Confinement effects on the crystallization and SSA thermal fractionation of the PE block within PE-b-PS diblock copolymers
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In strongly segregated systems (high χN values, T_ODT > Tg > Tc), the phase segregated structure of the melt is preserved, but the amorphous block is in the glassy state, so crystallization of the crystalline block occurs under hard confinement.
“The phase segregated structure of the melt is preserved, but in this case, the amorphous block is in the glassy state, therefore the crystallization process of the crystalline block occurs under hard confinement (the same behaviour is observed for double crystalline diblock copolymers, once the first block crystallizes, the second one crystallizes under hard confinement) [ 101 , 104 , 105 , 108 ,”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [108]
Similar effects have been reported for miscible block copolymers such as polyethylene-b-poly(ethylene-alt-propylene), where a stronger dilution effect induced by amorphous poly(ethylene-alt-propylene) chains causes the need for much higher supercoolings to crystallize the PE block chains but at compositions close to 50 wt %.
“Similar effects have been reported for miscible block copolymers such as polyethyleneb -poly(ethylenealt -propylene), where a stronger dilution effect induced by amorphous poly(ethylenealt -propylene) chains causes the need for much higher supercoolings to crystallize the PE block chains but at compositions close to 50 wt %. 75,76”
From Crystallization Kinetics and Morphology of Biodegradable Double Crystalline PLLA- <i>b</i> -PCL Diblock Copolymers (2010) · cites this paper as [75]
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- Authors
- Lorenzo, A. T., Arnal, M. L., Müller, A. J., Boschetti de Fierro, A., & Abetz, V.
- Affiliations
- Universidad Simón Bolívar (VE)
- Corresponding author
- Müller, A.J.
- Venue
- European Polymer Journal
- Publisher
- Elsevier BV
- Published
- 2006-03
- Volume
- 42
- Issue
- 3
- Pages
- 516-533
- ISSN
- 0014-3057 (ISSN-L)
- OpenAlex
- W2066029160
- Cited by
- 75
- References
- 83
- Citations by year
- 2025: 4 · 2024: 2 · 2023: 1 · 2022: 3 · 2021: 5 · 2018: 2 · 2017: 4 · 2016: 3 · 2015: 6 · 2014: 2 · 2013: 6 · 2012: 6
- FWCI
- 4.65
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- European Polymer Journal (publishedVersion)
- Funders
- Deutsche Forschungsgemeinschaft
- Fondo Nacional de Ciencia Tecnología e Innovación
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- confined crystallization, polyethylene, fractional crystallization, thermal fractionation, lamellar thickness distribution, topological confinement, Gibbs-Thomson equation, homogeneous nucleation, heterogeneous nucleation, interfacial phenomena, microdomains, anionic polymerization, hydrogenated polybutadiene, lamellar crystals, block copolymer morphology
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