Correlations between microstructural characterization and thermal properties of well defined poly(ε-caprolactone) samples by ring opening polymerization with neutral and cationic bis(2,4,6-triisopropylphenyl)tin(IV) compounds
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The final properties of copolymers are dictated not only by composition but also by macromolecular structure details such as molecular weight, dispersity, end-groups, microstructure and architecture.
“The final properties of the copolymers are dictated not only by their composition. Additionally, the details of the macromolecular structure, such as the molecular weight and dispersity, kind of end-groups [22], the polymer microstructure and architecture are important factors [23].”
From Thermo-Rheological and Shape Memory Properties of Block and Random Copolymers of Lactide and ε-Caprolactone (2021) · cites this paper as [22]
Cites
Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
March, J. (1977) · Andalas University Repository (Andalas University) · Cited by 4,029 · see citing works
Comprehensive Coordination Chemistry II
McCleverty, J. A., & Meyer, T. J. J. (2003) · Bristol Research (University of Bristol) · Cited by 2,690 · see citing works
Petry, F. E. (1997) · Kluwer Academic Publishers eBooks · Cited by 2,295 · see citing works
Controlled Ring-Opening Polymerization of Lactide and Glycolide
Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257 · see citing works
Recent Developments in Ring Opening Polymerization of Lactones for Biomedical Applications
Albertsson, A.-C., & Varma, I. K. (2003) · Biomacromolecules · doi:10.1021/bm034247a · Cited by 1,582 · see citing works
Treatise on Solid State Chemistry
(1976) · Springer eBooks · doi:10.1007/978-1-4613-4316-5 · Cited by 1,416 · see citing works
Mandelkern, L. (2004) · Cambridge University Press eBooks · doi:10.1017/cbo9780511535413 · Cited by 1,357 · see citing works
Principles of polymer processing
(2007) · Choice Reviews Online · doi:10.5860/choice.44-2729 · Cited by 1,205 · see citing works
Lindenmeyer, P. H. (1963) · Journal of Polymer Science Part C Polymer Symposia · doi:10.1002/polc.5070010103 · Cited by 945 · see citing works
WU, J., YU, T., CHEN, C., & LIN, C. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.07.010 · Cited by 779 · see citing works
Principles of Polymer Processing
(1979) · doi:10.1007/978-1-349-16234-5 · Cited by 696 · see citing works
Kricheldorf, H. R., Berl, M., & Scharnagl, N. (1988) · Macromolecules · doi:10.1021/ma00180a002 · Cited by 597 · see citing works
Nature or Petrochemistry?—Biologically Degradable Materials
Mecking, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200301655 · Cited by 590 · see citing works
Kowalski, A., Duda, A., & Penczek, S. (2000) · Macromolecules · doi:10.1021/ma000125o · Cited by 484 · see citing works
Thermal degradation of poly[(R)-3-hydroxybutyrate], poly[ε-caprolactone], and poly[(S)-lactide]
Aoyagi, Y., Yamashita, K., & Doi, Y. (2002) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(01)00265-8 · Cited by 456 · see citing works
Mechanisms and Kinetics of Thermal Degradation of Poly(ε-caprolactone)
Persenaire, O., Alexandre, M., Degée, P., & Dubois, P. (2001) · Biomacromolecules · doi:10.1021/bm0056310 · Cited by 444 · see citing works
Kowalski, A., Duda, A., & Penczek, S. (2000) · Macromolecules · doi:10.1021/ma9906940 · Cited by 408 · see citing works
Lewis acid catalyzed polymerization of L-lactide. Kinetics and mechanism of the bulk polymerization
Nijenhuis, A. J., Grijpma, D. W., & Pennings, A. J. (1992) · Macromolecules · doi:10.1021/ma00050a006 · Cited by 407 · see citing works
(1984) · Springer eBooks · doi:10.1007/978-1-4613-2433-1 · Cited by 314 · see citing works
Synthesis of high‐molecular‐weight poly(<scp>L</scp>‐lactide) initiated with tin 2‐ethylhexanoate
Leenslag, J. W., & Pennings, A. J. (1987) · Die Makromolekulare Chemie · doi:10.1002/macp.1987.021880804 · Cited by 290 · see citing works
Kinetics of polymer crystallisation
Yu, L., Shanks, R. A., & Stachurski, Z. H. (1995) · Progress in Polymer Science · doi:10.1016/0079-6700(95)00002-w · Cited by 253 · see citing works
Role of reptation in the rate of crystallization of polyethylene fractions from the melt
Hoffman, J. (1982) · Polymer · doi:10.1016/0032-3861(82)90048-9 · Cited by 248 · see citing works
Pappalardo, D., Annunziata, L., & Pellecchia, C. (2009) · Macromolecules · doi:10.1021/ma9010439 · Cited by 199 · see citing works
Self-citationChen, E.-C., & Wu, T. (2007) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2007.02.019 · Cited by 178 · see citing works
The effect of molecular weight on the crystallization kinetics of polycaprolactone
Jenkins, M. J., & Harrison, K. L. (2006) · Polymers for Advanced Technologies · doi:10.1002/pat.733 · Cited by 176 · see citing works
Shen, Y., Shen, Z., Zhang, Y., & Yao, K. (1996) · Macromolecules · doi:10.1021/ma9518060 · Cited by 152 · see citing works
ABA Type Copolymers of Lactide with Poly(ethylene glycol). Kinetic, Mechanistic, and Model Studies
Du, Y. J., Lemstra, P. J., Nijenhuis, A. J., Aert, H. A. M. V., & Bastiaansen, C. W. M. (1995) · Macromolecules · doi:10.1021/ma00111a004 · Cited by 149 · see citing works
Nano clay reinforced PCL/starch blends obtained by high energy ball milling
Vertuccio, L., Gorrasi, G., Sorrentino, A., & Vittoria, V. (2009) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2008.07.020 · Cited by 142 · see citing works
Self-citationLou, X., Detrembleur, C., & Jérôme, R. (2002) · Macromolecules · doi:10.1021/ma0113677 · Cited by 119 · see citing works
Spherulitic Crystallization Behavior of Poly(ε-caprolactone) with a Wide Range of Molecular Weight
Chen, H., Li, L., Ou-Yang, W.-C., Hwang, J. C., & Wong, W.-Y. (1997) · Macromolecules · doi:10.1021/ma960673v · Cited by 113 · see citing works
Star-shaped poly(ɛ-caprolactone) with polyhedral oligomeric silsesquioxane core
Liu, Y., Yang, X., Zhang, W., & Zheng, S. (2006) · Polymer · doi:10.1016/j.polymer.2006.07.050 · Cited by 111 · see citing works
Cayuela, J., Bounor-Legaré, V., Cassagnau, P., & Michel, A. (2006) · Macromolecules · doi:10.1021/ma051272v · Cited by 110 · see citing works
Thermal degradation of poly (ε-caprolactone)
Sivalingam, G., & Madras, G. (2003) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(02)00376-2 · Cited by 109 · see citing works
Ring-Opening Polymerization and Copolymerization of Lactones by Samarium(II) Aryloxide Complexes
Nishiura, M., Hou, Z., Koizumi, T., Imamoto, T., & Wakatsuki, Y. (1999) · Macromolecules · doi:10.1021/ma990101l · Cited by 109 · see citing works
Chmura, A. J., Davidson, M. G., Jones, M. D., Lunn, M. D., & Mahon, M. F. (2006) · Dalton Trans. · doi:10.1039/b513345a · Cited by 108 · see citing works
Kinetics of thermal degradation of poly(ε-caprolactone)
Sivalingam, G., Karthik, R., & Madras, G. (2003) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/s0165-2370(03)00045-7 · Cited by 107 · see citing works
Crystallization studies of poly(ε‐caprolactone).I. Morphology and kinetics
Phillips, P. J., Rensch, G. J., & Taylor, K. D. (1987) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.1987.090250814 · Cited by 106 · see citing works
Kerton, F. M., Whitwood, A. C., & Willans, C. E. (2004) · Dalton Transactions · doi:10.1039/b406841f · Cited by 102 · see citing works
Chen, M.-Z., Sun, H., Li, W., Wang, Z.-G., Shen, Q., & Zhang, Y. (2006) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2006.01.031 · Cited by 101 · see citing works
Isothermal melt-crystallization and melting behavior for three linear aromatic polyesters
Dangseeyun, N., Srimoaon, P., Supaphol, P., & Nithitanakul, M. (2003) · Thermochimica Acta · doi:10.1016/s0040-6031(03)00331-9 · Cited by 99 · see citing works
Kricheldorf, H. R., Sumbel, M. V., & Kreiser‐Saunders, I. (1991) · Macromolecules · doi:10.1021/ma00008a035 · Cited by 98 · see citing works
Garozzo, D., Giuffrida, M., & Montaudo, G. (1986) · Macromolecules · doi:10.1021/ma00160a027 · Cited by 91 · see citing works
Supaphol, P. (2001) · Thermochimica Acta · doi:10.1016/s0040-6031(00)00767-x · Cited by 74 · see citing works
Abe, H., Takahashi, N., Kim, K. J., Mochizuki, M., & Doi, Y. (2004) · Biomacromolecules · doi:10.1021/bm049945p · Cited by 74 · see citing works
Wang, H., Chan, H., Okuda, J., & Xie, Z. (2005) · Organometallics · doi:10.1021/om050079m · Cited by 63 · see citing works
Surprising Activity of Organoactinide Complexes in the Polymerization of Cyclic Mono- and Diesters
Barnea, E., Moradove, D., Berthet, J. ‐., Ephritikhine, M., & Eisen, M. S. (2005) · Organometallics · doi:10.1021/om050966p · Cited by 61 · see citing works
Nojima, S., Tsutsui, H., Urushihara, M., Kosaka, W., Kato, N., & Ashida, T. (1986) · Polymer Journal · doi:10.1295/polymj.18.451 · Cited by 60 · see citing works
Plage, B., & Schulten, H. R. (1990) · Macromolecules · doi:10.1021/ma00212a008 · Cited by 54 · see citing works
Non-isothermal melt- and cold-crystallization kinetics of poly(3-hydroxybutyrate)
Ziaee, Z., & Supaphol, P. (2006) · Polymer Testing · doi:10.1016/j.polymertesting.2006.04.009 · Cited by 53 · see citing works
Deshayes, G., Mercier, F. A. G., Degée, P., Verbruggen, I., Biesemans, M., Willem, R., & Dúbois, P. (2003) · Chemistry - A European Journal · doi:10.1002/chem.200304769 · Cited by 46 · see citing works
Polylactones 49: Bu4Sn-initiated polymerizations of ɛ-caprolactone
Kricheldorf, H. R. (2000) · Polymer · doi:10.1016/s0032-3861(99)00606-0 · Cited by 40 · see citing works
Über den thermischen abbau des poly(ε‐caprolacton)s
Lüderwald, I. (1977) · Die Makromolekulare Chemie · doi:10.1002/macp.1977.021780911 · Cited by 36 · see citing works
Architectural Effects of Poly(ε-caprolactone)s on the Crystallization Kinetics
Choi, J., & Kwak, S. (2004) · Macromolecules · doi:10.1021/ma035387f · Cited by 35 · see citing works
Crystallization studies of poly(ε‐caprolactone). II. Lamellar thickening and melting
Phillips, P. J., & Rensch, G. J. (1989) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.1989.090270110 · Cited by 34 · see citing works
Pappalardo, D., Annunziata, L., Pellecchia, C., Biesemans, M., & Willem, R. (2007) · Macromolecules · doi:10.1021/ma0623486 · Cited by 32 · see citing works
Self-citationBulk Crystallization Behavior of Poly(ε-caprolactone) with a Wide Range of Molecular Weight
Ou-Yang, W.-C., Li, L., Chen, H., & Hwang, J. C. (1997) · Polymer Journal · doi:10.1295/polymj.29.889 · Cited by 25 · see citing works
Annunziata, L., Pappalardo, D., Tedesco, C., Antinucci, S., & Pellecchia, C. (2006) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2005.12.011 · Cited by 6 · see citing works
Self-citationStassin, F., Halleux, O., Dubois, P., Detrembleur, C., Lecomte, P., & Jérôme, R. (2000) · Macromolecular Symposia · doi:10.1002/1521-3900(200003)153:1
Flagged first, then by citations
Cited by
Sorted by citations
Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides
Sarazin, Y., & Carpentier, J. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00033 · Cited by 301 · see citing works
Meduri, A., Fuoco, T., Lamberti, M., Pellecchia, C., & Pappalardo, D. (2014) · Macromolecules · doi:10.1021/ma402174y · Cited by 89 · see citing works
Self-citationFuoco, T., Meduri, A., Lamberti, M., Venditto, V., Pellecchia, C., & Pappalardo, D. (2015) · Polymer Chemistry · doi:10.1039/c4py01445f · Cited by 38 · see citing works
Self-citationSacchetin, P. S. C., Setti, R. F., Rosa, P. D. T. V. E., & Moraes, Â. M. (2015) · Materials Science and Engineering C · doi:10.1016/j.msec.2015.09.071 · Cited by 30 · see citing works
Naddeo, M., Sorrentino, A., & Pappalardo, D. (2021) · Polymers · doi:10.3390/polym13040627 · Cited by 25 · see citing works
“Additionally, the details of the macromolecular structure, such as the molecular weight and dispersity, kind of end-groups [22], the polymer microstructure and architecture are important factors [23].”
BackgroundSelf-citationAtanase, L. I., Glaied, O., & Riess, G. (2011) · Polymer · doi:10.1016/j.polymer.2011.05.017 · Cited by 26 · see citing works
Nucleation as a new concept for morphology adjustment of crystalline thermosetting epoxy polymers
Lützen, H., Gesing, T. M., & Hartwig, A. (2013) · Reactive and Functional Polymers · doi:10.1016/j.reactfunctpolym.2013.04.014 · Cited by 19 · see citing works
Polyethylene-like macrolactone-based polyesters: Rheological, thermal and barrier properties
Sorrentino, A., Gorrasi, G., Bugatti, V., Fuoco, T., & Pappalardo, D. (2018) · Materials Today Communications · doi:10.1016/j.mtcomm.2018.10.001 · Cited by 18 · see citing works
Self-citationGorrasi, G., Pappalardo, D., & Pellecchia, C. (2012) · Reactive and Functional Polymers · doi:10.1016/j.reactfunctpolym.2012.07.007 · Cited by 14 · see citing works
Self-citationRinaldi, G., Coccia, E., Ferrentino, N., Germinario, C., Grifa, C., Paolucci, M., & Pappalardo, D. (2024) · Advances in Polymer Technology · doi:10.1155/2024/3308910 · Cited by 9 · see citing works
Self-citationPalygorskite as Efficient Catalyst for Ring-Opening Polymerization of ϵ-Caprolactone
Wang, G., Ma, R., Chen, T., Yan, C., Gao, J., & Bao, F. (2013) · Polymer-Plastics Technology and Engineering · doi:10.1080/03602559.2013.798822 · Cited by 7 · see citing works
Mixed-mode interpenetrating polymer networks from polymerizable eutectics
Mutch, A. L., & Thickett, S. C. (2025) · Polymer Chemistry · doi:10.1039/d4py01456a · Cited by 6 · see citing works
Redondo, F. L., Ninago, M. D., de Freitas, A. G. O., Giacomelli, C., Ciolino, A. E., & Villar, M. A. (2018) · International Journal of Polymer Science · doi:10.1155/2018/8252481 · Cited by 6 · see citing works
Nanomodification of Chitosan Microspheres with Dendron Molecules
Aldana, A. A., Strumia, M. C., & Martinelli, M. (2012) · Journal of Biomaterials and Tissue Engineering · doi:10.1166/jbt.2013.1075 · Cited by 2 · see citing works
Sánchez-Pech, J. C., Ávila‐Ortega, A., Nic-Can, G. I., Carrillo‐Cocom, L. M., Cervantes‐Uc, J. M., Martín-Pat, G. E., Talavera-Pech, W. A., Bacelis, Á., Carrera‐Figueiras, C., Oliva-Arias, A. I., et al. (2024) · SSRN Electronic Journal · doi:10.2139/ssrn.4838567
- Authors
- Gorrasi, G., Vertuccio, L., Annunziata, L., Pellecchia, C., & Pappalardo, D.
- Affiliations
- University of Salerno (IT)
- University of Sannio (IT)
- Venue
- Reactive and Functional Polymers
- Publisher
- Elsevier BV
- Published
- 2010-03
- Volume
- 70
- Issue
- 3
- Pages
- 151-158
- ISSN
- 1381-5148 (ISSN-L)
- OpenAlex
- W1990925282
- Cited by
- 15
- References
- 58
- Citations by year
- 2025: 1 · 2024: 2 · 2021: 1 · 2018: 2 · 2015: 2 · 2014: 2 · 2013: 2 · 2012: 2
- FWCI
- 0.44
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Reactive and Functional Polymers (publishedVersion)
- Archivio Istituzionale della Ricerca - Università degli Studi della Campania "Luigi Vanvitelli" (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Science and PVC
- Keywords
- polycaprolactone, ring-opening polymerization, living polymerization, thermal degradation, thermal stability, crystallization kinetics, melting behavior, molecular weight distribution, polydispersity index, end groups, microstructure-property relationship
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review