The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis
Abstract
Direct conversion of carbon dioxide (CO 2 ) into lower olefins (C 2 = –C 4 = ), generally referring to ethylene, propylene, and butylene, is highly attractive as a sustainable production route for its great significance in greenhouse gas control and fossil fuel substitution, but such a route always tends to be low in selectivity toward olefins. Here we present a bifunctional catalysis process that offers C 2 = –C 4 = selectivity as high as 80% and C 2 –C 4 selectivity around 93% at more than 35% CO 2 conversion. This is achieved by a bifunctional catalyst composed of indium–zirconium composite oxide and SAPO-34 zeolite, which is responsible for CO 2 activation and selective C–C coupling, respectively. We demonstrate that both the precise control of oxygen vacancies on the oxide surface and the integration manner of the components are crucial in the direct production of lower olefins from CO 2 hydrogenation. No obvious deactivation is observed over 150 h, indicating a promising potential for industrial application.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Transformation of Carbon Dioxide
Sakakura, T., Choi, J.-C., & Yasuda, H. (2007) · Chemical Reviews · doi:10.1021/cr068357u · Cited by 3,853
Ghosh Chaudhuri, R., & Paria, S. (2012) · Chemical Reviews · doi:10.1021/cr100449n · Cited by 3,614
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Olsbye, U., Svelle, S., Bjørgen, M., Beato, P., Janssens, T. V. W., Joensen, F., Bordiga, S., & Lillerud, K. P. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201103657 · Cited by 1,802
Methanol to Olefins (MTO): From Fundamentals to Commercialization
Tian, P., Wei, Y., Ye, M., & Liu, Z. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00007 · Cited by 1,723
Self-citationOlah, G. A., Goeppert, A., & Prakash, G. K. S. (2009) · The Journal of Organic Chemistry · doi:10.1021/jo801260f · Cited by 1,605
Selective conversion of syngas to light olefins
Jiao, F., Li, J., Pan, X., Xiao, J., Li, H., Ma, H., Wei, M., Pan, Y., Zhou, Z., Li, M., et al. (2016) · Science · doi:10.1126/science.aaf1835 · Cited by 1,521
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2
Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., et al. (2014) · Science · doi:10.1126/science.1253057 · Cited by 1,452
Anthropogenic Chemical Carbon Cycle for a Sustainable Future
Olah, G. A., Prakash, G. K. S., & Goeppert, A. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202642y · Cited by 1,376
Porosoff, M. D., Yan, B., & Chen, J. G. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02657a · Cited by 1,345
Cited by
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
New trends in tailoring active sites in zeolite-based catalysts
Shamzhy, M., Opanasenko, M., Concepción, P., & Martínez, A. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00887f · Cited by 508
Selective conversion of CO2 and H2 into aromatics
Ni, Y., Chen, Z., Fu, Y., Liu, Y., Zhu, W., & Liu, Z. (2018) · Nature Communications · doi:10.1038/s41467-018-05880-4 · Cited by 484
Self-citationPan, X., Jiao, F., Miao, D., & Bao, X. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01012 · Cited by 423
Cui, W.-G., Zhang, G.-Y., Hu, T.-L., & Bu, X.-H. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.02.001 · Cited by 406
Self-citationAdvances in Catalytic Applications of Zeolite‐Supported Metal Catalysts
Sun, Q., Wang, N., & Yu, J. (2021) · Advanced Materials · doi:10.1002/adma.202104442 · Cited by 371
Significant Advances in C1 Catalysis: Highly Efficient Catalysts and Catalytic Reactions
Bao, J., Yang, G., Yoneyama, Y., & Tsubaki, N. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b03924 · Cited by 367
Wang, Y., Tan, L., Tan, M., Zhang, P., Fang, Y., Yoneyama, Y., Yang, G., & Tsubaki, N. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b01344 · Cited by 365
Dang, S., Yang, H., Gao, P., Wang, H., Li, X., Wei, W., & Sun, Y. (2019) · Catalysis Today · doi:10.1016/j.cattod.2018.04.021 · Cited by 355
Self-citationAdvances in the Design of Heterogeneous Catalysts and Thermocatalytic Processes for CO2 Utilization
De, S., Dokania, A., Ramirez, A., & Gascon, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c04273 · Cited by 355
Development of Tandem Catalysts for CO2 Hydrogenation to Olefins
Ma, Z., & Porosoff, M. D. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b05060 · Cited by 323
Applications of Zeolites to C1 Chemistry: Recent Advances, Challenges, and Opportunities
Zhang, Q., Yu, J., & Corma, A. (2020) · Advanced Materials · doi:10.1002/adma.202002927 · Cited by 316
Metadata
- Authors
- Gao, P., Dang, S., Li, S., Bu, X., Liu, Z., Qiu, M., Yang, C., Wang, H., Zhong, L., Han, Y., Liu, Q., Wei, W., & Sun, Y.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-12-14
- Volume
- 8
- Issue
- 1
- Pages
- 571-578
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2775247499
- Cited by
- 533
- References
- 39
- FWCI
- 10.65
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
