Cited by 426

The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.

Promotion of Electrocatalytic Hydrogen Evolution Reaction on Nitrogen-Doped Carbon Nanosheets with Secondary Heteroatoms

Open access

Qu, Konggang, Zheng, Yao, Zhang, Xianxi, Davey, Ken, Dai, Sheng, Qiao, Shi Zhang·2017·ACS Nano

Open this paper in CoChat — free account

Abstract

Dual heteroatom-doped carbon materials are efficient electrocatalysts via a synergistic effect. With nitrogen as the primary dopant, boron, sulfur, and phosphorus can be used as secondary elements for co-doped carbons. However, evaluation and analysis of the promotional effect of B, P, and S to N-doped carbons has not been widely researched. Here we report a robust platform that is constructed through polydopamine to prepare N,B-, N,P-, and N,S-co-doped carbon nanosheets, characterized by similar N species content and efficient B, P, and S doping. Systematic investigation reveals S to have the greatest promotional effect in hydrogen evolution reactions (HER) followed by P and that B decreases the activity of N-doped carbons. Experimental and theoretical analyses show the secondary heteroatom promotional effect is impacted by the intrinsic structures and extrinsic surface areas of both materials, i.e., electronic structures exclusively determine the catalytic activity of active sites, while large surface areas optimize apparent HER performance.

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Integrity signals

Registry

Crossref · 10.1021/acsnano.7b03290

Cites

47 of 47 references verified0 citation errors · 0 not checkable

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Improved Synthesis of Graphene Oxide
Marcano, D. C., Kosynkin, D. V., Berlin, J. M., Sinitskii, A., Sun, Z., Slesarev, A., Alemany, L. B., Lu, W., & Tour, J. M. (2010) · ACS Nano · doi:10.1021/nn1006368 · Cited by 11,989
Mussel-inspired surface chemistry for multifunctional coatings
Lee, H., Dellatore, S. M., Miller, W. M., & Messersmith, P. B. (2007) · Science · doi:10.1126/science.1147241 · Cited by 10,965
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,310
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
Gong, K., Du, F., Xia, Z., Durstock, M., & Dai, L. (2009) · Science · doi:10.1126/science.1168049 · Cited by 7,188
Sustainable Hydrogen Production
Turner, J. A. (2004) · Science · doi:10.1126/science.1103197 · Cited by 6,602
Alternative energy technologies
Dresselhaus, M. S., & Thomas, I. L. (2001) · Nature · doi:10.1038/35104599 · Cited by 4,894
Polydopamine and Its Derivative Materials: Synthesis and Promising Applications in Energy, Environmental, and Biomedical Fields
Liu, Y., Ai, K., & Lu, L. (2014) · Chemical Reviews · doi:10.1021/cr400407a · Cited by 4,794
The path towards sustainable energy
Chu, S., Cui, Y., & Liu, N. (2017) · Nature Materials · doi:10.1038/nmat4834 · Cited by 4,791
Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts
Guo, D., Shibuya, R., Akiba, C., Saji, S., Kondo, T., & Nakamura, J. (2016) · Science · doi:10.1126/science.aad0832 · Cited by 4,230
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies
Cançado, L. G., Jorio, A., Ferreira, E. H. M., Stavale, F., Achete, C. A., Capaz, R. B., Moutinho, M. V. O., Lombardo, A., Kulmala, T. S., & Ferrari, A. C. (2011) · Nano Letters · doi:10.1021/nl201432g · Cited by 3,694
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions
Zhang, J., Zhao, Z., Xia, Z., & Dai, L. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.48 · Cited by 3,094
Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction
Lai, L., Potts, J. R., Zhan, D., Wang, L., Poh, C. K., Tang, C., Gong, H., Shen, Z., Lin, J., & Ruoff, R. S. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21802j · Cited by 2,277
Hydrogen evolution by a metal-free electrocatalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Du, A., Jaroniec, M., & Qiao, S. Z. (2014) · Nature Communications · doi:10.1038/ncomms4783 · Cited by 2,236
Self-citation
Sulfur and Nitrogen Dual‐Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance
Liang, J., Jiao, Y., Jaroniec, M., & Qiao, S. Z. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201206720 · Cited by 2,093
Self-citation
Advancing the Electrochemistry of the Hydrogen‐Evolution Reaction through Combining Experiment and Theory
Zheng, Y., Jiao, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201407031 · Cited by 2,046
Self-citation
Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst
Yang, H. B., Miao, J., Hung, S.-F., Chen, J., Tao, H. B., Wang, X., Zhang, L., Chen, R., Gao, J., Chen, H. M., et al. (2016) · Science Advances · doi:10.1126/sciadv.1501122 · Cited by 1,333
Sustainability and in situ monitoring in battery development
Grey, C. P., & Tarascon, J. M. (2017) · Nature Materials · doi:10.1038/nmat4777 · Cited by 1,213
Activity origin and catalyst design principles for electrocatalytic hydrogen evolution on heteroatom-doped graphene
Jiao, Y., Zheng, Y., Davey, K., & Qiao, S.-Z. (2016) · Nature Energy · doi:10.1038/nenergy.2016.130 · Cited by 1,196
Self-citation
Toward Design of Synergistically Active Carbon-Based Catalysts for Electrocatalytic Hydrogen Evolution
Zheng, Y., Jiao, Y., Li, L. H., Xing, T., Chen, Y., Jaroniec, M., & Qiao, S. Z. (2014) · ACS Nano · doi:10.1021/nn501434a · Cited by 1,060
Self-citation
Two‐Step Boron and Nitrogen Doping in Graphene for Enhanced Synergistic Catalysis
Zheng, Y., Jiao, Y., Ge, L., Jaroniec, M., & Qiao, S. Z. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209548 · Cited by 1,049
Self-citation
Nitrogen-doped carbon nanomaterials as non-metal electrocatalysts for water oxidation
Zhao, Y., Nakamura, R., Kamiya, K., Nakanishi, S., & Hashimoto, K. (2013) · Nature Communications · doi:10.1038/ncomms3390 · Cited by 1,043
High Catalytic Activity of Nitrogen and Sulfur Co‐Doped Nanoporous Graphene in the Hydrogen Evolution Reaction
Ito, Y., Cong, W., Fujita, T., Tang, Z., & Chen, M. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201410050 · Cited by 896
Graphitic Carbon Nitride Nanosheet–Carbon Nanotube Three‐Dimensional Porous Composites as High‐Performance Oxygen Evolution Electrocatalysts
Ma, T. Y., Dai, S., Jaroniec, M., & Qiao, S. Z. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403946 · Cited by 814
Self-citation
Phosphorus‐Doped Graphitic Carbon Nitrides Grown In Situ on Carbon‐Fiber Paper: Flexible and Reversible Oxygen Electrodes
Ma, T. Y., Ran, J., Dai, S., Jaroniec, M., & Qiao, S. Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201411125 · Cited by 802
Self-citation
Vertically Aligned BCN Nanotubes as Efficient Metal‐Free Electrocatalysts for the Oxygen Reduction Reaction: A Synergetic Effect by Co‐Doping with Boron and Nitrogen
Wang, S., Iyyamperumal, E., Roy, A., Xue, Y., Yu, D., & Dai, L. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201105204 · Cited by 783
Dopamine covalently modifies and functionally inactivates parkin
LaVoie, M. J., Ostaszewski, B. L., Weihofen, A., Schlossmacher, M. G., & Selkoe, D. J. (2005) · Nature Medicine · doi:10.1038/nm1314 · Cited by 722
Nitrogen and Phosphorus Dual-Doped Graphene/Carbon Nanosheets as Bifunctional Electrocatalysts for Oxygen Reduction and Evolution
Li, R., Wei, Z., & Gou, X. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00601 · Cited by 709
Graphene oxide-polydopamine derived N, S-codoped carbon nanosheets as superior bifunctional electrocatalysts for oxygen reduction and evolution
Qu, K., Zheng, Y., Dai, S., & Qiao, S. Z. (2016) · Nano Energy · doi:10.1016/j.nanoen.2015.11.027 · Cited by 623
Self-citation
Nitrogen-Doped Colloidal Graphene Quantum Dots and Their Size-Dependent Electrocatalytic Activity for the Oxygen Reduction Reaction
Li, Q., Zhang, S., Dai, L., & Li, L.-S. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309270h · Cited by 593
Building‐Block Diversity in Polydopamine Underpins a Multifunctional Eumelanin‐Type Platform Tunable Through a Quinone Control Point
Della Vecchia, N. F., Avolio, R., Alfè, M., Errico, M. E., Napolitano, A., & d'Ischia, M. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201202127 · Cited by 582
Graphitic Carbon Nitride Nanoribbons: Graphene‐Assisted Formation and Synergic Function for Highly Efficient Hydrogen Evolution
Zhao, Y., Zhao, F., Wang, X., Xu, C., Zhang, Z., Shi, G., & Qu, L. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201409080 · Cited by 519
Infrared spectroscopy of different phosphates structures
Jastrzębski, W., Sitarz, M., Rokita, M., & Bułat, K. (2011) · Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2010.08.044 · Cited by 492
Simultaneous Reduction and Surface Functionalization of Graphene Oxide by Mussel‐Inspired Chemistry
Kang, S. M., Park, S., Kim, D., Park, S. Y., Ruoff, R. S., & Lee, H. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201001692 · Cited by 439
Polydopamine‐Inspired, Dual Heteroatom‐Doped Carbon Nanotubes for Highly Efficient Overall Water Splitting
Qu, K., Zheng, Y., Jiao, Y., Zhang, X., Dai, S., & Qiao, S. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201602068 · Cited by 410
Self-citation
Boron-Doped Graphene Quantum Dots for Selective Glucose Sensing Based on the “Abnormal” Aggregation-Induced Photoluminescence Enhancement
Zhang, L., Zhang, Z.-Y., Liang, R.-P., Li, Y.-H., & Qiu, J.-D. (2014) · Analytical Chemistry · doi:10.1021/ac500289c · Cited by 382
Efficient Electrocatalytic Reduction of CO2 by Nitrogen‐Doped Nanoporous Carbon/Carbon Nanotube Membranes: A Step Towards the Electrochemical CO2 Refinery
Wang, H., Jia, J., Song, P., Wang, Q., Li, D., Min, S., Qian, C., Wang, L., Li, Y. F., Ma, C., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201703720 · Cited by 315
Monodisperse Polymer Capsules: Tailoring Size, Shell Thickness, and Hydrophobic Cargo Loading via Emulsion Templating
Cui, J., Wang, Y., Postma, A., Hao, J., Hosta‐Rigau, L., & Caruso, F. (2010) · Advanced Functional Materials · doi:10.1002/adfm.201000209 · Cited by 290
Robust polydopamine nano/microcapsules and their loading and release behavior
Yu, B., Wang, D. A., Ye, Q., Zhou, F., & Liu, W. (2009) · Chemical Communications · doi:10.1039/b910679k · Cited by 221
Nitrogen-Doped Nanoporous Carbon Membranes with Co/CoP Janus-Type Nanocrystals as Hydrogen Evolution Electrode in Both Acidic and Alkaline Environments
Wang, H., Min, S., Wang, Q., Li, D., Casillas, G., Ma, C., Li, Y., Liu, Z., Li, L.-J., Yuan, J., et al. (2017) · ACS Nano · doi:10.1021/acsnano.7b01946 · Cited by 218
Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting
Wang, H., Min, S., Ma, C., Liu, Z., Zhang, W., Wang, Q., Li, D., Li, Y., Turner, S., Han, Y., et al. (2017) · Nature Communications · doi:10.1038/ncomms13592 · Cited by 176
Natural DNA-Modified Graphene/Pd Nanoparticles as Highly Active Catalyst for Formic Acid Electro-Oxidation and for the Suzuki Reaction
Qu, K., Wu, L. J., Ren, J., & Qu, X. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am301376m · Cited by 138
Self-citation
Polydopamine–graphene oxide derived mesoporous carbon nanosheets for enhanced oxygen reduction
Qu, K., Zheng, Y., Dai, S., & Qiao, S. (2015) · Nanoscale · doi:10.1039/c5nr03089g · Cited by 109
Self-citation
Different synthesis methods allow to tune the permeability and permselectivity of dopamine–melanin films to electrochemical probes
Bernsmann, F., Voegel, J., & Ball, V. (2011) · Electrochimica Acta · doi:10.1016/j.electacta.2011.02.028 · Cited by 92
Nitrogen- and boron-co-doped core–shell carbon nanoparticles as efficient metal-free catalysts for oxygen reduction reactions in microbial fuel cells
Zhong, S., Zhou, L., Wu, L., Lianfeng, T., He, Q., & Ahmed, J. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.08.114 · Cited by 72
The nanoscale carbon p–n junction between carbon nanotubes and N,B-codoped holey graphene enhances the catalytic activity towards selective oxidation
Wang, H., Zheng, X., Chen, H., Yan, K., Zhu, Z., & Yang, S. (2014) · Chemical Communications · doi:10.1039/c4cc01707b · Cited by 30

Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
Zhu, J., Hu, L., Zhao, P., Lee, L. Y. S., & Wong, K.-Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00248 · Cited by 3,133
Rechargeable Batteries for Grid Scale Energy Storage
Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
Oxygen Evolution Reaction in Alkaline Environment: Material Challenges and Solutions
Xie, X., Du, L., Yan, L., Park, S., Qiu, Y., Sokolowski, J., Wang, W., & Shao, Y. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202110036 · Cited by 792
MOF‐Derived Bifunctional Cu3P Nanoparticles Coated by a N,P‐Codoped Carbon Shell for Hydrogen Evolution and Oxygen Reduction
Wang, R., Dong, X., Du, J., Zhao, J., & Zang, S. (2018) · Advanced Materials · doi:10.1002/adma.201703711 · Cited by 580
Multiscale Principles To Boost Reactivity in Gas-Involving Energy Electrocatalysis
Tang, C., Wang, H.-F., & Zhang, Q. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00616 · Cited by 527

See all 426

Authors: Qu, K., Zheng, Y., Zhang, X., Davey, K., Dai, S., & Qiao, S. Z.
Venue: ACS Nano
Publisher: American Chemical Society (ACS)
Published: 2017-06-29
Volume: 11
Issue: 7
Pages: 7293-7300
ISSN: 1936-0851 (ISSN-L)
1936-086X
DOI: 10.1021/acsnano.7b03290
OpenAlex: W2665876104
Cited by: 426
References: 47
FWCI: 15.01
Type: journal article
Language: en
Open access: green

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.

Promotion of Electrocatalytic Hydrogen Evolution Reaction on Nitrogen-Doped Carbon Nanosheets with Secondary Heteroatoms

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Self-check

Citations

Cites

Cited by

Metadata

Record

About these checks

Data sources