Cited by 76Polymer crystallization and propertiesBlock Copolymer Self-AssemblyAdvanced Polymer Synthesis and Characterization

Confinement effects on the crystallization and SSA thermal fractionation of the PE block within PE-b-PS diblock copolymers

Lorenzo, A.T., Arnal, M.L., Müller, A.J., Boschetti de Fierro, A., Abetz, V.·2006·European Polymer Journal

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Crossref · 10.1016/j.eurpolymj.2005.09.001

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  • In strongly segregated systems (high χN values, T_ODT > Tg > Tc), the phase segregated structure of the melt is preserved, but the amorphous block is in the glassy state, so crystallization of the crystalline block occurs under hard confinement.

    “The phase segregated structure of the melt is preserved, but in this case, the amorphous block is in the glassy state, therefore the crystallization process of the crystalline block occurs under hard confinement (the same behaviour is observed for double crystalline diblock copolymers, once the first block crystallizes, the second one crystallizes under hard confinement) [ 101 , 104 , 105 , 108 ,”

    From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [108]

  • Similar effects have been reported for miscible block copolymers such as polyethylene-b-poly(ethylene-alt-propylene), where a stronger dilution effect induced by amorphous poly(ethylene-alt-propylene) chains causes the need for much higher supercoolings to crystallize the PE block chains but at compositions close to 50 wt %.

    “Similar effects have been reported for miscible block copolymers such as polyethyleneb -poly(ethylenealt -propylene), where a stronger dilution effect induced by amorphous poly(ethylenealt -propylene) chains causes the need for much higher supercoolings to crystallize the PE block chains but at compositions close to 50 wt %. 75,76”

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Authors
Lorenzo, A. T., Arnal, M. L., Müller, A. J., Boschetti de Fierro, A., & Abetz, V.
Affiliations
Universidad Simón Bolívar (VE)
Corresponding author
Müller, A.J.
Venue
European Polymer Journal
Publisher
Elsevier BV
Published
2006-03
Volume
42
Issue
3
Pages
516-533
ISSN
0014-3057 (ISSN-L)
OpenAlex
W2066029160
Cited by
75
References
83
Citations by year
2025: 4 · 2024: 2 · 2023: 1 · 2022: 3 · 2021: 5 · 2018: 2 · 2017: 4 · 2016: 3 · 2015: 6 · 2014: 2 · 2013: 6 · 2012: 6
FWCI
4.65
Type
journal article
Language
en
Open access
closed
Locations
European Polymer Journal (publishedVersion)
Funders
  • Deutsche Forschungsgemeinschaft
  • Fondo Nacional de Ciencia Tecnología e Innovación
Topics
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
  • Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords
confined crystallization, polyethylene, fractional crystallization, thermal fractionation, lamellar thickness distribution, topological confinement, Gibbs-Thomson equation, homogeneous nucleation, heterogeneous nucleation, interfacial phenomena, microdomains, anionic polymerization, hydrogenated polybutadiene, lamellar crystals, block copolymer morphology

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