The Global Rise of Zero Liquid Discharge for Wastewater Management: Drivers, Technologies, and Future Directions
Open accessAbstract
Zero liquid discharge (ZLD)-a wastewater management strategy that eliminates liquid waste and maximizes water usage efficiency - has attracted renewed interest worldwide in recent years. Although implementation of ZLD reduces water pollution and augments water supply, the technology is constrained by high cost and intensive energy consumption. In this critical review, we discuss the drivers, incentives, technologies, and environmental impacts of ZLD. Within this framework, the global applications of ZLD in the United States and emerging economies such as China and India are examined. We highlight the evolution of ZLD from thermal- to membrane-based processes, and analyze the advantages and limitations of existing and emerging ZLD technologies. The potential environmental impacts of ZLD, notably greenhouse gas emission and generation of solid waste, are discussed and the prospects of ZLD technologies and research needs are highlighted.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
ED can concentrate influent water to higher salinity levels than reverse osmosis.
“ED can concentrate influent water to higher salinity levels than reverse osmosis”
From Electrochemical Direct Lithium Extraction: A Review of Electrodialysis and Capacitive Deionization Technologies (2025) · cites this paper as [72]
ED consumes more energy than reverse osmosis, requiring approximately 7-15 kWh/m3 of feed water to concentrate brine to high salinity levels.
“ED also consumes more energy, requiring approximately 7-15 kWh/m 3 of feed water to concentrate brine to high salinity levels”
From Electrochemical Direct Lithium Extraction: A Review of Electrodialysis and Capacitive Deionization Technologies (2025) · cites this paper as [72]
Cites
Global threats to human water security and river biodiversity
Vörösmarty, C. J., McIntyre, P. B., Gessner, M. O., Dudgeon, D., Prusevich, A., Green, P., Glidden, S., Bunn, S. E., Sullivan, C. A., Liermann, C. R., et al. (2010) · Nature · doi:10.1038/nature09440 · Cited by 7,582 · see citing works
The Future of Seawater Desalination: Energy, Technology, and the Environment
Elimelech, M., & Phillip, W. A. (2011) · Science · doi:10.1126/science.1200488 · Cited by 6,775 · see citing works
Self-citationReverse osmosis desalination: Water sources, technology, and today's challenges
Greenlee, L. F., Lawler, D. F., Freeman, B. D., Marrot, B., & Moulin, P. (2009) · Water Research · doi:10.1016/j.watres.2009.03.010 · Cited by 3,418 · see citing works
Membrane distillation: A comprehensive review
Alkhudhiri, A., Darwish, N. A., & Hilal, N. (2011) · Desalination · doi:10.1016/j.desal.2011.08.027 · Cited by 2,640 · see citing works
Forward osmosis: Principles, applications, and recent developments
Cath, T. Y., Childress, A. E., & Elimelech, M. (2006) · Journal of Membrane Science · doi:10.1016/j.memsci.2006.05.048 · Cited by 2,542 · see citing works
Self-citationSurface Modifications for Antifouling Membranes
Rana, D. K., & Matsuura, T. (2010) · Chemical Reviews · doi:10.1021/cr800208y · Cited by 2,165 · see citing works
Global Water Pollution and Human Health
Schwarzenbach, R. P., Egli, T. W., Hofstetter, T. B., von Gunten, U., & Wehrli, B. (2010) · Annual Review of Environment and Resources · doi:10.1146/annurev-environ-100809-125342 · Cited by 2,113 · see citing works
State-of-the-art of reverse osmosis desalination
Fritzmann, C., Löwenberg, J., Wintgens, T., & Melin, T. (2007) · Desalination · doi:10.1016/j.desal.2006.12.009 · Cited by 1,982 · see citing works
Lawson, K. W., & Lloyd, D. R. (1997) · Journal of Membrane Science · doi:10.1016/s0376-7388(96)00236-0 · Cited by 1,893 · see citing works
Ghaffour, N., Missimer, T. M., & Amy, G. L. (2013) · Desalination · doi:10.1016/j.desal.2012.10.015 · Cited by 1,603 · see citing works
Electrodialysis, a mature technology with a multitude of new applications
Strathmann, H. (2010) · Desalination · doi:10.1016/j.desal.2010.04.069 · Cited by 1,549 · see citing works
Unprecedented 21st century drought risk in the American Southwest and Central Plains
Cook, B. I., Ault, T. R., & Smerdon, J. E. (2015) · Science Advances · doi:10.1126/sciadv.1400082 · Cited by 1,455 · see citing works
A framework for better understanding membrane distillation separation process
El‐Bourawi, M. S., Ding, Z., Ma, R., & Khayet, M. (2006) · Journal of Membrane Science · doi:10.1016/j.memsci.2006.08.002 · Cited by 1,321 · see citing works
Al-Karaghouli, A., & Kazmerski, L. L. (2013) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2012.12.064 · Cited by 1,274 · see citing works
A novel ammonia—carbon dioxide forward (direct) osmosis desalination process
McCutcheon, J. R., McGinnis, R. L., & Elimelech, M. (2005) · Desalination · doi:10.1016/j.desal.2004.11.002 · Cited by 971 · see citing works
Self-citationEmerging desalination technologies for water treatment: A critical review
Subramani, A., & Jacangelo, J. G. (2015) · Water Research · doi:10.1016/j.watres.2015.02.032 · Cited by 963 · see citing works
Al-Obaidani, S., Curcio, E., Macedonio, F., et al. (2008) · Journal of Membrane Science · doi:10.1016/j.memsci.2008.06.006 · Cited by 867 · see citing works
Forward osmosis: Where are we now?
Shaffer, D. L., Werber, J. R., Jaramillo, H., Lin, S., & Elimelech, M. (2014) · Desalination · doi:10.1016/j.desal.2014.10.031 · Cited by 847 · see citing works
Self-citationShaffer, D. L., Chavez, L. H. A., Ben‐Sasson, M., Castrillón, S. R.-V., Yip, N. Y., & Elimelech, M. (2013) · Environmental Science & Technology · doi:10.1021/es401966e · Cited by 821 · see citing works
Self-citationAdvances in Membrane Distillation for Water Desalination and Purification Applications
Camacho, L. M., Dumée, L. F., Zhang, J., Li, J., Duke, M., Gómez, J., & Gray, S. R. (2013) · Water · doi:10.3390/w5010094 · Cited by 777 · see citing works
Membrane-distillation desalination: Status and potential
Alklaibi, A. M., & Lior, N. (2005) · Desalination · doi:10.1016/j.desal.2004.03.024 · Cited by 761 · see citing works
Membrane Distillation and Related Operations—A Review
Curcio, E., & Drioli, E. (2005) · Separation and Purification Reviews · doi:10.1081/spm-200054951 · Cited by 746 · see citing works
Taking the “Waste” Out of “Wastewater” for Human Water Security and Ecosystem Sustainability
Grant, S. B., Saphores, J.-D. M., FELDMAN, D. L., Hamilton, A. J., Fletcher, T. D., Cook, P. L. M., Stewardson, M. J., Sanders, B. F., Levin, L. A., Ambrose, R. F., et al. (2012) · Science · doi:10.1126/science.1216852 · Cited by 659 · see citing works
Xie, M., Shon, H. K., Gray, S. R., & Elimelech, M. (2015) · Water Research · doi:10.1016/j.watres.2015.11.045 · Cited by 584 · see citing works
Self-citationEnergy requirements of ammonia–carbon dioxide forward osmosis desalination
McGinnis, R. L., & Elimelech, M. (2007) · Desalination · doi:10.1016/j.desal.2006.08.012 · Cited by 576 · see citing works
Self-citationHigh recovery of concentrated RO brines using forward osmosis and membrane distillation
Martinetti, C. R., Childress, A. E., & Cath, T. Y. (2009) · Journal of Membrane Science · doi:10.1016/j.memsci.2009.01.003 · Cited by 569 · see citing works
Thin-Film Composite Polyamide Membranes Functionalized with Biocidal Graphene Oxide Nanosheets
Perreault, F., Tousley, M. E., & Elimelech, M. (2013) · Environmental Science & Technology Letters · doi:10.1021/ez4001356 · Cited by 537 · see citing works
Self-citationZhu, J., Hu, K., Lu, X., Huang, X., Liu, K., & Wu, X. (2015) · Energy · doi:10.1016/j.energy.2015.08.098 · Cited by 467 · see citing works
Electrodialysis‐based separation technologies: A critical review
Xu, T., & Huang, C. (2008) · AIChE Journal · doi:10.1002/aic.11643 · Cited by 428 · see citing works
Direct application of geothermal energy: 2005 Worldwide review
Lund, J., Freeston, D. H., & Boyd, T. L. (2005) · Geothermics · doi:10.1016/j.geothermics.2005.09.003 · Cited by 428 · see citing works
Recent progress of membrane distillation using electrospun nanofibrous membrane
Tijing, L. D., Choi, J.-S., Lee, S., et al. (2013) · Journal of Membrane Science · doi:10.1016/j.memsci.2013.11.022 · Cited by 381 · see citing works
Pilot demonstration of the NH3/CO2 forward osmosis desalination process on high salinity brines
McGinnis, R. L., Hancock, N. T., Nowosielski-Slepowron, M. S., & McGurgan, G. D. (2012) · Desalination · doi:10.1016/j.desal.2012.11.032 · Cited by 368 · see citing works
The treatment of brewery wastewater for reuse: State of the art
Simate, G. S., Cluett, J., Iyuke, S. E., Musapatika, E. T., Ndlovu, S., Walubita, L. F., & Álvarez, A. E. (2011) · Desalination · doi:10.1016/j.desal.2011.02.035 · Cited by 363 · see citing works
Coal chemical industry and its sustainable development in China
Xie, K., Li, W., & Zhao, W. T. (2009) · Energy · doi:10.1016/j.energy.2009.05.029 · Cited by 340 · see citing works
Treatment technologies for reverse osmosis concentrate volume minimization: A review
Subramani, A., & Jacangelo, J. G. (2013) · Separation and Purification Technology · doi:10.1016/j.seppur.2013.12.004 · Cited by 334 · see citing works
Water scarcity challenges to business
Hoekstra, A. Y. (2014) · Nature Climate Change · doi:10.1038/nclimate2214 · Cited by 286 · see citing works
China's water security: Current status, emerging challenges and future prospects
Jiang, Y. (2015) · Environmental Science & Policy · doi:10.1016/j.envsci.2015.06.006 · Cited by 277 · see citing works
Energy and Air Emission Effects of Water Supply
Stokes-Draut, J. R., & Horvath, A. (2009) · Environmental Science & Technology · doi:10.1021/es801802h · Cited by 276 · see citing works
Pre-treatment strategies for seawater desalination by reverse osmosis system
Prihasto, N., Liu, Q., & Kim, S. (2009) · Desalination · doi:10.1016/j.desal.2008.09.010 · Cited by 266 · see citing works
Desalination and water recycling by air gap membrane distillation
Meindersma, G. W., Guijt, C. M., & de Haan, A. B. (2006) · Desalination · doi:10.1016/j.desal.2005.04.088 · Cited by 262 · see citing works
Ye, G., Lee, J., Perreault, F., & Elimelech, M. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b06647 · Cited by 256 · see citing works
Self-citationPilot studies on high recovery BWRO-EDR for near zero liquid discharge approach
Oren, Y., Korngold, E., Daltrophe, N., Messalem, R. M., Volkman, Y., Aronov, L., Weismann, M., Bouriakov, N., Glueckstern, P., & Gilron, J. (2010) · Desalination · doi:10.1016/j.desal.2010.06.010 · Cited by 243 · see citing works
Mining Critical Metals and Elements from Seawater: Opportunities and Challenges
Diallo, M. S., Kotte, M. R., & Cho, M. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b00463 · Cited by 218 · see citing works
Tufa, R. A., Curcio, E., Brauns, E., et al. (2015) · Journal of Membrane Science · doi:10.1016/j.memsci.2015.09.008 · Cited by 215 · see citing works
Lin, S., Yip, N. Y., & Elimelech, M. (2013) · Journal of Membrane Science · doi:10.1016/j.memsci.2013.11.016 · Cited by 214 · see citing works
Self-citationOn the cost of electrodialysis for the desalination of high salinity feeds
McGovern, R. K., Weiner, A. M., Sun, L., Chambers, C. G., Zubair, S. M., & Lienhard, J. H. (2014) · Applied Energy · doi:10.1016/j.apenergy.2014.09.050 · Cited by 190 · see citing works
Quantity, Quality, and Availability of Waste Heat from United States Thermal Power Generation
Gingerich, D. B., & Mauter, M. S. (2015) · Environmental Science & Technology · doi:10.1021/es5060989 · Cited by 188 · see citing works
Influence of colloidal fouling and feed water recovery on salt rejection of RO and NF membranes
Lee, S., Cho, J., & Elimelech, M. (2004) · Desalination · doi:10.1016/s0011-9164(04)90013-6 · Cited by 155 · see citing works
Self-citationDuong, H. C., Cooper, P. W., Nelemans, B., Cath, T. Y., & Nghiem, L. D. (2015) · Desalination · doi:10.1016/j.desal.2015.07.009 · Cited by 141 · see citing works
Electrodialysis of brine solutions discharged from an RO plant
Korngold, E., Aronov, L., & Daltrophe, N. (2009) · Desalination · doi:10.1016/j.desal.2008.04.008 · Cited by 132 · see citing works
Environmental Issues of Desalination
Younos, T. (2009) · Journal of Contemporary Water Research & Education · doi:10.1111/j.1936-704x.2005.mp132001003.x · Cited by 132 · see citing works
Zhang, C., Zhong, L., Fu, X., et al. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.5b05374 · Cited by 131 · see citing works
Xevgenos, D., Moustakas, K. G., Malamis, D., et al. (2014) · Desalination and Water Treatment · doi:10.1080/19443994.2014.984927 · Cited by 126 · see citing works
Cost effective electrodialytic seawater desalination
Turek, M. (2003) · Desalination · doi:10.1016/s0011-9164(02)01130-x · Cited by 120 · see citing works
Vishnu, G., Palanisamy, S., & Joseph, K. (2007) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2007.06.005 · Cited by 100 · see citing works
RO concentrate minimization by electrodialysis: Techno-economic analysis and environmental concerns
Zhang, Y., Ghyselbrecht, K., Vanherpe, R., Meesschaert, B. D., Pinoy, L., & der Bruggen, B. V. (2012) · Journal of Environmental Management · doi:10.1016/j.jenvman.2012.04.020 · Cited by 96 · see citing works
Loganathan, K., Chelme‐Ayala, P., & El‐Din, M. G. (2015) · Desalination · doi:10.1016/j.desal.2015.01.020 · Cited by 87 · see citing works
Salt production from coal-mine brine in ED–evaporation–crystallization system
Turek, M., Dydo, P., & Klimek, R. (2005) · Desalination · doi:10.1016/j.desal.2005.03.047 · Cited by 70 · see citing works
Zeroing in on ZLD Technologies for Inland Desalination
Bond, R. G., & Veerapaneni, S. (2008) · American Water Works Association · doi:10.1002/j.1551-8833.2008.tb09722.x · Cited by 68 · see citing works
Electrodialytic desalination and concentration of coal-mine brine
Turek, M. (2004) · Desalination · doi:10.1016/s0011-9164(04)00069-4 · Cited by 60 · see citing works
Inland Desalination: Challenges and Research Needs
Brady, P. V., Kottenstette, R. J., Mayer, T. M., & Hightower, M. (2009) · Journal of Contemporary Water Research & Education · doi:10.1111/j.1936-704x.2005.mp132001007.x · Cited by 57 · see citing works
Water Treatment Capacity of Forward-Osmosis Systems Utilizing Power-Plant Waste Heat
Zhou, X., Gingerich, D. B., & Mauter, M. S. (2015) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.5b00460 · Cited by 52 · see citing works
Stanford, B. D., Leising, J. F., Bond, R. G., et al. (2009) · Sustainability science and engineering · doi:10.1016/s1871-2711(09)00211-6 · Cited by 49 · see citing works
Loganathan, K., Chelme‐Ayala, P., & El‐Din, M. G. (2015) · Journal of Environmental Management · doi:10.1016/j.jenvman.2015.09.019 · Cited by 47 · see citing works
Neilly, A., Jegatheesan, V., & Shu, L. (2009) · Desalination and Water Treatment · doi:10.5004/dwt.2009.843 · Cited by 42 · see citing works
Pretreatment of Coal Gasification Wastewater by Acidification Demulsion
Zhang, W., Ma, J., Yang, S., et al. (2006) · Chinese Journal of Chemical Engineering · doi:10.1016/s1004-9541(06)60090-6 · Cited by 35 · see citing works
Achieving Zero Liquid Discharge in SAGD Heavy Oil Recovery
Heins, W. F., & Schooley, K. (2004) · Journal of Canadian Petroleum Technology · doi:10.2118/04-08-01 · Cited by 31 · see citing works
A zero-liquid-discharge scheme for vanadium extraction process by electrodialysis-based technology
Wang, M., Xing, H.-B., Jia, Y.-X., et al. (2015) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2015.05.042 · Cited by 28 · see citing works
Urban Water Resources Quota Management: The Core Strategy for Water Demand Management in China
Jiang, Y., Chen, Y., Younos, T., et al. (2010) · AMBIO · doi:10.1007/s13280-010-0080-x · Cited by 22 · see citing works
Water reuse and zero liquid discharge: a sustainable water resource solution
Durham, B., & Mierzejewski, M. (2003) · Water Science & Technology Water Supply · doi:10.2166/ws.2003.0050 · Cited by 21 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Artificial intelligence for waste management in smart cities: a review
Fang, B., Yu, J., Chen, Z., Osman, A. I., Farghali, M., Ihara, I., Hamza, E. H., Rooney, D. W., & Yap, P.-S. (2023) · Environmental Chemistry Letters · doi:10.1007/s10311-023-01604-3 · Cited by 629 · see citing works
Gurreri, L., Tamburini, A., Cipollina, A., & Micale, G. (2020) · Membranes · doi:10.3390/membranes10070146 · Cited by 492 · see citing works
Arola, K., Van der Bruggen, B., Mänttäri, M., & Kallioinen, M. (2019) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643389.2019.1594519 · Cited by 148 · see citing works
Managing and treating per‐ and polyfluoroalkyl substances (PFAS) in membrane concentrates
Tow, E. W., Ersan, M. S., Kum, S., Lee, T., Speth, T. F., Owen, C., Bellona, C., Nadagouda, M. N., Mikelonis, A. M., Westerhoff, P., et al. (2021) · AWWA Water Science · doi:10.1002/aws2.1233 · Cited by 146 · see citing works
“…membrane treatment processes (or any residual waste stream) may be significantly reduced via the application of additional RO and NF membrane treatment processes in batch or semi-batch configurations, which are optimized for higher recovery (Bond & Veerapaneni, 2008; Tong & Elimelech, 2016).”
Reverse Osmosis Concentrate: Physicochemical Characteristics, Environmental Impact, and Technologies
Valdés, H., Saavedra, A., Flores, M., Vera-Puerto, I., Aviña, H., & Belmonte, M. (2021) · Membranes · doi:10.3390/membranes11100753 · Cited by 52 · see citing works
Park, J., Lee, J., Shim, I.-T., Kim, E., Nam, S.-H., Koo, J.-W., & Hwang, T.-M. (2025) · Resources · doi:10.3390/resources14020027 · Cited by 44 · see citing works
“However, ED also consumes more energy, requiring approximately 7–15 kWh/m 3 of feed water to concentrate brine to high salinity levels [72].”
Robbins, C. A., Du, X., Bradley, T. H., Quinn, J. C., Bandhauer, T. M., Conrad, S. A., Carlson, K. H., & Tong, T. (2022) · Resources, Conservation and Recycling · doi:10.1016/j.resconrec.2021.106011 · Cited by 36 · see citing works
Self-citation
- Authors
- Tong, T., & Elimelech, M.
- Affiliations
- Yale University (US)
- Corresponding author
- Elimelech, Menachem
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-06-08
- Volume
- 50
- Issue
- 13
- Pages
- 6846-6855
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2417511329
- Cited by
- 1,126
- References
- 70
- Citations by year
- 2026: 140 · 2025: 159 · 2024: 132 · 2023: 140 · 2022: 135 · 2021: 151 · 2020: 103 · 2019: 76 · 2018: 52 · 2017: 34 · 2016: 4
- FWCI
- 32.75
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Locations
- Environmental Science & Technology (publishedVersion, other-oa)
- PubMed (publishedVersion)
- Funders
- Division of Engineering Education and Centers (1449500)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Membrane Separation Technologies
- Physical Sciences › Environmental Science › Waste Management and Disposal › Wastewater Treatment and Reuse
- Physical Sciences › Engineering › Computational Mechanics › Water and Wastewater Treatment
- Keywords
- zero liquid discharge, wastewater management, water reuse, thermal evaporation, energy consumption, greenhouse gas emissions, solid waste generation, environmental impact, emerging markets, water pollution reduction
- MeSH terms
- China, Technology, Water Pollution, Water Supply, Wastewater
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review