The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
In Situ Electrochemical Oxidation of Cu2S into CuO Nanowires as a Durable and Efficient Electrocatalyst for Oxygen Evolution Reaction
Open accessAbstract
Development of cost-effective oxygen evolution catalysts is of capital importance for the deployment of large-scale energy-storage systems based on metal–air batteries and reversible fuel cells. In this direction, a wide range of materials have been explored, especially under more favorable alkaline conditions, and several metal chalcogenides have particularly demonstrated excellent performances. However, chalcogenides are thermodynamically less stable than the corresponding oxides and hydroxides under oxidizing potentials in alkaline media. Although this instability in some cases has prevented the application of chalcogenides as oxygen evolution catalysts and it has been disregarded in some others, we propose to use it in our favor to produce high-performance oxygen evolution catalysts. We characterize here the in situ chemical, structural, and morphological transformation during the oxygen evolution reaction (OER) in alkaline media of Cu 2 S into CuO nanowires, mediating the intermediate formation of Cu(OH) 2 . We also test their OER activity and stability under OER operation in alkaline media and compare them with the OER performance of Cu(OH) 2 and CuO nanostructures directly grown on the surface of a copper mesh. We demonstrate here that CuO produced from in situ electrochemical oxidation of Cu 2 S displays an extraordinary electrocatalytic performance toward OER, well above that of CuO and Cu(OH) 2 synthesized without this transformation.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
Metallic Nickel Nitride Nanosheets Realizing Enhanced Electrochemical Water Oxidation
Xu, K., Chen, P., Li, X., Tong, Y., Ding, H., Wu, X., Chu, W., Peng, Z., Wu, C., & Xie, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5119495 · Cited by 1,115
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Self-citationZhang, Y., Ouyang, B., Xu, J., Jia, G., Chen, S., Rawat, R. S., & Fan, H. J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604372 · Cited by 737
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Cited by
Zhao, Y., Adiyeri Saseendran, D. P., Huang, C., Triana, C. A., Marks, W. R., Chen, H., Zhao, H., & Patzke, G. R. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00515 · Cited by 802
Oxygen Evolution Reaction in Alkaline Environment: Material Challenges and Solutions
Xie, X., Du, L., Yan, L., Park, S., Qiu, Y., Sokolowski, J., Wang, W., & Shao, Y. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202110036 · Cited by 792
Du, W., Shi, Y., Zhou, W., Yu, Y., & Zhang, B. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202015723 · Cited by 512
Selvam, N. C. S., Du, L., Xia, B. Y., Yoo, P. J., & You, B. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202008190 · Cited by 289
Ren, G., Liu, B., Xu, X., Jing, P., Wu, J., & Zhang, J. (2024) · Nano Today · doi:10.1016/j.nantod.2024.102315 · Cited by 50
Metadata
- Authors
- Zuo, Y., Liu, Y., Li, J., Du, R., Han, X., Zhang, T., Arbiol, J., Divins, N. J., Llorca, J., Guijarro, N., Sivula, K., & Cabot, A.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-08-15
- Volume
- 31
- Issue
- 18
- Pages
- 7732-7743
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2968260998
- Cited by
- 209
- References
- 8
- FWCI
- 4.43
- Type
- journal article
- Language
- en
- Open access
- green
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- Zuo, Y., Liu, Y., Li, J., Du, R., Han, X., Zhang, T., Arbiol, J., Divins, N. J., Llorca, J., Guijarro, N., Sivula, K., & Cabot, A. (2019). In Situ Electrochemical Oxidation of Cu2S into CuO Nanowires as a Durable and Efficient Electrocatalyst for Oxygen Evolution Reaction. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.9b02790
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