Characterization and selection of biochar for an efficient retention of tricyclazole in a flooded alluvial paddy soil
Abstract
Biochars, from different organic residues, are increasingly proposed as soil amendments for their agronomic and environmental benefits. A systematic detection method that correlates biochar properties to their abilities to adsorb organic compounds is still lacking. Seven biochars obtained after pyrolysis at different temperatures and from different feedstock (alperujo compost, rice hull, and woody debris), were characterized and tested to reveal potential remedial forms for pesticide capture in flooded soils. Biochar properties were determined by nuclear magnetic resonance (NMR) spectroscopy, Fourier transform infrared spectroscopy, specific surface area (SSA) assessment and scanning electron microscopy. In addition, dissolved organic matter (DOM) from these biochars was extracted and quantified in order to evaluate the effect on pesticide sorption. The biochars from alperujo compost presented very high affinity to the fungicide tricyclazole (55.9, 83.5, and 90.3% for B1, B4, and B5, respectively). This affinity was positively correlated with the pyrolysis temperature, the pH, the increased SSA of the biochars, and the enhanced aromaticity. Sorptive capacities were negatively related to DOM contents. The amendment with a mixture of compost and biochar endows the alluvial soil with high sorptive properties (from K(fads(soil)) = 9.26 to K(fads(mixture)) = 17.89) without impeding the slow release of tricyclazole.
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Increase of the pH value could be attributed to the concentration of nonpyrolyzed inorganic elements and also to decomposition of organic matrix.
“Increase of the pH value could be attributed to the concentration of nonpyrolyzed inorganic elements and also to decomposition of organic matrix (Garcia-Jaramillo et al. 2015).”
From Biochar physicochemical properties: pyrolysis temperature and feedstock kind effects (2020) · cites this paper as Garcia-Jaramillo et al. 2015
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- Authors
- García-Jaramillo, M., Cox, L., Knicker, H. E., Cornejo, J., Spokas, K. A., & Hermosín, M. C.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- Agricultural Research Service (US)
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2015-04
- Volume
- 286
- Pages
- 581-588
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W1979132873
- Cited by
- 60
- References
- 75
- Citations by year
- 2026: 2 · 2025: 3 · 2024: 4 · 2023: 7 · 2022: 7 · 2021: 7 · 2020: 4 · 2019: 8 · 2018: 3 · 2017: 8 · 2016: 5 · 2015: 1
- FWCI
- 3.29
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Journal of Hazardous Materials (publishedVersion)
- PubMed (publishedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (submittedVersion)
- Funders
- Ministry of Economy and Competitiveness (AGL2010-21421 and AGL2013-48446-C3-1-R)
- Autonomous Government of Andalusia (PAIDI AGR-264)
- Topics
- Physical Sciences › Environmental Science › Pollution › Pesticide and Herbicide Environmental Studies
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- biochar, tricyclazole, pesticide sorption, flooded paddy soil, rice husk, woody debris, pyrolysis temperature, dissolved organic matter, specific surface area, aromaticity, soil amendment, slow release, alluvial soils
- MeSH terms
- Adsorption, Charcoal, Fungicides, Industrial, Oryza, Soil, Soil Pollutants, Surface Properties, Thiazoles, Environmental Restoration and Remediation, Floods
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