The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
Garnet Solid Electrolyte Protected Li-Metal Batteries
Abstract
Garnet-type solid state electrolyte (SSE) is a promising candidate for high performance lithium (Li)-metal batteries due to its good stability and high ionic conductivity. One of the main challenges for garnet solid state batteries is the poor solid–solid contact between the garnet and electrodes, which results in high interfacial resistance, large polarizations, and low efficiencies in batteries. To address this challenge, in this work gel electrolyte is used as an interlayer between solid electrolyte and solid electrodes to improve their contact and reduce their interfacial resistance. The gel electrolyte has a soft structure, high ionic conductivity, and good wettability. Through construction of the garnet/gel interlayer/electrode structure, the interfacial resistance of the garnet significantly decreased from 6.5 × 10 4 to 248 Ω cm 2 for the cathode and from 1.4 × 10 3 to 214 Ω cm 2 for the Li-metal anode, successfully demonstrating a full cell with high capacity (140 mAh/g for LiFePO 4 cathode) over 70 stable cycles in room temperature. This work provides a binary electrolyte consisting of gel electrolyte and solid electrolyte to address the interfacial challenge of solid electrolyte and electrodes and the demonstrated hybrid battery presents a promising future for battery development with high energy and good safety.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Issues and challenges facing rechargeable lithium batteries
Tarascon, J.-M., & Armand, M. (2001) · Nature · doi:10.1038/35104644 · Cited by 21,130
Challenges for Rechargeable Li Batteries
Goodenough, J. B., & Kim, Y. (2010) · Chemistry of Materials · doi:10.1021/cm901452z · Cited by 10,943
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
Ji, X., Lee, K. T., & Nazar, L. F. (2009) · Nature Materials · doi:10.1038/nmat2460 · Cited by 5,988
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
A lithium superionic conductor
Kamaya, N., Homma, K., Yamakawa, Y., Hirayama, M., Kanno, R., Yonemura, M., Kamiyama, T., Kato, Y., Hama, S., Kawamoto, K., et al. (2011) · Nature Materials · doi:10.1038/nmat3066 · Cited by 4,978
Lithium metal anodes for rechargeable batteries
Xu, W., Wang, J., Ding, F., Chen, X., Nasybulin, E., Zhang, Y., & Zhang, J.-G. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee40795k · Cited by 4,704
Lithium battery chemistries enabled by solid-state electrolytes
Manthiram, A., Yu, X., & Wang, S. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.103 · Cited by 4,689
Fast Lithium Ion Conduction in Garnet‐Type Li7La3Zr2O12
Murugan, R., Thangadurai, V., & Weppner, W. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200701144 · Cited by 3,250
Lithium−Air Battery: Promise and Challenges
Girishkumar, G., McCloskey, B., Luntz, A. C., Swanson, S., & Wilcke, W. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1005384 · Cited by 2,528
Negating interfacial impedance in garnet-based solid-state Li metal batteries
Han, X., Gong, Y., Fu, K., He, X., Hitz, G. T., Dai, J., Pearse, A., Liu, B., Wang, H., Rubloff, G., et al. (2017) · Nature Materials · doi:10.1038/nmat4821 · Cited by 2,025
Self-citationZhu, Y., He, X., & Mo, Y. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b07517 · Cited by 1,936
Lin, D., Liu, Y., Liang, Z., Lee, H.-W., Sun, J., Wang, H., Yan, K., Xie, J., & Cui, Y. (2016) · Nature Nanotechnology · doi:10.1038/nnano.2016.32 · Cited by 1,798
A Review of Solid Electrolyte Interphases on Lithium Metal Anode
Cheng, X., Zhang, R., Zhao, C., Wei, F., Zhang, J., & Zhang, Q. (2016) · Advanced Science · doi:10.1002/advs.201500213 · Cited by 1,786
The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces
Monroe, C., & Newman, J. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1850854 · Cited by 1,701
Interface Stability in Solid-State Batteries
Richards, W. D., Miara, L. J., Wang, Y., Kim, J. C., & Ceder, G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04082 · Cited by 1,652
Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives
Quartarone, E., & Mustarelli, P. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00081g · Cited by 1,607
Yang, C.-P., Yin, Y.-X., Zhang, S.-F., Li, N.-W., & Guo, Y.-G. (2015) · Nature Communications · doi:10.1038/ncomms9058 · Cited by 1,589
Self-citationAn Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes
Li, N., Yin, Y., Yang, C., & Guo, Y. (2016) · Advanced Materials · doi:10.1002/adma.201504526 · Cited by 1,577
Self-citationGarnet-type solid-state fast Li ion conductors for Li batteries: critical review
Thangadurai, V., Narayanan, S., & Pinzaru, D. (2014) · Chemical Society Reviews · doi:10.1039/c4cs00020j · Cited by 1,534
Inorganic solid Li ion conductors: An overview
Knauth, P. (2009) · Solid State Ionics · doi:10.1016/j.ssi.2009.03.022 · Cited by 1,170
Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte
Zhou, W., Wang, S., Li, Y., Xin, S., Manthiram, A., & Goodenough, J. B. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05341 · Cited by 1,006
Cheng, X., Hou, T., Zhang, R., Peng, H., Zhao, C., Huang, J., & Zhang, Q. (2016) · Advanced Materials · doi:10.1002/adma.201506124 · Cited by 994
Review on composite polymer electrolytes for lithium batteries
Manuel Stephan, A., & Nahm, K. S. (2006) · Polymer · doi:10.1016/j.polymer.2006.05.069 · Cited by 971
Detection of subsurface structures underneath dendrites formed on cycled lithium metal electrodes
Harry, K. J., Hallinan, D. T., Parkinson, D. Y., MacDowell, A. A., & Balsara, N. P. (2014) · Nature Materials · doi:10.1038/nmat3793 · Cited by 868
Fu, K. (., Gong, Y., Liu, B., Zhu, Y., Xu, S., Yao, Y., Luo, W., Wang, C., Lacey, S. D., Dai, J., et al. (2017) · Science Advances · doi:10.1126/sciadv.1601659 · Cited by 842
Self-citationIn situ NMR observation of the formation of metallic lithium microstructures in lithium batteries
Bhattacharyya, R., Key, B., Chen, H., Best, A. S., Hollenkamp, A. F., & Grey, C. P. (2010) · Nature Materials · doi:10.1038/nmat2764 · Cited by 813
A Stable Thin‐Film Lithium Electrolyte: Lithium Phosphorus Oxynitride
Yu, X., Bates, J. B., Jellison, G. E., & Hart, F. X. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837443 · Cited by 808
Chen, R., Qu, W., Guo, X., Li, L., & Wu, F. (2016) · Materials Horizons · doi:10.1039/c6mh00218h · Cited by 797
A review of lithium and non-lithium based solid state batteries
Kim, J. G., Son, B., Mukherjee, S., Schuppert, N., Bates, A., Kwon, O., Choi, M. J., Chung, H. Y., & Park, S. (2015) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.02.054 · Cited by 783
Yan, K., Lee, H.-W., Gao, T., Zheng, G., Yao, H., Wang, H., Lu, Z., Zhou, Y., Liang, Z., Liu, Z., et al. (2014) · Nano Letters · doi:10.1021/nl503125u · Cited by 742
Structure and dynamics of the fast lithium ion conductor “Li7La3Zr2O12”
Buschmann, H., Dölle, J., Berendts, S., Kuhn, A., Bottke, P., Wilkening, M., Heitjans, P., Senyshyn, A., Ehrenberg, H., Lotnyk, A., et al. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp22108f · Cited by 695
Transition from Superlithiophobicity to Superlithiophilicity of Garnet Solid-State Electrolyte
Luo, W., Gong, Y., Zhu, Y., Fu, K. K., Dai, J., Lacey, S. D., Wang, C., Liu, B., Han, X., Mo, Y., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06777 · Cited by 671
Self-citationHigh lithium ionic conductivity in the garnet-type oxide Li7−X La3(Zr2−X, NbX)O12 (X=0–2)
Ohta, S., Kobayashi, T., & Asaoka, T. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2010.11.089 · Cited by 665
Electrical properties of amorphous lithium electrolyte thin films
BATES, J. (1992) · Solid State Ionics · doi:10.1016/0167-2738(92)90442-r · Cited by 600
Polymer Nanofiber-Guided Uniform Lithium Deposition for Battery Electrodes
Liang, Z., Zheng, G., Liu, C., Liu, N., Li, W., Yan, K., Yao, H., Hsu, P.-C., Chu, S., & Cui, Y. (2015) · Nano Letters · doi:10.1021/nl5046318 · Cited by 540
Sharafi, A., Meyer, H. M., Nanda, J., Wolfenstine, J., & Sakamoto, J. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.10.053 · Cited by 536
Zeng, X.-X., Yin, Y.-X., Li, N.-W., Du, W.-C., Guo, Y.-G., & Wan, L.-J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b10088 · Cited by 459
Wang, C., Yang, Y., Liu, X., Zhong, H., Xu, H., Xu, Z., Shao, H., & Ding, F. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b00336 · Cited by 419
Fast Solid-State Li Ion Conducting Garnet-Type Structure Metal Oxides for Energy Storage
Thangadurai, V., Pinzaru, D., Narayanan, S., & Baral, A. K. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/jz501828v · Cited by 249
An Aqueous Rechargeable Lithium Battery Using Coated Li Metal as Anode
Wang, X., Hou, Y., Zhu, Y., Wu, Y., & Holze, R. (2013) · Scientific Reports · doi:10.1038/srep01401 · Cited by 235
Zhang, P., Yang, L. C., Li, L. L., Ding, M. L., Wu, Y. P., & Holze, R. (2011) · Journal of Membrane Science · doi:10.1016/j.memsci.2011.05.043 · Cited by 169
Hybrid Lithium–Sulfur Batteries with a Solid Electrolyte Membrane and Lithium Polysulfide Catholyte
Yu, X., Bi, Z., Zhao, F., & Manthiram, A. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b04209 · Cited by 126
Padarti, J. K., Nishimura, K., Senna, M., Düvel, A., Heitjans, P., Kawaguchi, T., Sakamoto, N., Wakiya, N., & SUZUKI, H. (2016) · RSC Advances · doi:10.1039/c6ra09695f · Cited by 95
Rawlence, M., Garbayo, Í., Buecheler, S., & Rupp, J. L. M. (2016) · Nanoscale · doi:10.1039/c6nr04162k · Cited by 80
Anisotropic ion transport in nanostructured solid polymer electrolytes
Cheng, S., Smith, D. M., Pan, Q., Wang, S., & Li, C. Y. (2015) · RSC Advances · doi:10.1039/c5ra05240h · Cited by 74
Cheng, S., Smith, D. M., & Li, C. Y. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00972 · Cited by 65
Cited by
Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes
Banerjee, A., Wang, X., Fang, C., Wu, E. A., & Meng, Y. S. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00101 · Cited by 1,526
Gao, Z., Sun, H., Fu, L., Ye, F., Zhang, Y., Luo, W., & Huang, Y. (2018) · Advanced Materials · doi:10.1002/adma.201705702 · Cited by 1,300
Artificial Interphases for Highly Stable Lithium Metal Anode
Xu, R., Cheng, X.-B., Yan, C., Zhang, X.-Q., Xiao, Y., Zhao, C.-Z., Huang, J.-Q., & Zhang, Q. (2019) · Matter · doi:10.1016/j.matt.2019.05.016 · Cited by 721
Liu, W., Liu, P., & Mitlin, D. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202002297 · Cited by 687
Samson, A. J., Hofstetter, K., Bag, S., & Thangadurai, V. (2019) · Energy & Environmental Science · doi:10.1039/c9ee01548e · Cited by 502
Metadata
- Authors
- Liu, B., Gong, Y., Fu, K., Han, X., Yao, Y., Pastel, G., Yang, C., Xie, H., Wachsman, E. D., & Hu, L.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-05-22
- Volume
- 9
- Issue
- 22
- Pages
- 18809-18815
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2613266122
- Cited by
- 287
- References
- 47
- FWCI
- 14.66
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
