Cited by 36Per- and polyfluoroalkyl substances researchIndoor Air Quality and Microbial ExposureToxic Organic Pollutants Impact

Cloth–Air Partitioning of Neutral Per- and Polyfluoroalkyl Substances (PFAS) in North Carolina Homes during the Indoor PFAS Assessment (IPA) Campaign

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Eichler, Clara M. A., Chang, Naomi Y., Cohen Hubal, Elaine A., Amparo, Daniel E., Zhou, Jiaqi, Surratt, Jason D., Morrison, Glenn C., Turpin, Barbara J.·2023·Environmental Science & Technology

Abstract

Partitioning of per- and polyfluoroalkyl substances (PFAS) to indoor materials, including clothing, may prolong the residence time of PFAS indoors and contribute to exposure. During the Indoor PFAS Assessment (IPA) Campaign, we measured concentrations of nine neutral PFAS in air and cotton cloth in 11 homes in North Carolina, for up to 9 months. Fluorotelomer alcohols (i.e., 6:2 FTOH, 8:2 FTOH, and 10:2 FTOH) are the dominant target species in indoor air, with concentrations ranging from 1.8 to 49 ng m – 3, 1.2 to 53 ng m – 3, and 0.21 to 5.7 ng m – 3, respectively. In cloth, perfluorooctane sulfonamidoethanols (i.e., MeFOSE and EtFOSE) accumulated most significantly over time, reaching concentrations of up to 0.26 ng cm – 2 and 0.24 ng cm – 2, respectively. From paired measurements of neutral PFAS in air and suspended cloth, we derived cloth–air partition coefficients ( K ca ) for 6:2, 8:2, and 10:2 FTOH; ethylperfluorooctane sulfonamide (EtFOSA); MeFOSE; and EtFOSE. Mean log( K ca ) values range from 4.7 to 6.6 and are positively correlated with the octanol–air partition coefficient. We investigated the effect of the cloth storage method on PFAS accumulation and the influence of home characteristics on air concentrations. Temperature had the overall greatest effect. This study provides valuable insights into PFAS distribution, fate, and exposure indoors.

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  • Additional sources of PFAS in urban stormwater include building materials, food packaging waste, laundry effluent, atmospheric deposition from incineration, and AFFF residues.

    “Additional sources of PFAS in urban stormwater include building materials (e.g., sealants, adhesives, roofing materials) [53], food packaging waste in public litter streams [9], laundry effluent from washing PFAS-treated textiles [54], atmospheric deposition from nearby incineration facilities, and residues from historical uses of aqueous film-forming foams (AFFF) [55].”

    From Per- and Polyfluoroalkyl Substances (PFAS) in Urban Stormwater Runoff: Insights from a Roadside Rain Garden (2025) · cites this paper as [54]

    The [54] citation is attached to the claim that laundry effluent from washing PFAS-treated textiles is a source of PFAS in urban stormwater. The Cloth Sampling and Household Clothing Items sections discuss laundered clothing and PFAS found in clothing, but do not address PFAS in laundry effluent or its contribution to stormwater. Searches for washing-related releases, effluent, and stormwater found no passage establishing that pathway. (LLM, conf=0.76)

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Authors
Eichler, C. M. A., Chang, N. Y., Cohen Hubal, E. A., Amparo, D. E., Zhou, J., Surratt, J. D., Morrison, G. C., & Turpin, B. J.
Affiliations
  • University of North Carolina at Chapel Hill (US)
  • U.S. EPA, Center for Public Health and Environmental Assessment, Research Triangle Park, North Carolina 27711, United States
Corresponding author
Turpin, Barbara J.
Venue
Environmental Science & Technology
Published
2023-09-27
Volume
57
Issue
40
Pages
15173-15183
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W4387080454
Cited by
36
References
10
Citations by year
2026: 12 · 2025: 12 · 2024: 12
FWCI
3.10
Type
journal article
Language
en
Open access
Locations
  • Environmental Science & Technology (publishedVersion)
  • PubMed (publishedVersion)
  • PubMed Central (acceptedVersion)
  • Carolina Digital Repository (University of North Carolina at Chapel Hill) (submittedVersion)
  • UNC Libraries
Funders
  • Division of Graduate Education (2020305405)
  • Alfred P. Sloan Foundation (G-2020-13937, G-2017-9794)
  • National Institute for Occupational Safety and Health (T42-OH008673)
Topics
  • Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
  • Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Indoor Air Quality and Microbial Exposure
  • Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Toxic Organic Pollutants Impact
Keywords
per- and polyfluoroalkyl substances, PFAS, indoor air, clothing, fluorotelomer alcohols, perfluorooctane sulfonamide, octanol-air partition coefficient, housing characteristics, temperature effects
MeSH terms
Air Pollutants, Environmental Monitoring, Fluorocarbons, North Carolina

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