The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Electrodeposited Zn Dendrites with Enhanced CO Selectivity for Electrocatalytic CO2 Reduction
Abstract
Electrochemical CO 2 reduction is a key reaction for CO 2 conversion to valuable fuels and chemicals. Because of the high stability of the CO 2 molecule, a catalyst is typically required to minimize the energy input and improve reaction rates needed for device level commercialization. In this paper, we report a nanostructured Zn dendrite catalyst that is able to electrochemically reduce CO 2 to CO in an aqueous bicarbonate electrolyte with greatly enhanced properties. The catalytic activity is over an order of magnitude higher than that of bulk Zn counterparts, with a CO faradaic efficiency around 3-fold higher. The stability of the Zn electrode under realistic CO 2 electrolysis conditions was explored using scanning electron microscopy and in situ/operando X-ray absorption spectroscopy techniques. The results clearly demonstrate that nanostructured and bulk Zn catalysts are structurally stable at potentials more negative than −0.7 V versus RHE, whereas severe chemical oxidation occurs at more positive potentials.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
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Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
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Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
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Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
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Nitrogen-Based Catalysts for the Electrochemical Reduction of CO 2 to CO
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
CO2 Reduction: From the Electrochemical to Photochemical Approach
Wu, J., Huang, Y., Ye, W., & Li, Y. (2017) · Advanced Science · doi:10.1002/advs.201700194 · Cited by 937
Ren, D., Ang, B. S.-H., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02162 · Cited by 721
Highly Efficient, Selective, and Stable CO2 Electroreduction on a Hexagonal Zn Catalyst
Won, D. H., Shin, H., Koh, J., Chung, J., Lee, H. S., Kim, H., & Woo, S. I. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602888 · Cited by 363
Metadata
- Authors
- Rosen, J., Hutchings, G. S., Lu, Q., Forest, R. V., Moore, A., & Jiao, F.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-07-01
- Volume
- 5
- Issue
- 8
- Pages
- 4586-4591
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2493300873
- Cited by
- 447
- References
- 10
- FWCI
- 9.97
- Type
- journal article
- Language
- en
- Open access
- closed
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