Evidence of a dual network/spherulitic crystalline morphology in PLA stereocomplexes
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This trend has also been reported for triblock and di-block copolymers composed of well-defined high-molecular-weight PDLA-b-PLLA and PDLA-b-PLLA-b-PDLA stereoblock architectures, as shown by the group of Rastogi et al.
“This trend has also been reported for triblock and di-block copolymers composed of well-defined high-molecular-weight PDLA-b-PLLA and PDLA-b-PLLA-b-PDLA stereoblock architectures, as shown by the group of Rastogi et al. 89”
In their study, increasing block length and molar mass led to a pronounced enhancement in elongation at break, which was attributed to improved chain entanglement and more effective stress transfer between crystalline and amorphous domains.
“In their study, increasing block length and molar mass led to a pronounced enhancement in elongation at break, which was attributed to improved chain entanglement and more effective stress transfer between crystalline and amorphous domains.”
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- Authors
- Saeidlou, S., Huneault, M. A., Li, H., Sammut, P., & Park, C. B.
- Affiliations
- Université de Sherbrooke (CA)
- National Research Council Canada (CA)
- University of Toronto (CA)
- Corresponding author
- Huneault, Michel A.
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2012-11
- Volume
- 53
- Issue
- 25
- Pages
- 5816-5824
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2045744574
- Cited by
- 120
- References
- 43
- Citations by year
- 2026: 4 · 2025: 6 · 2024: 8 · 2023: 11 · 2022: 12 · 2021: 11 · 2020: 12 · 2019: 6 · 2018: 11 · 2017: 7 · 2016: 4 · 2015: 12 · 2014: 4 · 2013: 12
- FWCI
- 7.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer (publishedVersion)
- NPARC (submittedVersion)
- Funders
- NSERC
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Keywords
- poly(L-lactic acid), poly(D-lactide), stereocomplex formation, transcrystalline layer, nucleation, crystallization kinetics, melt viscosity
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