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Electrodeposited Zn Dendrites with Enhanced CO Selectivity for Electrocatalytic CO2 Reduction
Abstract
Electrochemical CO 2 reduction is a key reaction for CO 2 conversion to valuable fuels and chemicals. Because of the high stability of the CO 2 molecule, a catalyst is typically required to minimize the energy input and improve reaction rates needed for device level commercialization. In this paper, we report a nanostructured Zn dendrite catalyst that is able to electrochemically reduce CO 2 to CO in an aqueous bicarbonate electrolyte with greatly enhanced properties. The catalytic activity is over an order of magnitude higher than that of bulk Zn counterparts, with a CO faradaic efficiency around 3-fold higher. The stability of the Zn electrode under realistic CO 2 electrolysis conditions was explored using scanning electron microscopy and in situ/operando X-ray absorption spectroscopy techniques. The results clearly demonstrate that nanostructured and bulk Zn catalysts are structurally stable at potentials more negative than −0.7 V versus RHE, whereas severe chemical oxidation occurs at more positive potentials.
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Metadata
- Authors
- Rosen, J., Hutchings, G. S., Lu, Q., Forest, R. V., Moore, A., & Jiao, F.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-07-01
- Volume
- 5
- Issue
- 8
- Pages
- 4586-4591
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2493300873
- Cited by
- 447
- References
- 25
- FWCI
- 9.97
- Type
- journal article
- Language
- en
- Open access
- closed
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