The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Surface Oxidized Cobalt-Phosphide Nanorods As an Advanced Oxygen Evolution Catalyst in Alkaline Solution
Abstract
Electrochemical water splitting in alkaline solution plays a growing role in alternative energy devices due to the need for clean and sustainable energy. However, catalysts that are active for both hydrogen evolution and oxygen evolution reactions are rare. Herein, we demonstrate that cobalt phosphide (CoP), which was synthesized via the hydrothermal route and has been shown to have hydrogen evolution activity, is highly active for oxygen evolution. A current density of 10 mA cm –2 was generated at an overpotential of only 320 mV in 1 M KOH for a CoP nanorod-based electrode (CoP NR/C), which was competitive with commercial IrO 2 . The Tafel slope for CoP NR/C was only 71 mV dec –1, and the catalyst maintained high stability during a 12 h test. This high activity was attributed to the formation of a thin layer of ultrafine crystalline cobalt oxide on the CoP surface.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
Ni2P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni2P nanoparticles
Stern, L.-A., Feng, L., Song, F., & Hu, X. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01155h · Cited by 1,616
Efficient Water Oxidation Using Nanostructured α-Nickel-Hydroxide as an Electrocatalyst
Gao, M., Sheng, W., Zhuang, Z., Fang, Q., Gu, S., Jiang, J., & Yan, Y. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502128j · Cited by 1,322
Liu, Q., Tian, J., Cui, W., Jiang, P., Cheng, N., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201404161 · Cited by 1,117
Water Oxidation at Hematite Photoelectrodes: The Role of Surface States
Klahr, B., Gimenez, S., Fabregat-Santiago, F., Hamann, T., & Bisquert, J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja210755h · Cited by 1,052
Kibsgaard, J., & Jaramillo, T. F. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408222 · Cited by 1,048
A Janus cobalt-based catalytic material for electro-splitting of water
Cobo, S., Heidkamp, J., Jacques, P.-A., Fize, J., Fourmond, V., Guetaz, L., Jousselme, B., Ivanova, V., Dau, H., Palacin, S., et al. (2012) · Nature Materials · doi:10.1038/nmat3385 · Cited by 845
Ma, T. Y., Dai, S., Jaroniec, M., & Qiao, S. Z. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403946 · Cited by 814
Fast Water Oxidation Using Iron
Ellis, W. C., McDaniel, N. D., Bernhard, S., & Collins, T. J. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104766z · Cited by 621
Wang, M., Chen, L., & Sun, L. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03309g · Cited by 529
Grosvenor, A. P., Wik, S. D., Cavell, R. G., & Mar, A. (2005) · Inorganic Chemistry · doi:10.1021/ic051004d · Cited by 464
A Biomimetic Copper Water Oxidation Catalyst with Low Overpotential
Zhang, T., Wang, C., Liu, S., Wang, J.-L., & Lin, W. (2014) · Journal of the American Chemical Society · doi:10.1021/ja409267p · Cited by 389
Mallouk, T. E. (2013) · Nature Chemistry · doi:10.1038/nchem.1634 · Cited by 383
Zhu, J., Sakaushi, K., Clavel, G., Shalom, M., Antonietti, M., & Fellinger, T.-P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b01072 · Cited by 334
Park, J., Koo, B., Yoon, K. Y., Hwang, Y., Kang, M., Park, J.-G., & Hyeon, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0427496 · Cited by 307
Pu, Z., Liu, Q., Jiang, P., Asiri, A. M., Obaid, A. Y., & Sun, X. (2014) · Chemistry of Materials · doi:10.1021/cm501273s · Cited by 293
Saadi, F. H., Carim, A. I., Verlage, E., Hemminger, J. C., Lewis, N. S., & Soriaga, M. P. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp5054452 · Cited by 240
Jiang, P., Liu, Q., Ge, C., Cui, W., Pu, Z., Asiri, A. M., & Sun, X. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta03261f · Cited by 232
Tran, P. D., Artero, V., & Fontecave, M. (2010) · Energy & Environmental Science · doi:10.1039/b926749b · Cited by 202
High catalytic activity for water oxidation based on nanostructured nickel phosphide precursors
Han, A., Chen, H., Sun, Z., Xu, J., & Du, P. (2015) · Chemical Communications · doi:10.1039/c5cc02626a · Cited by 197
Liu, X., Zheng, H., Sun, Z., Han, A., & Du, P. (2015) · ACS Catalysis · doi:10.1021/cs501480s · Cited by 181
Surface Interrogation of CoP i Water Oxidation Catalyst by Scanning Electrochemical Microscopy
Ahn, H. S., & Bard, A. J. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511740h · Cited by 128
Recent Advances in Cell Cost and Efficiency for PEM-Based Water Electrolysis
Ayers, K. E., Capuano, C., & Anderson, E. B. (2012) · ECS Transactions · doi:10.1149/1.3684798 · Cited by 105
Amorphous Nickel-Based Thin Film As a Janus Electrocatalyst for Water Splitting
He, C., Wu, X., & Hé, Z. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp408153b · Cited by 99
Chen, K., Huang, X., Wan, C., & Liu, H. (2015) · Chemical Communications · doi:10.1039/c5cc02028j · Cited by 87
Morales‐Guio, C. G., Liardet, L., Mayer, M. T., Tilley, S. D., Grätzel, M., & Hu, X. (2014) · Angewandte Chemie · doi:10.1002/ange.201410569 · Cited by 41
Research works printed but not linked: 3
- 10.1021/ja504282w · doi:10.1021/ja504282w
- 10.1002/aenm.201470082 · doi:10.1002/aenm.201470082
- 10.1002/advs.201570008 · doi:10.1002/advs.201570008
Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Anantharaj, S., Ede, S. R., Sakthikumar, K., Karthick, K., Mishra, S., & Kundu, S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02479 · Cited by 2,503
Masa, J., Weide, P., Peeters, D., Sinev, I., Xia, W., Sun, Z., Somsen, C., Muhler, M., & Schuhmann, W. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502313 · Cited by 854
Jiao, L., Zhou, Y.-X., & Jiang, H.-L. (2016) · Chemical Science · doi:10.1039/c5sc04425a · Cited by 798
Recent development in electrocatalysts for hydrogen production through water electrolysis
Anwar, S., Khan, F., Zhang, Y., & Djire, A. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.06.191 · Cited by 652
Metadata
- Authors
- Chang, J., Xiao, Y., Xiao, M., Ge, J., Liu, C., & Xing, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-20
- Volume
- 5
- Issue
- 11
- Pages
- 6874-6878
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2343044577
- Cited by
- 478
- References
- 29
- FWCI
- 17.40
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- Chinese Academy of Sciences (XDA0903104)
- Ministry of Science and Technology of the People's Republic of China (2012AA053401)
- National Natural Science Foundation of China (21373199, 21433003)
- State Administration of Foreign Experts Affairs (WQ20122200077)
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
