Converting Polyvinyl Chloride Plastic Wastes to Carbonaceous Materials via Room-Temperature Dehalogenation for High-Performance Supercapacitor
Abstract
Polyvinyl chloride (PVC) plastics are widely applicable in our daily life; however, their overuse and extremely high resistance to recycling/disposal have caused serious challenges to our environment. In this study, we proposed an effective and green method to convert PVC plastics to carbonaceous materials via KOH-assisted room-temperature dehalogenation, along with the formation of clean byproducts of KCl and H 2 O. Thereof, high-quality porous carbon materials are obtainable through performing simple annealing on the above-mentioned carbonaceous materials. The as-resulted carbon materials derived from PVC plastics were fabricated into electrodes for supercapacitor application. Remarkably, the porous carbon material derived from PVC plastic wrap (PW-C) exhibited excellent performance for aqueous symmetric supercapacitor. The specific capacitance reached up to 399 and 363 F g –1 (at 1.0 A g –1 ) in 6.0 mol L –1 KOH and 1.0 mol L –1 H 2 SO 4 electrolytes, respectively. Meanwhile, PW-C showed very good rate capability and cycling stability in both electrolytes. Therefore, our developed method is capable of treating PVC plastic wastes safely and efficiently and converting them into valued-added porous carbon electrode materials, which may find very soon practical implantations.
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During incineration or landfill of polyvinyl chloride, extremely harmful by-products of Cl2, HCl, and organochlorinated compounds are emitted, leading to serious environmental pollution.
“During the process of incineration or landfill, extremely harmful by-products of Cl 2 , HCl, and organochlorinated compounds are emitted, which will lead to serious environmental pollution (Chang et al. 2018).”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Chang et al. 2018
Carbon materials derived from polyvinyl chloride used as electrodes in water-based symmetrical supercapacitors exhibited a specific capacitance of 399 F/g at 1.0 A/g.
“In water-based symmetrical supercapacitors, carbon materials derived from polyvinyl chloride were used as electrodes and exhibited excellent performance.At 1.0 A/g, the specific capacitance reached 399 F/g (Chang et al. 2018).”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Chang et al. 2018
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- Authors
- Chang, Y., Pang, Y., Dang, Q., Kumar, A., Zhang, G., Chang, Z., & Sun, X.
- Affiliations
- State Key Laboratory of Chemical Resource Engineering (CN)
- Shandong University of Science and Technology (CN)
- Corresponding author
- Pang, Yingchun
- Zhang, Guoxin
- Chang, Zheng
- Venue
- ACS Applied Energy Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-10
- ISSN
- 2574-0962 (ISSN-L)
- OpenAlex
- W2891475627
- Cited by
- 50
- References
- 42
- Citations by year
- 2026: 2 · 2025: 9 · 2024: 5 · 2023: 17 · 2022: 11 · 2021: 1 · 2020: 1 · 2019: 4
- FWCI
- 0.45
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Applied Energy Materials (publishedVersion)
- Funders
- Ministry of Science and Technology of the People's Republic of China (2016YFF0204402)
- National Natural Science Foundation of China (21471014, 21701101)
- Shandong Joint Fund of Outstanding Young Talents (ZR2017BB018)
- Scientific Research Foundation for Recruited Talents, Shandong University of Science and Technology (2017RCJJ059)
- Shandong Scientific Research Awards Foundation for Outstanding Young Scientists (ZR2018JL010)
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Mechanical Engineering › Fiber-reinforced polymer composites
- Keywords
- polyvinyl chloride, plastic recycling, porous carbon, supercapacitor electrodes, symmetric supercapacitor, specific capacitance, plastic waste valorization
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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