke et al., 2004; Higgins and Luthy, 2006; Johnson et al., 2007).”
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Metadata
- Authors
- Pan, G., Jia, C., Zhao, D., You, C., Chen, H., & Jiang, G.
- Venue
- Environmental Pollution
- Publisher
- Elsevier BV
- Published
- 2009-01
- Volume
- 157
- Issue
- 1
- Pages
- 325-330
- ISSN
- 0269-7491
- Cited by
- 170
- References
- 3
- Language
- en
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