The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Metallocene implanted metalloporphyrin organic framework for highly selective CO2 electroreduction
Abstract
Abstract Metal organic frameworks (MOFs) with tunable porosity and metal sites have been considered as excellent candidates for electrochemical CO2 reduction reaction (CO2RR). However, the poor electron conductivity and electron-donating capability of MOFs constrain the improvement of catalytic efficiency. Herein, we implant metallocene in MOFs through a facile chemical vapor deposition method and thus-obtained catalysts present excellent CO2RR electrocatalysis performances. For instance, the FECO of CoCp2@MOF-545-Co can be as high as 97% at −0.7 V. The high performances might be attributed to the strong binding-interaction between metallocene and metalloporphyrin that can largely reduce the adsorption energy of CO2 as revealed by density functional theory calculations. The introduction of metallocene can serve as electron donator and carrier to create continuous electron transfer channel in MOFs and provide strong binding-interaction with metalloporphyrin during CO2RR process to enhance the CO2RR activity. This method might shed light on development of highly-selective CO2RR electrocatalysts.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
Technical photosynthesis involving CO2 electrolysis and fermentation
Haas, T., Krause, R., Weber, R., Demler, M., & Schmid, G. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0005-1 · Cited by 649
Cited by
Younas, M., Rezakazemi, M., Daud, M., Wazir, M. B., Ahmad, S., Ullah, N., Inamuddin, & Ramakrishna, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100849 · Cited by 421
Recent Progress of Vacancy Engineering for Electrochemical Energy Conversion Related Applications
Wu, Z., Zhao, Y., Jin, W., Jia, B., Wang, J., & Ma, T. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202009070 · Cited by 373
Recent progress in metal–organic frameworks (MOFs) for electrocatalysis
Li, C., Zhang, H., Liu, M., Lang, F.-F., Pang, J., & Bu, X.-H. (2023) · Industrial Chemistry & Materials · doi:10.1039/d2im00063f · Cited by 339
Tang, T., Wang, Z., & Guan, J. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202111504 · Cited by 304
Zhang, L., Li, X.-X., Lang, Z.-L., Liu, Y., Liu, J., Yuan, L., Lu, W.-Y., Xia, Y.-S., Dong, L.-Z., Yuan, D.-Q., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.0c11450 · Cited by 292
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Metadata
- Authors
- Xin, Z., Wang, Y.-R., Chen, Y., Li, W.-L., Dong, L.-Z., & Lan, Y.-Q.
- Venue
- Nano Energy
- Publisher
- Elsevier BV
- Published
- 2020-01
- Volume
- 67
- Pages
- 104233
- ISSN
- 2211-2855 (ISSN-L)
- OpenAlex
- W2982666814
- Cited by
- 159
- References
- 5
- FWCI
- 3.14
- Type
- journal article
- Language
- en
- Open access
- closed
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