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Highly Active ZnO-ZrO2 Aerogels Integrated with H-ZSM-5 for Aromatics Synthesis from Carbon Dioxide
Abstract
Bifunctional catalysis coupling CO 2 to methanol and methanol to hydrocarbons is a promising strategy for the direct hydrogenation of CO 2 into high-value chemicals. However, bifunctional catalysts suffer from low productivity due to the inertness of CO 2 and high activation energy of C–C coupling. Herein, we report a highly active bifunctional catalyst consisting of a ZnO-ZrO 2 aerogel and zeolite H-ZSM-5 for the hydrogenation of CO 2 into aromatics with 76% selectivity at a single-pass CO 2 conversion of 16%. The selectivity of CH 4 is lower than 1% at the same time. The space–time yield of aromatic hydrocarbons is as high as 0.24 g g oxide –1 h –1 under the reaction conditions of 340 °C and 40 bar over ae -ZnO-ZrO 2 /H-ZSM-5 catalyst, which outperforms the previously reported catalysts, including modified Fischer–Tropsch catalysts. We demonstrate that the ZnO-ZrO 2 aerogel catalyst, which is prepared by a combined sol–gel and subsequent supercritical drying method, not only possesses high surface area but also provides large amounts of oxygen vacancies. The formation rate of the methanol intermediate over ZnO-ZrO 2 is dominated by the total amount of oxygen vacancies. Moreover, the stable performance of the bifunctional catalyst under industrially relevant conditions suggests promising prospects for industrial applications.
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Citations
Cites
Handbook of Heterogeneous Catalysis: Online
(2008) · Wiley eBooks · doi:10.1002/9783527610044 · Cited by 5,540
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
Liu, L., & Corma, A. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00776 · Cited by 4,777
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity
van Deelen, T. W., Hernández Mejía, C., & de Jong, K. P. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0364-x · Cited by 2,349
Olsbye, U., Svelle, S., Bjørgen, M., Beato, P., Janssens, T. V. W., Joensen, F., Bordiga, S., & Lillerud, K. P. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201103657 · Cited by 1,802
Selective conversion of syngas to light olefins
Jiao, F., Li, J., Pan, X., Xiao, J., Li, H., Ma, H., Wei, M., Pan, Y., Zhou, Z., Li, M., et al. (2016) · Science · doi:10.1126/science.aaf1835 · Cited by 1,521
Porosoff, M. D., Yan, B., & Chen, J. G. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02657a · Cited by 1,345
Ganduglia-Pirovano, M. V., Hofmann, A., & Sauer, J. (2007) · Surface Science Reports · doi:10.1016/j.surfrep.2007.03.002 · Cited by 1,284
Zhou, W., Cheng, K., Kang, J., Zhou, C., Subramanian, V., Zhang, Q., & Wang, Y. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00502h · Cited by 1,183
Self-citationA highly selective and stable ZnO-ZrO2solid solution catalyst for CO2hydrogenation to methanol
Wang, J., Li, G., Li, Z., Tang, C., Feng, Z., An, H., Liu, H., Liu, T., & Li, C. (2017) · Science Advances · doi:10.1126/sciadv.1701290 · Cited by 1,165
Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst
Gao, P., Li, S., Bu, X., Dang, S., Liu, Z., Wang, H., Zhong, L., Qiu, M., Yang, C., Cai, J., et al. (2017) · Nature Chemistry · doi:10.1038/nchem.2794 · Cited by 1,122
Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation
Martin, O., Martín, A. J., Mondelli, C., Mitchell, S., Segawa, T. F., Hauert, R., Drouilly, C., Curulla‐Ferré, D., & Pérez‐Ramírez, J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201600943 · Cited by 1,119
Directly converting CO2 into a gasoline fuel
Wei, J., Ge, Q., Yao, R., Wen, Z., Fang, C., Guo, L., Xu, H., & Sun, J. (2017) · Nature Communications · doi:10.1038/ncomms15174 · Cited by 1,086
Kattel, S., Yan, B., Yang, Y., Chen, J. G., & Liu, P. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05791 · Cited by 909
Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study
Ye, J., Liu, C., Mei, D., & Ge, Q. (2013) · ACS Catalysis · doi:10.1021/cs400132a · Cited by 793
Recent trends and fundamental insights in the methanol-to-hydrocarbons process
Yarulina, I., Chowdhury, A. D., Meirer, F., Weckhuysen, B. M., & Gascon, J. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0078-5 · Cited by 765
Allowable CO2 emissions based on regional and impact-related climate targets
Seneviratne, S. I., Donat, M. G., Pitman, A. J., Knutti, R., & Wilby, R. L. (2016) · Nature · doi:10.1038/nature16542 · Cited by 743
CO2 hydrogenation to methanol over Pd/In2O3: effects of Pd and oxygen vacancy
Rui, N., Wang, Z., Sun, K., Ye, J., Ge, Q., & Liu, C.-J. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.06.069 · Cited by 733
A short review of recent advances in CO2hydrogenation to hydrocarbons over heterogeneous catalysts
Li, W., Wang, H., Jiang, X., Zhu, J., Liu, Z., Guo, X., & Song, C. (2018) · RSC Advances · doi:10.1039/c7ra13546g · Cited by 669
Liu, B., Li, C., Zhang, G., Yao, X., Chuang, S. S. C., & Li, Z. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00415 · Cited by 668
Larmier, K., Liao, W., Tada, S., Lam, E., Verel, R., Bansode, A., Urakawa, A., Comas‐Vives, A., & Copéret, C. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201610166 · Cited by 650
Cheng, K., Gu, B., Liu, X., Kang, J., Zhang, Q., & Wang, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601208 · Cited by 646
Self-citationHighly Selective Conversion of Carbon Dioxide to Lower Olefins
Li, Z., Wang, J., Qu, Y., Liu, H., Tang, C., Miao, S., Feng, Z., An, H., & Li, C. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b03251 · Cited by 593
Cheng, K., Zhou, W., Kang, J., He, S., Shi, S., Zhang, Q., Pan, Y., Wen, W., & Wang, Y. (2017) · Chem · doi:10.1016/j.chempr.2017.05.007 · Cited by 533
Self-citationA review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons
Yang, H., Zhang, C., Gao, P., Wang, H., Li, X., Zhong, L., Wei, W., & Sun, Y. (2017) · Catalysis Science & Technology · doi:10.1039/c7cy01403a · Cited by 530
Oxygen Vacancy: The Invisible Agent on Oxide Surfaces
Pacchioni, G. (2003) · ChemPhysChem · doi:10.1002/cphc.200300835 · Cited by 526
Integrated tuneable synthesis of liquid fuels via Fischer–Tropsch technology
Li, J., He, Y., Tan, L., Zhang, P., Peng, X., Oruganti, A., Yang, G., Abe, H., Wang, Y., & Tsubaki, N. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0144-z · Cited by 488
Self-citationSelective conversion of CO2 and H2 into aromatics
Ni, Y., Chen, Z., Fu, Y., Liu, Y., Zhu, W., & Liu, Z. (2018) · Nature Communications · doi:10.1038/s41467-018-05880-4 · Cited by 484
Highly Selective Conversion of Carbon Dioxide to Aromatics over Tandem Catalysts
Li, Z., Qu, Y., Wang, J., Liu, H., Li, M., Miao, S., & Li, C. (2019) · Joule · doi:10.1016/j.joule.2018.10.027 · Cited by 476
Crystallographic Dependence of CO Activation on Cobalt Catalysts: HCP versus FCC
Liu, J.-X., Su, H.-Y., Sun, D.-P., Zhang, B.-Y., & Li, W.-X. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408521w · Cited by 440
CO2 Hydrogenation to Methanol over ZrO2-Containing Catalysts: Insights into ZrO2 Induced Synergy
Li, K., & Chen, J. G. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b01943 · Cited by 440
Pajonk, G. M. (1991) · Applied Catalysis · doi:10.1016/0166-9834(91)85054-y · Cited by 431
Liu, X., Wang, M., Zhou, C., Zhou, W., Cheng, K., Kang, J., Zhang, Q., Deng, W., & Wang, Y. (2018) · Chemical Communications · doi:10.1039/c7cc08642c · Cited by 385
Self-citationWang, Y., Tan, L., Tan, M., Zhang, P., Fang, Y., Yoneyama, Y., Yang, G., & Tsubaki, N. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b01344 · Cited by 365
Self-citationZhang, J., Qian, W., Kong, C., & Wei, F. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00192 · Cited by 318
Propane Aromatization over HZSM‐5 and Ga/HZSM‐5 Catalysts
Bhan, A., & Nicholas Delgass, W. (2008) · Catalysis Reviews · doi:10.1080/01614940701804745 · Cited by 305
Marques Mota, F., & Kim, D. H. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00527c · Cited by 289
SCHNEIDER, M., & BAIKER, A. (1995) · Catalysis Reviews · doi:10.1080/01614949508006450 · Cited by 251
Advances in Catalysis for Syngas Conversion to Hydrocarbons
Cheng, K., Kang, J., King, D. L., Subramanian, V., Zhou, C., Zhang, Q., & Wang, Y. (2017) · Advances in Catalysis · doi:10.1016/bs.acat.2017.09.003 · Cited by 221
Self-citationRamirez, A., Dutta Chowdhury, A., Dokania, A., Cnudde, P., Caglayan, M., Yarulina, I., Abou-Hamad, E., Gevers, L., Ould-Chikh, S., De Wispelaere, K., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b01466 · Cited by 220
Fischer–Tropsch Catalysts for the Production of Hydrocarbon Fuels with High Selectivity
Zhang, Q., Cheng, K., Kang, J., Deng, W., & Wang, Y. (2014) · ChemSusChem · doi:10.1002/cssc.201300797 · Cited by 211
Self-citationA Critical Look at Direct Catalytic Hydrogenation of Carbon Dioxide to Olefins
Ronda‐Lloret, M., Rothenberg, G., & Shiju, N. R. (2019) · ChemSusChem · doi:10.1002/cssc.201900915 · Cited by 193
Niziolek, A. M., Onel, O., & Floudas, C. A. (2016) · AIChE Journal · doi:10.1002/aic.15144 · Cited by 191
Aromatic hydrocarbons formation during coal pyrolysis
Cypres, R. (1987) · Fuel Processing Technology · doi:10.1016/0378-3820(87)90030-0 · Cited by 177
Song, H., Laudenschleger, D., Carey, J. J., Ruland, H., Nolan, M., & Muhler, M. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01822 · Cited by 175
Conversion of Methanol to Light Aromatics on Zn-Modified Nano-HZSM-5 Zeolite Catalysts
Zhang, G. Q., Bai, T., Chen, T. F., Fan, W. T., & Zhang, X. (2014) · Industrial & Engineering Chemistry Research · doi:10.1021/ie5021156 · Cited by 169
Selective production of aromatics from CO2
Xu, Y., Shi, C., Liu, B., Wang, T., Zheng, J., Li, W., Liu, D., & Liu, X. (2019) · Catalysis Science & Technology · doi:10.1039/c8cy02024h · Cited by 168
Pajonk, G. M. (1997) · Catalysis Today · doi:10.1016/s0920-5861(96)00163-0 · Cited by 163
Chen, J., Wang, X., Wu, D., Zhang, J., Ma, Q., Gao, X., Lai, X., Xia, H., Fan, S., & Zhao, T. (2018) · Fuel · doi:10.1016/j.fuel.2018.10.148 · Cited by 152
Dokania, A., Ramírez, A., Bavykina, A., & Gascón, J. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01910 · Cited by 135
Advances in Catalysis for Methanol-to-Olefins Conversion
Xu, S., Zhi, Y., Han, J., Zhang, W., Wu, X., Sun, T., Wei, Y., & Liu, Z. (2017) · Advances in catalysis · doi:10.1016/bs.acat.2017.10.002 · Cited by 134
Köppel, R. A., Stöcker, C., & Baiker, A. (1998) · Journal of Catalysis · doi:10.1006/jcat.1998.2252 · Cited by 106
Wang, J., Zhang, A., Jiang, X., Song, C., & Guo, X. (2018) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2018.07.006 · Cited by 89
Zhang, M., Dou, M., & Yu, Y. (2017) · Applied Surface Science · doi:10.1016/j.apsusc.2017.10.097 · Cited by 80
CH4–CO2 reforming over Ni/Al2O3 aerogel catalysts in a fluidized bed reactor
Hao, Z., Zhu, Q., Lei, Z., & Li, H. (2007) · Powder Technology · doi:10.1016/j.powtec.2007.05.024 · Cited by 39
Aerogels—Airy Materials: Chemistry, Structure, and Properties
(1998) · doi:10.1002/(sici)1521-3773(19980202)37:1/2<22::aid-anie22>3.0.co;2-i
Cited by
Pan, X., Jiao, F., Miao, D., & Bao, X. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01012 · Cited by 423
Novel Heterogeneous Catalysts for CO2 Hydrogenation to Liquid Fuels
Gao, P., Zhang, L., Li, S., Zhou, Z., & Sun, Y. (2020) · ACS Central Science · doi:10.1021/acscentsci.0c00976 · Cited by 361
Metadata
- Authors
- Zhou, C., Shi, J., Zhou, W., Cheng, K., Zhang, Q., Kang, J., & Wang, Y.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-11-25
- Volume
- 10
- Issue
- 1
- Pages
- 302-310
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2990621550
- Cited by
- 361
- References
- 56
- FWCI
- 7.17
- Type
- journal article
- Language
- en
- Open access
- closed
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