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A 3D Nanostructure Based on Transition-Metal Phosphide Decorated Heteroatom-Doped Mesoporous Nanospheres Interconnected with Graphene: Synthesis and Applications
Abstract
A novel three-dimensional nanostructure based on cobalt phosphide nanoparticles (Co 2 P NPs) and heteroatom-doped mesoporous carbon spheres interconnected with graphene (3D PZM@Co 2 P@RGO) was facilely synthesized for the first time, and it was used for enhancing the flame retardancy and toxicity suppression of epoxy resins (EP) via a synergistic effect. Herein, the cross-linked polyphosphazene hollow spheres (PZM) were used as templates for the fabrication of 3D architecture. The 3D architecture based on Co 2 P-decorated heteroatom-doped carbon sphere and reduced graphene oxide was prepared via a carbonization procedure followed by a hydrothermal self-assembly strategy. The as-prepared material exhibits excellent catalytic activity with regard to the combustion process. Notably, inclusion of incorporating PZM@Co 2 P@RGO resulted in a dramatic reduction of the fire hazards of EP, such as a 47.9% maximum decrease in peak heat release rate and a 29.2% maximum decrease in total heat release, lower toxic CO yield, and formation of high-graphitized protective char layer. In addition, the mechanism for flame retardancy and toxicity suppression was proposed. It is reasonable to know that the improved flame-retardant performance for EP nanocomposites is attributed to tripartite cooperative effect from respective components (Co 2 P NPs and RGO) plus the heteroatom-doped carbon spheres.
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“Recent results demonstrated that catalyst activity for HER can be boosted by assembling them on some highly conductive nanocarbon composites, e.g., reduced graphene oxide (rGO), carbon nanotubes (CNTs), and other MoSx-carbon electrode materials.11,24,34−39”
From Thiomolybdate [Mo3S13]2– Nanoclusters Anchored on Reduced Graphene Oxide-Carbon Nanotube Aerogels for Efficient Electrocatalytic Hydrogen Evolution (2017) · cites this paper as [24]
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“Also, MoS2 nanoparticles exerted favorably catalytic activity for HER.11,24−27”
From Thiomolybdate [Mo3S13]2– Nanoclusters Anchored on Reduced Graphene Oxide-Carbon Nanotube Aerogels for Efficient Electrocatalytic Hydrogen Evolution (2017) · cites this paper as [24]
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- 10.1039/C5CS00434A · DOI · Paper page
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Cited by
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Metadata
- Authors
- Qiu, S., Xing, W., Mu, X., Feng, X., Ma, C., Yuen, R. K. K., & Hu, Y.
- Affiliations
- University of Science and Technology of China (CN)
- Corresponding author
- Xing, Weiyi
- Hu, Yuan
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-11-17
- Volume
- 8
- Issue
- 47
- Pages
- 32528-32540
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2553543101
- Cited by
- 58
- References
- 48
- Citations by year
- 2026: 2 · 2025: 2 · 2023: 9 · 2022: 5 · 2021: 7 · 2020: 11 · 2019: 7 · 2018: 9 · 2017: 6
- FWCI
- 5.02
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Applied Materials & Interfaces (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Research Grants Council, University Grants Committee (CityU 11301015, T32-101/15-R)
- National Natural Science Foundation of China (21374111, 51675502)
- Natural Science Foundation of Anhui Province (1608085QE99)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Flame retardant materials and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Epoxy Resin Curing Processes
- Physical Sciences › Engineering › Safety, Risk, Reliability and Quality › Fire dynamics and safety research
- Keywords
- cobalt phosphide nanoparticles, transition metal phosphides, reduced graphene oxide, three-dimensional nanostructures, combustion catalysis, heat release rate, carbon monoxide suppression, hydrothermal self-assembly, carbonization, nanocomposites
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