Degradation mechanisms of polycaprolactone in the context of chemistry, geometry and environment

The return of a forgotten polymer—Polycaprolactone in the 21st century

Woodruff, M. A., & Hutmacher, D. W. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2010.04.002 · Cited by 4,033

Synthesis of polycaprolactone: A review

Labet, M., & Thielemans, W. (2009) · Chemical Society Reviews · doi:10.1039/b820162p · Cited by 1,673

Biodegradable polyesters for medical and ecological applications

Ikada, Y., & Tsuji, H. (2000) · Macromolecular Rapid Communications · doi:10.1002/(sici)1521-3927(20000201)21:3 · Cited by 1,538

Mechanical properties and cell cultural response of polycaprolactone scaffolds designed and fabricated via fused deposition modeling

Hutmacher, D. W., Schantz, T., Zein, I., Ng, K. W., Teoh, S. H., & Tan, K. C. (2001) · Journal of Biomedical Materials Research · doi:10.1002/1097-4636(200105)55:2 · Cited by 1,442

Why degradable polymers undergo surface erosion or bulk erosion

Burkersroda, F. V., Schedl, L., & Göpferich, A. (2002) · Biomaterials · doi:10.1016/s0142-9612(02)00170-9 · Cited by 1,146

Poly-ϵ-caprolactone microspheres and nanospheres: an overview

Sinha, V. R., Bansal, K., Kaushik, R., Kumria, R., & Trehan, A. (2004) · International Journal of Pharmaceutics · doi:10.1016/j.ijpharm.2004.01.044 · Cited by 1,101

The in vivo degradation, absorption and excretion of PCL-based implant

Sun, H., Mei, L., Song, C. X., Cui, X., & Wang, P. (2005) · Biomaterials · doi:10.1016/j.biomaterials.2005.09.019 · Cited by 992

Hydrolytic degradation of devices based on poly(DL-lactic acid) size-dependence

Grizzi, I., Garreau, H., Li, S., & Vert, M. (1995) · Biomaterials · doi:10.1016/0142-9612(95)93258-f · Cited by 895

Aliphatic polyesters II. The degradation of poly (DL-lactide), poly (ε-caprolactone), and their copolymers in vivo

Pitt, G. G., Gratzl, M. M., Kimmel, G. L., Surles, J., & Sohindler, A. (1981) · Biomaterials · doi:10.1016/0142-9612(81)90060-0 · Cited by 857

Physico-mechanical properties of degradable polymers used in medical applications: A comparative study

Engelberg, I., & Kohn, J. (1991) · Biomaterials · doi:10.1016/0142-9612(91)90037-b · Cited by 820

Evaluation of the polycaprolactone hydrolytic degradation in acid solvent and its influence on the electrospinning process

Anaya‐Mancipe, J. M., de Figueiredo, A. C., Rabello, L. G., Dias, M. L., & Thiré, R. M. D. S. M. (2024) · Journal of Applied Polymer Science · doi:10.1002/app.55662 · Cited by 26

Experimental Analysis of the Enzymatic Degradation of Polycaprolactone: Microcrystalline Cellulose Composites and Numerical Method for the Prediction of the Degraded Geometry

Abdelfatah, J., Paz, R., Alemán‐Domínguez, M. E., Monzón, M., Donate, R., & Winter, G. (2021) · Materials · doi:10.3390/ma14092460 · Cited by 23

Osmotic core-shell polymeric implant for sustained BDNF AntagoNAT delivery in CNS using minimally invasive nasal depot (MIND) approach

Padmakumar, S., Jones, G., Khorkova, O., Hsiao, J. H., Kim, J., Bleier, B. S., & Amiji, M. M. (2021) · Biomaterials · doi:10.1016/j.biomaterials.2021.120989 · Cited by 23

Poly ɛ-caprolactone/nanostarch composite nanofibrous wound dressing with antibacterial property and pH stimulus drug release

Reshmi, C. R., Sagitha, P., Sheeja, & Sujith, A. (2021) · Cellulose · doi:10.1007/s10570-021-04287-7 · Cited by 23

Curcumin loaded polycaprolactone scaffold capable of anti-inflammation to enhance tracheal cartilage regeneration

Yang, M., Sun, W., Wang, L., Tang, H., Xu, X., Yang, L., Ni, J., Zheng, K., Jiang, X., Xu, W., et al. (2022) · Materials & Design · doi:10.1016/j.matdes.2022.111299 · Cited by 23

Multi-stimuli-responsive chitosan-functionalized magnetite/poly(ε-caprolactone) nanoparticles as theranostic platforms for combined tumor magnetic resonance imaging and chemotherapy

García-García, G., Caro, C., Fernández-Álvarez, F., García‐Martín, M. L., & Arias, J. L. (2023) · Nanomedicine Nanotechnology Biology and Medicine · doi:10.1016/j.nano.2023.102695 · Cited by 23

Melt electrowriting scaffolds with fibre-guiding features for periodontal attachment

Staples, R., Ivanovski, S., Vaswani, K., & Vaquette, C. (2024) · Acta Biomaterialia · doi:10.1016/j.actbio.2024.04.006 · Cited by 22

Tailoring the mechanical and degradation properties of 3DP PLA/PCL scaffolds for biomedical applications

Kalva, S. N., Zakaria, Y., Velasquez, C. A., & Koç‬, M. (2025) · REVIEWS ON ADVANCED MATERIALS SCIENCE · doi:10.1515/rams-2025-0098 · Cited by 22

Melt-extrusion 3D printing of resorbable levofloxacin-loaded meshes: Emerging strategy for urogynaecological applications

Corduas, F., Mathew, E., McGlynn, R. J., Mariotti, D., Lamprou, D. A., & Mancuso, E. (2021) · Materials Science and Engineering C · doi:10.1016/j.msec.2021.112523 · Cited by 22

Thermal Stability of Polycaprolactone Grafted Densely with Maleic Anhydride Analysed Using the Coats–Redfern Equation

Thangunpai, K., Hu, D., Su, X., Kajiyama, M., Neves, M. A., & Enomae, T. (2022) · Polymers · doi:10.3390/polym14194100 · Cited by 22

Control of drug release kinetics from hot-melt extruded drug-loaded polycaprolactone matrices

Chen, Y.-C., Shishikura, S., Moseson, D. E., Ignatovich, A. J., Lomeo, J., Zhu, A., Horava, S. D., Richard, C. A., Park, K., & Yeo, Y. (2023) · Journal of Controlled Release · doi:10.1016/j.jconrel.2023.05.049 · Cited by 22

A mini-review on wrinkled nanofibers: Preparation principles via electrospinning and potential applications

Zaarour, B., Liu, W. H., Omran, W., Alhinnawi, M. F., Dib, F., Alshabab, M. S., Ghannoum, S., Kayed, K., Mansour, G., & Balidi, G. (2024) · Journal of Industrial Textiles · doi:10.1177/15280837241255396 · Cited by 22

In vivo biocompatible shape memory polyester derived from recycled polycarbonate e-waste for biomedical application

Ghosal, K., Pal, S., Ghosh, D., Jana, K., & Sarkar, K. (2022) · Biomaterials Advances · doi:10.1016/j.bioadv.2022.212961 · Cited by 21

Effect of chitosan and curcumin nanoparticles against skeletal muscle fibrosis at early regenerative stage of glycerol-injured rat muscles

Mahdy, M. A. A., Akl, M. A., & Madkour, F. A. (2022) · BMC Musculoskeletal Disorders · doi:10.1186/s12891-022-05633-x · Cited by 21

Smart Nanofiber Mesh with Locally Sustained Drug Release Enabled Synergistic Combination Therapy for Glioblastoma

Li, Y.-N., Matsumoto, Y., Chen, L., Sugawara, Y., Oe, E., Fujisawa, N., Ebara, M., & Sakurai, H. (2023) · Nanomaterials · doi:10.3390/nano13030414 · Cited by 14

Functionalized thermoplastic polyurethane with tunable tribopolarity and biodegradability for high performance and biodegradable triboelectric nanogenerator

Joo, H., Gwak, S., Lee, M. H., Park, H., Lee, C., Lee, J. H., Han, S. A., & Lee, J. (2023) · Sustainable materials and technologies · doi:10.1016/j.susmat.2023.e00638 · Cited by 21

Stretchable and biodegradable triboelectric nanogenerator based on elastomeric nanocomposites

Kang, H., Han, W. B., Yang, S. M., Ko, G., Ryu, Y., Lee, J. H., Shin, J., Jang, T., Rajaram, K., Han, S., et al. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.146208 · Cited by 21

Integrating bioprinting, cell therapies and drug delivery towards in vivo regeneration of cartilage, bone and osteochondral tissue

Abbadessa, A., Ronca, A., & Salerno, A. (2023) · Drug Delivery and Translational Research · doi:10.1007/s13346-023-01437-1 · Cited by 24

Microrobotic carrier with enzymatically encoded drug release in the presence of pancreatic cancer cells via programmed self-destruction

Pacheco, M., Mayorga‐Martinez, C. C., Viktorová, J., Ruml, T., Escarpa, A., & Pumera, M. (2022) · Applied Materials Today · doi:10.1016/j.apmt.2022.101494 · Cited by 21

Copolymerization of Caprolactone Isomers to Obtain Nanoparticles with Constant Hydrophobicity and Tunable Crystallinity

Bandelli, D., Muljajew, I., Scheuer, K., Max, J. B., Weber, C., Schacher, F. H., Jandt, K. D., & Schubert, U. S. (2020) · Macromolecules · doi:10.1021/acs.macromol.0c00486 · Cited by 20

Noninvasive In Vivo Imaging and Monitoring of 3D-Printed Polycaprolactone Scaffolds Labeled with an NIR Region II Fluorescent Dye

Jing, L., Sun, M., Xu, P., Yao, K., Yang, J., Wang, X., Liu, H., Sun, M., Sun, Y., Ni, R., et al. (2021) · ACS Applied Bio Materials · doi:10.1021/acsabm.0c01587 · Cited by 20

A Deeper Insight into the Influence of the Electric Field Strength When Melt‐Electrowriting on Non‐Planar Surfaces

Saha, U., Nairn, R., Keenan, O., & Monaghan, M. G. (2021) · Macromolecular Materials and Engineering · doi:10.1002/mame.202100496 · Cited by 20

Surface biofunctional bFGF-loaded electrospun suture accelerates incisional wound healing

Li, Y., Luo, H., Li, Y., Huang, P., Xu, J., Zhang, J., Cai, P., He, H., Wu, J., & Li, X. (2022) · Materials & Design · doi:10.1016/j.matdes.2022.111451 · Cited by 20

One-Step Gas Foaming Strategy for Constructing Strontium Nanoparticle Decorated 3D Scaffolds: a New Platform for Repairing Critical Bone Defects

Chen, Y., Li, Y., Wang, X., Mo, X., Chen, Y., Deng, Z., Ye, X., & Yu, J. (2024) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.4c13119 · Cited by 20

Kinetic degradation and biocompatibility evaluation of polycaprolactone‐based biologics delivery matrices for regenerative engineering of the rotator cuff

Prabhath, A., Vernekar, V. N., Vasu, V., Badon, M. A., Avochinou, J., Asandei, A. D., Kumbar, S. G., Weber, E., & Laurencin, C. T. (2021) · Journal of Biomedical Materials Research Part A · doi:10.1002/jbm.a.37200 · Cited by 20

3D printing in musculoskeletal interface engineering: Current progress and future directions

Xu, T., Rao, J., Mo, Y., Lam, A. C.-H., Yang, Y., Wong, S. W.-F., Wong, K., & Zhao, X. (2025) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2025.115552 · Cited by 21

Degradation of Melt Electrowritten PCL Scaffolds Following Melt Processing and Plasma Surface Treatment

Paxton, N. C., Ho, S. W. K., Tuten, B. T., Lipton‐Duffin, J., & Woodruff, M. A. (2021) · Macromolecular Rapid Communications · doi:10.1002/marc.202100433 · Cited by 19

Fused filament fabrication of polycaprolactone bioscaffolds: Influence of fabrication parameters and thermal environment on geometric fidelity and mechanical properties

Paetzold, R., Coulter, F. B., Singh, G., Kelly, D. J., & O’Cearbhaill, E. D. (2022) · Bioprinting · doi:10.1016/j.bprint.2022.e00206 · Cited by 19

Micellar Polymer Magnetic Microrobots as Efficient Nerve Agent Microcleaners

Pacheco, M., Mayorga‐Martinez, C. C., Escarpa, A., & Pumera, M. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c02926 · Cited by 19

Electrospun Nisin-Loaded Poly(ε-caprolactone)-Based Active Food Packaging

Šišková, A. O., Mosnáčková, K., Musioł, M., Opálek, A., Bučková, M., Rychter, P., & Andicsová, A. E. (2022) · Materials · doi:10.3390/ma15134540 · Cited by 19

ZnO nanoparticles-modified polycaprolactone-gelatin membranes for guided/bone tissue regeneration, antibacterial and osteogenic differentiation properties

Prado-Prone, G., Silva-Bermúdez, P. S., Rodil, S. E., Ganjkhani, Y., Moradi, A., Méndez, F. J., García-Macedo, J. A., Bazzar, M., & Almaguer‐Flores, A. (2023) · Biomedical Physics & Engineering Express · doi:10.1088/2057-1976/acbe47 · Cited by 19

Melt electrowritten scaffolds containing fluorescent nanodiamonds for improved mechanical properties and degradation monitoring

Wu, X., Vedelaar, T., Li, R., Schirhagl, R., Kamperman, M., & Włodarczyk‐Biegun, M. K. (2023) · Bioprinting · doi:10.1016/j.bprint.2023.e00288 · Cited by 19

pH-sensitive cationic nanoparticles for endosomal cell-free DNA scavenging against acute inflammation

Feng, Y., Wei, C., Gu, Y., Zhang, H., Liu, L., Chen, Y., & Zhao, T. (2024) · Journal of Controlled Release · doi:10.1016/j.jconrel.2024.03.003 · Cited by 19

Fabrication of a Compliant Vascular Graft Using Extrusion Printing and Electrospinning Technique

Fazal, F., Melchels, F. P. W., McCormack, A., Silva, A. F., Handley, E., Mazlan, N. A., Callanan, A., Koutsos, V., & Radacsi, N. (2024) · Advanced Materials Technologies · doi:10.1002/admt.202400224 · Cited by 19

Boron Nitride Nanotubes for Heat Dissipation in Polycaprolactone Composites

Pietri, T., Wiley, B. J., & Simonato, J. (2021) · ACS Applied Nano Materials · doi:10.1021/acsanm.1c00365 · Cited by 22

Development of poly( p -coumaric acid) as a self-anticancer nanocarrier for efficient and biosafe cancer therapy

Wang, L., You, X., Dai, C., Fang, Y., & Wu, J. (2022) · Biomaterials Science · doi:10.1039/d2bm00027j · Cited by 19

Electrochemical Amination of Aryl Halides with NH 3

Liu, Y., Sun, Y., Deng, Y., & Qiu, Y. (2025) · Angewandte Chemie International Edition · doi:10.1002/anie.202504459 · Cited by 19

A Review on Biodegradable Materials of Sustainable Soft Robotics and Electronics

Xie, Y., Han, J., Dai, X., Zhang, X., Xiao, K., Huang, J., Cao, Y., Zhong, A., & Huang, L. (2025) · Advanced Science · doi:10.1002/advs.202510320 · Cited by 21

Novel elastomeric fibrous composites of poly-ε-caprolactone/propolis and their evaluation for biomedical applications

Mohamadinooripoor, R., Kashanian, S., Moradipour, P., Sajadimajd, S., Arkan, E., Tajehmiri, A., & Rashidi, K. (2022) · Journal of Polymer Research · doi:10.1007/s10965-022-03165-5 · Cited by 18

Synthesis of Candida Antarctica Lipase B (CALB) enzyme-powered magnetite nanomotor based on PCL/Chitosan Janus nanostructure

Mafakheri, F., & Khoee, S. (2022) · Scientific Reports · doi:10.1038/s41598-022-16777-0 · Cited by 18

Nanoparticle-mediated polycaprolactone based nanofiber mats for enhanced apoptosis of breast cancer cell line with improved cell viability of fibroblast cell line: Controlled drug release and antimicrobial assay

Jaisankar, E., Azarudeen, R. S., & Thirumarimurugan, M. (2023) · Journal of Drug Delivery Science and Technology · doi:10.1016/j.jddst.2023.104451 · Cited by 18

A novel bifunctional multilayered nanofibrous membrane combining polycaprolactone and poly (vinyl alcohol) enriched with platelet lysate for skin wound healing

Blanquer, A., Košťáková, E. K., Filová, E., Lisnenko, M., Brož, A., Müllerová, J., Novotný, V., Havlíčková, K., Jakubkova, S., HAUZEROVÁ, Š., et al. (2024) · Nanoscale · doi:10.1039/d3nr04705a · Cited by 18

Surface-Conjugated Galactose on Electrospun Polycaprolactone Nanofibers: An Innovative Scaffold for Uterine Tissue Engineering

Hanuman, S., Kumar, H., Pai, K. S. R., & Nune, M. (2024) · ACS Omega · doi:10.1021/acsomega.3c10445 · Cited by 19

Selective visible-light-driven toxicity breakdown of nerve agent simulant methyl paraoxon over a photoactive nanofabric

Filho, J. B. G., Bruziquesi, C. G. O., Rios, R. D. F., de Castro, A. A., Victória, H. F. V., Krambrock, K., Mansur, A. A. P., Mansur, H. S., Siniterra, R. D., Ramalho, T. C., et al. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119774 · Cited by 18

Biodegradable polycaprolactone metallopolymer–antibiotic bioconjugates containing phenylboronic acid and cobaltocenium for antimicrobial application

Yang, P., Luo, Y., Kurnaz, L. B., Bam, M., Yang, X., Decho, A. W., Nagarkatti, M., & Tang, C. (2021) · Biomaterials Science · doi:10.1039/d1bm00970b · Cited by 19

Advanced analytical, chemometric, and genomic tools to identify polymer degradation products and potential microbial consumers in wastewater environments

Vila‐Costa, M., Martinez‐Varela, A., Rivas, D., Martinez, P., Pérez-López, C., Žonja, B., Montemurro, N., Tauler, R., Barceló, ‪., & Ginebreda, A. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.136175 · Cited by 18

Engineering Anisotropic Mechanical Properties in Large‐Scale Fabricated Cartilage Constructs Using Microfiber Reinforcement

Spauwen, L., Moliner, A. P., van Veenendaal, P. A. T. T., Custers, R. J. H., Malda, J., & de Ruijter, M. (2025) · Advanced Healthcare Materials · doi:10.1002/adhm.202501014 · Cited by 17

In vivo and in vitro per se effect evaluation of Polycaprolactone and Eudragit® RS100-based nanoparticles

dos Santos, R. B., Ribeiro, A. C. F., Maciel, T. R., Fonseca, D. P., Favarin, F. R., Nogueira-Librelotto, D. R., de Gomes, M. G., Ueda‐Nakamura, T., Rolim, C. M. B., & Haas, S. E. (2022) · Biomedicine & Pharmacotherapy · doi:10.1016/j.biopha.2022.113410 · Cited by 17

Evaluation of the Immune Response to Chitosan-graft-poly(caprolactone) Biopolymer Scaffolds

Moore, M., Lam, Y. T., Santos, M., Tan, R. P., Yang, N., Hung, J., Li, Z., Kilian, K. A., Rnjak‐Kovacina, J., Pitts, J., et al. (2023) · ACS Biomaterials Science & Engineering · doi:10.1021/acsbiomaterials.3c00553 · Cited by 18

A Polycaprolactone-Capped ZnO Quantum Dots-Based Fluorometric Sensor for the Detection of Fe3+ Ions in Seawater

Kamacı, M. (2023) · Journal of Fluorescence · doi:10.1007/s10895-023-03394-x · Cited by 17

A novel 3D printed type II silk fibroin/polycaprolactone mesh for the treatment of pelvic organ prolapse

Wu, J., Yao, H., Yu, L., Li, H., Zuo, Y., Liu, W., Zhang, C., Fu, C., & Liu, M. (2023) · Biomaterials Science · doi:10.1039/d3bm01158e · Cited by 17

Dental-derived stem cells in tissue engineering: the role of biomaterials and host response

Yuan, W., Ferreira, L. D. A. Q., Yu, B., Ansari, S., & Moshaverinia, A. (2023) · Regenerative Biomaterials · doi:10.1093/rb/rbad100 · Cited by 19

A Study on Tailoring Silver Release from Micro‐Arc Oxidation Coating Fabricated on Titanium

Kayan, G. Ö., Muhaffel, F., Kayan, A., Nofar, M., & Çi̇menoǧlu, H. (2024) · Advanced Engineering Materials · doi:10.1002/adem.202401129 · Cited by 17

Fabrication of 3D bioactive melt electrowriting composite scaffold with high osteogenic potential

Abdal‐hay, A., Kocak-Oztug, N. A., Sheikh, F. A., Han, P., Anwar, S., Fournier, B., & Ivanovski, S. (2024) · Colloids and Surfaces B Biointerfaces · doi:10.1016/j.colsurfb.2024.114270 · Cited by 17

Nano-scaffold-based delivery systems of antimicrobial agents in the treatment of osteomyelitis ; a narrative review

Yekani, M., Dizaj, S. M., Sharifi, S., Sedaghat, H., Saffari, M., & Memar, M. Y. (2024) · Heliyon · doi:10.1016/j.heliyon.2024.e38392 · Cited by 16

Phytotoxicity evaluation of poly (ɛ-caprolactone) nanocapsules prepared using different methods and compositions in Brassica juncea seeds

Preisler, A. C., Guariz, H. R., Carvalho, L. B., Pereira, A. D. E. S., de Oliveira, J. L., Fraceto, L. F., Dalazen, G., & Oliveira, H. C. (2022) · Plant Nano Biology · doi:10.1016/j.plana.2022.100003 · Cited by 16

Nanopore Deciphering Single Digital Polymers Towards High‐Density Data Storage

Hu, Z., Liu, Y., Xin, K., Yu, R., Zhang, L., & Ying, Y. (2023) · Chemistry - A European Journal · doi:10.1002/chem.202203919 · Cited by 16

Unique uniformity of calcium phosphate nanoparticle distribution in polymer substrates for additive manufacturing

Abdal‐hay, A., Bartnikowski, M., Blaudez, F., Vaquette, C., Hutmacher, D. W., & Ivanovski, S. (2023) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2023.107670 · Cited by 17

An oxygenating colloidal bioink for the engineering of biomimetic tissue constructs

Jeong, S., Hiemstra, J., Blokzijl, P. V., Damián-Ferrara, R., Santos, D. M. D., da Fonseca, J. H. L., Kang, M., Kim, J., Yilmaz‐Aykut, D., Cham‐Pérez, M. L. L., et al. (2024) · Bio-Design and Manufacturing · doi:10.1007/s42242-024-00281-7 · Cited by 18

Facile Green Synthesis of Zingerone Based Tissue‐Like Biodegradable Polyester with Shape‐Memory Features for Regenerative Medicine

Jindal, S., Ghosal, K., Khamaisi, B., Kana’an, N., Nassar‐Marjiya, E., & Farah, S. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202405827 · Cited by 16

Moldable Plastics (Polycaprolactone) can be Acutely Toxic to Developing Zebrafish and Activate Nuclear Receptors in Mammalian Cells

James, B. D., Medvedev, A. V., Makarov, S. S., Nelson, R. K., Reddy, C. M., & Hahn, M. E. (2024) · ACS Biomaterials Science & Engineering · doi:10.1021/acsbiomaterials.4c00693 · Cited by 15

3D Melt-Extrusion Printing of Medium Chain Length Polyhydroxyalkanoates and Their Application as Antibiotic-Free Antibacterial Scaffolds for Bone Regeneration

Marcello, E., Nigmatullin, R., Basnett, P., Maqbool, M. S., Prieto, M. A., Knowles, J. C., Boccaccini, A. R., & Roy, I. (2024) · ACS Biomaterials Science & Engineering · doi:10.1021/acsbiomaterials.4c00624 · Cited by 16

Bone regenerative medicine: An emerging field with opportunities and challenges

Sadat‐Shojai, M., Asadnia, M., Shahsavani, M. B., & Yousefi, M. M. (2025) · Journal of the American Ceramic Society · doi:10.1111/jace.20508 · Cited by 16

Oligomer Content Determines the Properties and Application of Polycaprolactone

Gong, C., Gu, Y., Wang, X., & Yi, C. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c00275 · Cited by 16

Icy core–shell composite nanofibers with cooling, antibacterial and healing properties for outdoor burns

Sun, T.-C., Bai, X., Cheng, G.-T., Ding, Y., Zhou, Z., Wang, B.-C., Xu, L., Ramakrishna, S., Zhang, J., & Long, Y. (2022) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2022.09.051 · Cited by 16

Periodontal bone regeneration with a degradable thermoplastic HA/PLCL bone graft

Xiao, X., Liu, Z., Shu, R., Wang, J., Zhu, X., Bai, D., & Lin, H. (2022) · Journal of Materials Chemistry B · doi:10.1039/d2tb02123d · Cited by 15

Effect of curing time on the mechanical properties of poly(glycerol sebacate)

Wu, Z., Jin, K., Wang, L., & Fan, Y. (2023) · Journal of Applied Polymer Science · doi:10.1002/app.53700 · Cited by 15

Optimizing the formulation variables for encapsulation of linezolid into polycaprolactone inhalable microspheres using double emulsion solvent evaporation

Sharma, Y., Mahar, R., Chakraborty, A., & Nainwal, N. (2023) · Tuberculosis · doi:10.1016/j.tube.2023.102417 · Cited by 19

Shish-kebab structure fiber with nano and micro diameter regulate macrophage polarization for anti-inflammatory and bone differentiation

Zhu, G., Zhang, R., Xie, Q., Li, P., Wang, F., Wang, L., & Li, C. (2023) · Materials Today Bio · doi:10.1016/j.mtbio.2023.100880 · Cited by 15

Modeling marine microplastic emissions in Life Cycle Assessment: characterization factors for biodegradable polymers and their application in a textile case study

Pellengahr, F., Corella‐Puertas, E., Mattelin, V., Saadi, N., Bertella, F., Boulay, A., & van der Meer, Y. (2025) · Frontiers in Toxicology · doi:10.3389/ftox.2025.1494220 · Cited by 15

Review of Gaps in the Clinical Indications and Use of Neural Conduits and Artificial Grafts for Nerve Repair and Reconstruction

Chan, Y. M., Judge, N. G., Hu, Y., Willits, R. K., Li, N. Y., & Becker, M. L. (2025) · Biomacromolecules · doi:10.1021/acs.biomac.5c00558 · Cited by 16

Biobased composites of poly(butylene furanoate) copolymers and hemp

Deng, Z., Liubchak, I., Holness, F. B., Shahrokhi, F., Price, A. D., & Gillies, E. R. (2023) · Journal of Polymer Science · doi:10.1002/pol.20230060 · Cited by 14

The performance of and promotion strategies for degradable polymers in triboelectric nanogenerators

Gao, C., Tong, W., Zhang, Y., Zhang, J., Liu, S., & Zhang, Y. (2023) · Journal of Materials Chemistry A · doi:10.1039/d3ta01076g · Cited by 13

A biomimetic multi-layer scaffold with collagen and zinc doped bioglass as a skin-regeneration agent in full-thickness injuries and its effects in vitro and in vivo

Kamrani, A., Nasrabadi, M. H., Halabian, R., & Ghorbani, M. (2023) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2023.127163 · Cited by 15

Fabrication of controlled-release polymeric microneedles containing progesterone-loaded self-microemulsions for transdermal delivery

Suriyaamporn, P., Aumklad, P., Rojanarata, T., Patrojanasophon, P., Ngawhirunpat, T., Pamornpathomkul, B., & Opanasopit, P. (2024) · Pharmaceutical Development and Technology · doi:10.1080/10837450.2024.2307996 · Cited by 14

Enhancing output current in degradable flexible piezoelectric nanogenerators through internal electrode construction

Yang, X., Guo, H., Yuan, C., Li, Y., & Sun, H. (2024) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2024.04.116 · Cited by 14

In Vivo Biomedical Imaging of Immune Tolerant, Radiopaque Nanoparticle-Embedded Polymeric Device Degradation

Pawelec, K. M., Hix, J. M. L., Troia, A., MacRenaris, K. W., Kiupel, M., & Shapiro, E. M. (2023) · Acta Biomaterialia · doi:10.1016/j.actbio.2024.04.031 · Cited by 16

Novel shish-kebab structured nanofibrous decorating chitosan unidirectional scaffolds to mimic extracellular matrix for tissue engineering

Feng, P., & Jing, X. (2024) · Journal of the mechanical behavior of biomedical materials/Journal of mechanical behavior of biomedical materials · doi:10.1016/j.jmbbm.2024.106677 · Cited by 14

Medical- and Non-Medical-Grade Polycaprolactone Mesh Printing for Prolapse Repair: Establishment of Melt Electrowriting Prototype Parameters

Vaz, F., Martins, J. P., Pinheiro, F., Ferreira, N. M., Brandão, S., Alves, J. L., Fernandes, A. A., Parente, M., & Silva, M. E. (2024) · Applied Sciences · doi:10.3390/app14219670 · Cited by 15

Prospects of phytoremediation in degradation of environmental contaminants: recent advances, challenges and way forward

Jassal, P. S., Kudave, P. S., Wani, A. K., & Yadav, T. (2025) · International Journal of Phytoremediation · doi:10.1080/15226514.2025.2500643 · Cited by 14

Binary PCL–waste photopolymer blends for biodegradable food packaging applications

Gürler, N., Pekdemir, M. E., Torğut, G., & Kök, M. (2023) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2023.134990 · Cited by 17

Controlled degradation of polycaprolactone-based micropillar arrays

Geoghegan, N., O′Loughlin, M., Delaney, C., Rochfort, K. D., Kennedy, M., Kolagatla, S., Podhorska, L., Rodriguez, B. J., Florea, L., & Kelleher, S. M. (2023) · Biomaterials Science · doi:10.1039/d3bm00165b · Cited by 14

In vivo biocompatibility and biodegradability of poly(lactic acid)/poly( ε -caprolactone) blend compatibilized with poly( ε -caprolactone-b-tetrahydrofuran) in Wistar rats

Conde, G., de Carvalho, J. R. G., Dias, P. D. P., Moranza, H. G., Montanhim, G. L., Ribeiro, J. D. O., Chinelatto, M. A., Moraes, P. C., Taboga, S. R., Bertolo, P. H. L., et al. (2021) · Biomedical Physics & Engineering Express · doi:10.1088/2057-1976/abeb5a · Cited by 14

Biopolymers in Biotechnology and Tissue Engineering: A Comprehensive Review

Grabowski, M., Gmyrek, D., Żurawska, M., & Trusek-Hołownia, A. (2025) · Macromol—A Journal of Macromolecular Research · doi:10.3390/macromol5030034 · Cited by 13

A detailed guide to melt electro-writing for tissue engineering applications

Snow, F., Doyle, S. E., Liu, E. I., Rauch, D. D., Millett, D., Wilding-McBride, J., Kita, M., Pirogova, E., Kapsa, R. M. I., & Quigley, A. F. (2025) · Biofabrication · doi:10.1088/1758-5090/adfbc4 · Cited by 16

Biological study of polyethyleneimine functionalized polycaprolactone 3D ‐printed scaffolds for bone tissue engineering

Khoshnood, N., Shahrezaee, M. H., Shahrezayee, M., Shams, A., & Zamanian, A. (2022) · Journal of Applied Polymer Science · doi:10.1002/app.52628 · Cited by 13

Encapsulation of Carbon Dots in a Core–Shell Mesh through Coaxial Direct Ink Writing for Improved Crop Growth

Arel, I., Ay, A., Wang, J., Gil-Herrera, L. K., Dumanlı, A. G., & Akbulut, Ö. (2023) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.3c02641 · Cited by 13

Poly (ε-caprolactone)-Based Scaffolds with Multizonal Architecture: Synthesis, Characterization, and In Vitro Tests

Lima, T. D. P. D. L., Canelas, C. A. D. A., Dutra, J. D. C. F., Rodrigues, A. P. D., Brígida, R. T. S. S., Concha, V. O. C., da Costa, F. A. M., & Passos, M. F. (2023) · Polymers · doi:10.3390/polym15224403 · Cited by 13

Valorization of polycaprolactone for the production of nylon-6 monomers

Zhang, H., Zhao, Y., Wang, Y., Li, R., Tang, M., Xue, W., Wang, Y., Chang, X., Han, B., & Liu, Z. (2024) · Green Chemistry · doi:10.1039/d3gc05118h · Cited by 13

Enhancing foam concrete: A comparative analysis of PLA+ fiber reinforcements with plain, hooked, and corrugated fibers

Yildizel, S. A., Acik, M., Kaplan, G., & Bayraktar, O. Y. (2024) · Construction and Building Materials · doi:10.1016/j.conbuildmat.2024.137807 · Cited by 13

A coaxial electrospun mat coupled with piezoelectric stimulation and atorvastatin for rapid vascularized bone regeneration

Chen, J., Su, Y., Wu, J., Zhang, C., Liu, N., Zhang, Y., Lin, K., & Zhang, S. (2024) · Journal of Materials Chemistry B · doi:10.1039/d4tb00173g · Cited by 13

A novel NIR-responsive coating for magnesium implants: Controllable degradation enhanced by air bomb

Lv, Y., Liu, X., Zheng, M., Shi, X., Dong, Z., & Zhang, X. (2025) · Journal of Material Science and Technology · doi:10.1016/j.jmst.2024.11.078 · Cited by 13

Application of biodegradable implants in pediatric orthopedics: shifting from absorbable polymers to biodegradable metals

Lu, Y., Zhang, T., Chen, K., Canavese, F., Huang, C., Yang, H., Shi, J., He, W., Zheng, Y., & Chen, S. (2025) · Bioactive Materials · doi:10.1016/j.bioactmat.2025.04.001 · Cited by 15

Investigating Potential Effects of Ultra-Short Laser-Textured Porous Poly-ε-Caprolactone Scaffolds on Bacterial Adhesion and Bone Cell Metabolism

Filipov, E., Angelova, L., Vig, S., Fernandes, M. H., Moreau, G., Lasgorceix, M., Buchvarov, I., & Daskalova, A. (2022) · Polymers · doi:10.3390/polym14122382 · Cited by 13

Single administration vaccines: delivery challenges, in vivo performance, and translational considerations

Michaelides, K., Prasanna, M., Badhan, R. K. S., Mohammed, A. R., Walters, A. A., Howard, M. K., Dulal, P., & Al-Khattawi, A. (2023) · Expert Review of Vaccines · doi:10.1080/14760584.2023.2229431 · Cited by 13

Comprehensive hydrolytic degradation study of a new poly(ester-amide) used for total meniscus replacement

Miles, C. E., Lima, M. R. N., Buevich, F., Gwin, C., Murthy, N. S., & Kohn, J. (2021) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2021.109617 · Cited by 13

Controlled Solid-State Ring-Opening Polymerization of Cyclic Carbonates via Mechanochemical H-Bonding Organocatalysis

Chen, K., Li, S., Wang, Z., Lin, Z., Han, Z., Wang, X., Wang, Z., & Hadjichristidis, N. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.5c08373 · Cited by 14

Enzymatic degradation of biopolymers in amorphous and molten states: mechanisms and applications

Pustak, A., & Maršavelski, A. (2025) · FEBS Open Bio · doi:10.1002/2211-5463.70177 · Cited by 16

Environment Friendly, Renewable and Sustainable Natural Fiber‐Reinforced Polylactic Acid ( PLA ) Composites

Zhao, X., Liang, L., Fan, M., Dong, S., Deng, C., Liao, S., Wu, H., & Zhou, L. Y. (2026) · Polymer Composites · doi:10.1002/pc.70796 · Cited by 12

Tissue integration and biodegradation of soft tissue substitutes with and without compression: an experimental study in the rat

Bienz, S. P., Vaquette, C., Ioannidis, A., Hämmerle, C. H. F., Jung, R. E., Ivanovski, S., & Thoma, D. S. (2022) · Clinical Oral Investigations · doi:10.1007/s00784-022-04726-0 · Cited by 12

Thermodynamics of Polycaprolactone-water systemsAnalysis of interactional issues by comparing ab-initio and molecular approaches with a classical latticefluid theory of mixtures

Capone, F. (2016)

Understanding Polycaprolactone Degradation: Molecular Mechanisms and Implications for Biomedical Device Design

Dziemiańczyk, P., Łysik, D., Vernay, F., & Mystkowska, J. (2026) · Materials · doi:10.3390/ma19183894

A study on biodegradation of polycaprolactone in vivo

Zhong-wei, C. (2004) · Xinjiang Yike Daxue xuebao

Biodegradation of polycaprolactone in vivo

Xin-Xiang, X. (1999) · Zhonghua shiyan waike zazhi

A review of the biodegradability and utility of poly(caprolactone)

Goldberg, D. (1995) · Journal of Polymers and the Environment · doi:10.1007/bf02067481 · Cited by 125