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Scalable 3-D Carbon Nitride Sponge as an Efficient Metal-Free Bifunctional Oxygen Electrocatalyst for Rechargeable Zn–Air Batteries
Abstract
Rational design of efficient and durable bifunctional oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) electrocatalysts is critical for rechargeable metal–air batteries. Here, we developed a facile strategy for fabricating three-dimensional phosphorus and sulfur codoped carbon nitride sponges sandwiched with carbon nanocrystals (P,S-CNS). These materials exhibited high surface area and superior ORR and OER bifunctional catalytic activities than those of Pt/C and RuO 2, respectively, concerning its limiting current density and onset potential. Further, we tested the suitability and durability of P,S-CNS as the oxygen cathode for primary and rechargeable Zn–air batteries. The resulting primary Zn–air battery exhibited a high open-circuit voltage of 1.51 V, a high discharge peak power density of 198 mW cm –2, a specific capacity of 830 mA h g –1, and better durability for 210 h after mechanical recharging. An extraordinary small charge–discharge voltage polarization (∼0.80 V at 25 mA cm –2 ), superior reversibility, and stability exceeding prolonged charge–discharge cycles have been attained in rechargeable Zn–air batteries with a three-electrode system. The origin of the electrocatalytic activity of P,S-CNS was elucidated by density functional theory analysis for both oxygen reactions. This work stimulates an innovative prospect for the enrichment of rechargeable Zn–air battery viable for commercial applications such as armamentaria, smart electronics, and electric vehicles.
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Citations
Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
Gong, K., Du, F., Xia, Z., Durstock, M., & Dai, L. (2009) · Science · doi:10.1126/science.1168049 · Cited by 7,188
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells
Qu, L., Liu, Y., Baek, J.-B., & Dai, L. (2010) · ACS Nano · doi:10.1021/nn901850u · Cited by 3,948
A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions
Zhang, J., Zhao, Z., Xia, Z., & Dai, L. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.48 · Cited by 3,094
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Recent advances in zinc–air batteries
Li, Y., & Dai, H. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00015c · Cited by 2,315
Unique Electronic Structure Induced High Photoreactivity of Sulfur-Doped Graphitic C3N4
Liu, G., Niu, P., Sun, C., Smith, S. C., Chen, Z., Lu, G. Q. (., & Cheng, H.-M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja103798k · Cited by 2,024
Yan, S. C., Li, Z. S., & Zou, Z. G. (2010) · Langmuir · doi:10.1021/la904023j · Cited by 1,670
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation
Gorlin, Y., & Jaramillo, T. F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104587v · Cited by 1,566
Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes
Wang, Z.-L., Xu, D., Xu, J.-J., & Zhang, X.-B. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60248f · Cited by 1,447
Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation
Zhang, Y., Mori, T., Ye, J., & Antonietti, M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja101749y · Cited by 1,336
Advanced zinc-air batteries based on high-performance hybrid electrocatalysts
Li, Y., Gong, M., Liang, Y., Feng, J., Kim, J.-E., Wang, H., Hong, G., Zhang, B., & Dai, H. (2013) · Nature Communications · doi:10.1038/ncomms2812 · Cited by 1,175
Iodine Modified Carbon Nitride Semiconductors as Visible Light Photocatalysts for Hydrogen Evolution
Zhang, G., Zhang, M., Ye, X., Qiu, X., Lin, S., & Wang, X. (2014) · Advanced Materials · doi:10.1002/adma.201303611 · Cited by 1,135
Yang, S., Feng, X., Wang, X., & Müllen, K. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100170 · Cited by 1,109
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500432h · Cited by 1,104
Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction
Wu, G., & Zelenay, P. (2013) · Accounts of Chemical Research · doi:10.1021/ar400011z · Cited by 1,071
Nitrogen-doped carbon nanomaterials as non-metal electrocatalysts for water oxidation
Zhao, Y., Nakamura, R., Kamiya, K., Nakanishi, S., & Hashimoto, K. (2013) · Nature Communications · doi:10.1038/ncomms3390 · Cited by 1,043
Nanoporous Graphitic-C3N4@Carbon Metal-Free Electrocatalysts for Highly Efficient Oxygen Reduction
Zheng, Y., Jiao, Y., Chen, J., Liu, J., Liang, J., Du, A., Zhang, W., Zhu, Z., Smith, S. C., Jaroniec, M., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja209206c · Cited by 1,036
Heterogeneous nanocarbon materials for oxygen reduction reaction
Wang, D.-W., & Su, D. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43463j · Cited by 1,018
Zhong, H., Wang, J., Zhang, Y., Xu, W., Xing, W., Xu, D., Zhang, Y., & Zhang, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408990 · Cited by 938
Yang, D.-S., Bhattacharjya, D., Inamdar, S., Park, J., & Yu, J.-S. (2012) · Journal of the American Chemical Society · doi:10.1021/ja306376s · Cited by 927
Zhang, J., Qu, L., Shi, G., Liu, J., Chen, J., & Dai, L. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201510495 · Cited by 873
Ma, T. Y., Dai, S., Jaroniec, M., & Qiao, S. Z. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403946 · Cited by 814
Ma, T. Y., Ran, J., Dai, S., Jaroniec, M., & Qiao, S. Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201411125 · Cited by 802
Over, H. (2012) · Chemical Reviews · doi:10.1021/cr200247n · Cited by 737
Liu, Z., Peng, F., Wang, H., Yu, H., Zheng, W., & Yang, J. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201006768 · Cited by 728
Chen, S., Duan, J., Jaroniec, M., & Qiao, S. (2014) · Advanced Materials · doi:10.1002/adma.201305608 · Cited by 658
Liu, Q., Wang, Y., Dai, L., & Yao, J. (2016) · Advanced Materials · doi:10.1002/adma.201506112 · Cited by 652
Liang, J., Zheng, Y., Chen, J., Liu, J., Hulicova‐Jurcakova, D., Jaroniec, M., & Qiao, S. Z. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107981 · Cited by 649
Yu, D., Zhang, Q., & Dai, L. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105617z · Cited by 646
Tian, G., Zhao, M., Yu, D., Kong, X., Huang, J., Zhang, Q., & Wei, F. (2014) · Small · doi:10.1002/smll.201303715 · Cited by 614
Mao, S., Wen, Z., Huang, T., Hou, Y., & Chen, J. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42696c · Cited by 598
Electrocatalytic Oxygen Evolution at Surface-Oxidized Multiwall Carbon Nanotubes
Lu, X., Yim, W.-L., Suryanto, B. H. R., & Zhao, C. (2015) · Journal of the American Chemical Society · doi:10.1021/ja509879r · Cited by 594
Higgins, D., Zamani, P., Yu, A., & Chen, Z. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02474a · Cited by 525
Masa, J., Xia, W., Sinev, I., Zhao, A., Sun, Z., Grützke, S., Weide, P., Muhler, M., & Schuhmann, W. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402710 · Cited by 523
Liu, Y., Jiang, H., Zhu, Y., Yang, X., & Li, C. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta10551j · Cited by 514
Carbon Alloy Catalysts: Active Sites for Oxygen Reduction Reaction
Ikeda, T., Boero, M., Huang, S.-F., Terakura, K., Oshima, M., & Ozaki, J.-I. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp806084d · Cited by 502
Non‐Aqueous and Hybrid Li‐O2 Batteries
Black, R., Adams, B., & Nazar, L. F. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200001 · Cited by 493
A Solution-Phase Bifunctional Catalyst for Lithium–Oxygen Batteries
Sun, D., Shen, Y., Zhang, W., Yu, L., Yi, Z., Yin, W., Wang, D., Huang, Y., Wang, J., Wang, D., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501877e · Cited by 466
Liu, R., Wu, D., Feng, X., & Müllen, K. (2010) · Angewandte Chemie · doi:10.1002/ange.200907289 · Cited by 464
Liang, H.-W., Wu, Z.-Y., Chen, L.-F., Li, C., & Yu, S.-H. (2015) · Nano Energy · doi:10.1016/j.nanoen.2014.11.008 · Cited by 440
Liu, X., Park, M., Kim, M. G., Gupta, S., Wu, G., & Cho, J. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201503612 · Cited by 429
Chen, Z., Yu, A., Higgins, D., Li, H., Wang, H., & Chen, Z. (2012) · Nano Letters · doi:10.1021/nl2044327 · Cited by 419
Zhu, Y., Zhang, B., Liu, X., Wang, D., & Su, D. S. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201405314 · Cited by 337
Tian, J., Liu, Q., Asiri, A. M., Alamry, K. A., & Sun, X. (2014) · ChemSusChem · doi:10.1002/cssc.201402118 · Cited by 266
Oxygen-deficient BaTiO3− perovskite as an efficient bifunctional oxygen electrocatalyst
Chen, C.-F., King, G., Dickerson, R. M., Papin, P. A., Gupta, S., Kellogg, W. R., & Wu, G. (2015) · Nano Energy · doi:10.1016/j.nanoen.2015.03.005 · Cited by 264
Du, G., Liu, X., Zong, Y., Hor, T. S. A., Yu, A., & Liu, Z. (2013) · Nanoscale · doi:10.1039/c3nr00300k · Cited by 250
Lee, D. U., Fu, J., Park, M. G., Liu, H., Ghorbani Kashkooli, A., & Chen, Z. (2016) · Nano Letters · doi:10.1021/acs.nanolett.5b04788 · Cited by 250
Liu, X., Park, M., Kim, M. G., Gupta, S., Wang, X., Wu, G., & Cho, J. (2016) · Nano Energy · doi:10.1016/j.nanoen.2015.11.030 · Cited by 197
Nam, G., Park, J., Choi, M., Oh, P., Park, S., Kim, M. G., Park, N., Cho, J., & Lee, J.-S. (2015) · ACS Nano · doi:10.1021/acsnano.5b02266 · Cited by 190
Self-citationPalaniselvam, T., Valappil, M. O., Illathvalappil, R., & Kurungot, S. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43648a · Cited by 170
Zhang, S., Cai, Y., He, H., Zhang, Y., Liu, R., Cao, H., Wang, M., Liu, J., Zhang, G., Li, Y., et al. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta10579j · Cited by 165
3D Ordered Mesoporous Bifunctional Oxygen Catalyst for Electrically Rechargeable Zinc–Air Batteries
Park, M. G., Lee, D. U., Seo, M. H., Cano, Z. P., & Chen, Z. (2016) · Small · doi:10.1002/smll.201600051 · Cited by 157
Gao, S., Li, L., Geng, K., Wei, X., & Zhang, S. (2015) · Nano Energy · doi:10.1016/j.nanoen.2015.07.009 · Cited by 132
Li, Z., Shao, M., Zhou, L., Yang, Q., Zhang, C., Wei, M., Evans, D. G., & Duan, X. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.041 · Cited by 128
Long‐Life, High‐Voltage Acidic Zn–Air Batteries
Li, L., & Manthiram, A. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201502054 · Cited by 127
Development of a Rechargeable Zinc-Air Battery
Toussaint, G., Stevens, P., Akrour, L., Rouget, R., & Fourgeot, F. (2010) · ECS Transactions · doi:10.1149/1.3507924 · Cited by 125
Li, L., Liu, C., He, G., Fan, D., & Manthiram, A. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02616d · Cited by 112
Sakaushi, K., Fellinger, T., & Antonietti, M. (2015) · ChemSusChem · doi:10.1002/cssc.201500102 · Cited by 92
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Pan, J., Xu, Y. Y., Yang, H., Dong, Z., Liu, H., & Xia, B. Y. (2018) · Advanced Science · doi:10.1002/advs.201700691 · Cited by 848
Amiinu, I. S., Liu, X., Pu, Z., Li, W., Li, Q., Zhang, J., Tang, H., Zhang, H., & Mu, S. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201704638 · Cited by 830
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Xie, X., Du, L., Yan, L., Park, S., Qiu, Y., Sokolowski, J., Wang, W., & Shao, Y. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202110036 · Cited by 792
Wang, H., Tang, C., & Zhang, Q. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201803329 · Cited by 772
Guo, Y., Yuan, P., Zhang, J., Hu, Y., Amiinu, I. S., Wang, X., Zhou, J., Xia, H., Song, Z., Xu, Q., et al. (2018) · ACS Nano · doi:10.1021/acsnano.7b08721 · Cited by 486
Metadata
- Authors
- Shinde, S. S., Lee, C.-H., Sami, A., Kim, D.-H., Lee, S.-U., & Lee, J.-H.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-27
- Volume
- 11
- Issue
- 1
- Pages
- 347-357
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2562919331
- Cited by
- 389
- References
- 64
- FWCI
- 14.93
- Type
- journal article
- Language
- en
- Open access
- closed
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