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Shining Emitter in a Stable Host: Design of Halide Perovskite Scintillators for X-ray Imaging from Commercial Concept
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Abstract Halide perovskite (HP) nanocrystals (NCs) have recently shown great potential for X-ray detection and imaging. However, the practical application still has a long way to go with many technical requirements waiting to be fulfilled, including structure optimization, stability enhancement, and cost reduction. A design principle in this beginning stage is urgently needed but still lacking. Herein, with an “emitter-in-matrix” principle refined from commercial scintillators, CsPbBr3@Cs4PbBr6 with emissive CsPbBr3 NCs embedded inside a solid-state Cs4PbBr6 host is subjected to X-ray sensing and imaging. The Cs4PbBr6 matrix not only enhances the attenuation of X-rays but also dramatically improves the stability of CsPbBr3 NCs. A favorable optical design with the Cs4PbBr6 matrix being transparent to the emission from CsPbBr3 NCs enables efficient light output. As a result, stable and sensitive scintillation response to X-ray signals is demonstrated with superior linearity and ultrahigh time resolution. In order to show the huge potential for practical applications, X-ray imaging using a large-area film (360 mm × 240 mm) by the blade-coating technique is carried out to obtain a high-quality image of interior structures invisible to the human eye. In addition to the above advantages in optics, CsPbBr3@Cs4PbBr6 also enjoys facile solution synthesis with large scalability, excellent repeatability, and low cost.
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Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Protesescu, L., Yakunin, S., Bodnarchuk, M. I., Krieg, F., Caputo, R., Hendon, C. H., Yang, R. X., Walsh, A., & Kovalenko, M. V. (2015) · Nano Letters · doi:10.1021/nl5048779 · Cited by 9,209
Emergence of colloidal quantum-dot light-emitting technologies
Shirasaki, Y., Supran, G. J., Bawendi, M. G., & Bulović, V. (2013) · Nature Photonics · doi:10.1038/nphoton.2012.328 · Cited by 2,635
Zhang, F., Zhong, H., Chen, C., Wu, X.-G., Hu, X., Huang, H., Han, J., Zou, B., & Dong, Y. (2015) · ACS Nano · doi:10.1021/acsnano.5b01154 · Cited by 2,431
All-inorganic perovskite nanocrystal scintillators
Chen, Q., Wu, J., Ou, X., Huang, B., Almutlaq, J., Zhumekenov, A. A., Guan, X., Han, S., Liang, L., Yi, Z., et al. (2018) · Nature · doi:10.1038/s41586-018-0451-1 · Cited by 2,052
Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals
Wei, H., Fang, Y., Mulligan, P., Chuirazzi, W., Fang, H.-H., Wang, C., Ecker, B. R., Gao, Y., Loi, M. A., Cao, L., et al. (2016) · Nature Photonics · doi:10.1038/nphoton.2016.41 · Cited by 1,877
Stoumpos, C. C., Malliakas, C. D., Peters, J. A., Liu, Z., Sebastian, M., Im, J., Chasapis, T. C., Wibowo, A. C., Chung, D. Y., Freeman, A. J., et al. (2013) · Crystal Growth & Design · doi:10.1021/cg400645t · Cited by 1,596
Cs2AgBiBr6 single-crystal X-ray detectors with a low detection limit
Pan, W., Wu, H., Luo, J., Deng, Z., Ge, C., Chen, C., Jiang, X., Yin, W.-J., Niu, G., Zhu, L., et al. (2017) · Nature Photonics · doi:10.1038/s41566-017-0012-4 · Cited by 1,416
Reversible Hydration of CH3NH3PbI3 in Films, Single Crystals, and Solar Cells
Leguy, A. M. A., Hu, Y., Campoy-Quiles, M., Alonso, M. I., Weber, O. J., Azarhoosh, P., van Schilfgaarde, M., Weller, M. T., Bein, T., Nelson, J., et al. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00660 · Cited by 1,366
Stability of Metal Halide Perovskite Solar Cells
Leijtens, T., Eperon, G. E., Noel, N. K., Habisreutinger, S. N., Petrozza, A., & Snaith, H. J. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500963 · Cited by 1,308
Printable organometallic perovskite enables large-area, low-dose X-ray imaging
Kim, Y. C., Kim, K. H., Son, D.-Y., Jeong, D.-N., Seo, J.-Y., Choi, Y. S., Han, I. T., Lee, S. Y., & Park, N.-G. (2017) · Nature · doi:10.1038/nature24032 · Cited by 1,206
Detection of X-ray photons by solution-processed lead halide perovskites
Yakunin, S., Sytnyk, M., Kriegner, D., Shrestha, S., Richter, M., Matt, G. J., Azimi, H., Brabec, C. J., Stangl, J., Kovalenko, M. V., et al. (2015) · Nature Photonics · doi:10.1038/nphoton.2015.82 · Cited by 1,184
Niu, G., Li, W., Meng, F., Wang, L., Dong, H., & Qiu, Y. (2014) · J. Mater. Chem. A · doi:10.1039/c3ta13606j · Cited by 1,075
Halide lead perovskites for ionizing radiation detection
Wei, H., & Huang, J. (2019) · Nature Communications · doi:10.1038/s41467-019-08981-w · Cited by 976
Luminescence Photophysics in Semiconductor Nanocrystals
Nirmal, M., & Brus, L. (1999) · Accounts of Chemical Research · doi:10.1021/ar9700320 · Cited by 925
Wei, H., DeSantis, D., Wei, W., Deng, Y., Guo, D., Savenije, T. J., Cao, L., & Huang, J. (2017) · Nature Materials · doi:10.1038/nmat4927 · Cited by 660
Inorganic scintillators: today and tomorrow
Weber, M. J. (2002) · Journal of Luminescence · doi:10.1016/s0022-2313(02)00423-4 · Cited by 648
Shrestha, S., Fischer, R., Matt, G. J., Feldner, P., Michel, T., Osvet, A., Levchuk, I., Merle, B., Golkar, S., Chen, H., et al. (2017) · Nature Photonics · doi:10.1038/nphoton.2017.94 · Cited by 646
Akkerman, Q. A., Park, S., Radicchi, E., Nunzi, F., Mosconi, E., De Angelis, F., Brescia, R., Rastogi, P., Prato, M., & Manna, L. (2017) · Nano Letters · doi:10.1021/acs.nanolett.6b05262 · Cited by 600
Pure Cs4PbBr6: Highly Luminescent Zero-Dimensional Perovskite Solids
Saidaminov, M. I., Almutlaq, J., Sarmah, S., Dursun, I., Zhumekenov, A. A., Begum, R., Pan, J., Cho, N., Mohammed, O. F., & Bakr, O. M. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00396 · Cited by 595
Radiation Risk From Medical Imaging
Lin, E. C. (2010) · Mayo Clinic Proceedings · doi:10.4065/mcp.2010.0260 · Cited by 554
Hailegnaw, B., Kirmayer, S., Edri, E., Hodes, G., & Cahen, D. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00504 · Cited by 523
Heo, J. H., Shin, D. H., Park, J. K., Kim, D. H., Lee, S. J., & Im, S. H. (2018) · Advanced Materials · doi:10.1002/adma.201801743 · Cited by 523
Metal Halide Perovskite Nanosheet for X-ray High-Resolution Scintillation Imaging Screens
Zhang, Y., Sun, R., Ou, X., Fu, K., Chen, Q., Ding, Y., Xu, L.-J., Liu, L., Han, Y., Malko, A. V., et al. (2019) · ACS Nano · doi:10.1021/acsnano.8b09484 · Cited by 506
Song, Z., Abate, A., Watthage, S. C., Liyanage, G. K., Phillips, A. B., Steiner, U., Graetzel, M., & Heben, M. J. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600846 · Cited by 439
X-ray Scintillation in Lead Halide Perovskite Crystals
Birowosuto, M. D., Cortecchia, D., Drozdowski, W., Brylew, K., Lachmanski, W., Bruno, A., & Soci, C. (2016) · Scientific Reports · doi:10.1038/srep37254 · Cited by 383
Flexible, Printable Soft‐X‐Ray Detectors Based on All‐Inorganic Perovskite Quantum Dots
Liu, J., Shabbir, B., Wang, C., Wan, T., Ou, Q., Yu, P., Tadich, A., Jiao, X., Chu, D., Qi, D., et al. (2019) · Advanced Materials · doi:10.1002/adma.201901644 · Cited by 375
Highly Emissive Green Perovskite Nanocrystals in a Solid State Crystalline Matrix
Quan, L. N., Quintero‐Bermudez, R., Voznyy, O., Walters, G., Jain, A., Fan, J. Z., Zheng, X., Yang, Z., & Sargent, E. H. (2017) · Advanced Materials · doi:10.1002/adma.201605945 · Cited by 374
The Evolution of Quantum Confinement in CsPbBr3 Perovskite Nanocrystals
Butkus, J., Vashishtha, P., Chen, K., Gallaher, J. K., Prasad, S. K. K., Metin, D. Z., Laufersky, G., Gaston, N., Halpert, J. E., & Hodgkiss, J. M. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b00478 · Cited by 362
Blasse, G. (1994) · Chemistry of Materials · doi:10.1021/cm00045a002 · Cited by 361
Zero-Dimensional Cs4PbBr6 Perovskite Nanocrystals
Zhang, Y., Saidaminov, M. I., Dursun, I., Yang, H., Murali, B., Alarousu, E., Yengel, E., Alshankiti, B. A., Bakr, O. M., & Mohammed, O. F. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b00105 · Cited by 348
Xie, C., You, P., Liu, Z., Li, L., & Yan, F. (2017) · Light: Science & Applications · doi:10.1038/lsa.2017.23 · Cited by 348
Resonant light scattering from metal nanoparticles: Practical analysis beyond Rayleigh approximation
Kuwata, H., Tamaru, H., Esumi, K., & Miyano, K. (2003) · Applied Physics Letters · doi:10.1063/1.1630351 · Cited by 346
Material and Device Stability in Perovskite Solar Cells
Kim, H., Seo, J., & Park, N. (2016) · ChemSusChem · doi:10.1002/cssc.201600915 · Cited by 346
Environmental Effects on the Photophysics of Organic–Inorganic Halide Perovskites
Galisteo-López, J. F., Anaya, M., Calvo, M. E., & Míguez, H. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00785 · Cited by 238
Inside Perovskites: Quantum Luminescence from Bulk Cs4PbBr6 Single Crystals
De Bastiani, M., Dursun, I., Zhang, Y., Alshankiti, B. A., Miao, X.-H., Yin, J., Yengel, E., Alarousu, E., Turedi, B., Almutlaq, J. M., et al. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b02415 · Cited by 237
Xu, J., Huang, W., Li, P., Onken, D. R., Dun, C., Guo, Y., Ucer, K. B., Lu, C. H., Wang, H., Geyer, S. M., et al. (2017) · Advanced Materials · doi:10.1002/adma.201703703 · Cited by 218
Palazon, F., Urso, C., De Trizio, L., Akkerman, Q., Marras, S., Locardi, F., Nelli, I., Ferretti, M., Prato, M., & Manna, L. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00842 · Cited by 213
Singh, S., Li, C., Panzer, F., Narasimhan, K. L., Graeser, A., Gujar, T. P., Köhler, A., Thelakkat, M., Huettner, S., & Kabra, D. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b01207 · Cited by 202
Point Defects and Green Emission in Zero-Dimensional Perovskites
Yin, J., Yang, H., Song, K., El-Zohry, A. M., Han, Y., Bakr, O. M., Brédas, J.-L., & Mohammed, O. F. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b02477 · Cited by 177
Photoinduced, reversible phase transitions in all-inorganic perovskite nanocrystals
Kirschner, M. S., Diroll, B. T., Guo, P., Harvey, S. M., Helweh, W., Flanders, N. C., Brumberg, A., Watkins, N. E., Leonard, A. A., Evans, A. M., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-08362-3 · Cited by 168
Bright and fast scintillation of organolead perovskite MAPbBr 3 at low temperatures
Mykhaylyk, V. B., Kraus, H., & Saliba, M. (2019) · Materials Horizons · doi:10.1039/c9mh00281b · Cited by 150
Wang, Y., Yu, D., Wang, Z., Li, X., Chen, X., Nalla, V., Zeng, H., & Sun, H. (2017) · Small · doi:10.1002/smll.201701587 · Cited by 148
Self-citationSeth, S., & Samanta, A. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b02100 · Cited by 148
Exploring Polaronic, Excitonic Structures and Luminescence in Cs 4 PbBr 6 /CsPbBr 3
Kang, B., & Biswas, K. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b03333 · Cited by 147
Revealing the Origin of Luminescence Center in 0D Cs 4 PbBr 6 Perovskite
Qin, Z., Dai, S., Hadjiev, V. G., Wang, C., Xie, L., Ni, Y., Wu, C., Yang, G., Chen, S., Deng, L., et al. (2019) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b03426 · Cited by 130
Direct Observation of Band Structure Modifications in Nanocrystals of CsPbBr3 Perovskite
Lin, J., Gómez, L., de Weerd, C., Fujiwara, Y., Gregorkiewicz, T., & Suenaga, K. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b03552 · Cited by 106
Perovskite/organic-semiconductor heterojunctions for ultrasensitive photodetection
Gu, L., & Fan, Z. (2017) · Light Science & Applications · doi:10.1038/lsa.2017.90 · Cited by 86
Hybridization of Single Nanocrystals of Cs4PbBr6 and CsPbBr3
de Weerd, C., Lin, J., Gómez, L., Fujiwara, Y., Suenaga, K., & Gregorkiewicz, T. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b05752 · Cited by 86
Ligand-Free Nanocrystals of Highly Emissive Cs4PbBr6 Perovskite
Zhang, Y., Sinatra, L., Alarousu, E., Yin, J. L., El‐Zohry, A. M., Bakr, O. M., & Mohammed, O. F. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b01735 · Cited by 68
Lin, C.-H., Verma, A., Kang, C., Pai, Y.-M., Chen, T., Yang, J.-J., Sher, C.-W., Yang, Y.-Z., Lee, P.-T., Lin, C., et al. (2019) · Photonics Research · doi:10.1364/prj.7.000579 · Cited by 67
Self-citationQuantum Dot-Organic Polymer Composite Materials for Radiation Detection and Imaging
Lawrence, W. G., Thacker, S., Palamakumbura, S., Riley, K. J., & Nagarkar, V. V. (2012) · IEEE Transactions on Nuclear Science · doi:10.1109/tns.2011.2178861 · Cited by 58
Lead Halide Perovskite Nanocrystals: Stability, Surface Passivation, and Structural Control
Luo, B., Naghadeh, S. B., & Zhang, J. Z. (2017) · ChemNanoMat · doi:10.1002/cnma.201700056 · Cited by 53
CaI2 and CaI2(Eu) Scintillation Crystals
Hofstadter, R., O’Dell, E. W., & Schmidt, C. T. (1964) · Review of Scientific Instruments · doi:10.1063/1.1718803 · Cited by 40
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Zhou, Y., Chen, J., Bakr, O. M., & Mohammed, O. F. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.0c02430 · Cited by 891
Lian, L., Zheng, M., Zhang, W., Yin, L., Du, X., Zhang, P., Zhang, X., Gao, J., Zhang, D., Gao, L., et al. (2020) · Advanced Science · doi:10.1002/advs.202000195 · Cited by 489
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Self-citation
Metadata
- Authors
- Cao, F., Yu, D., Ma, W., Xu, X., Cai, B., Yang, Y. M., Liu, S., He, L., Ke, Y., Lan, S., Choy, K.-L., & Zeng, H.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-11-27
- Volume
- 14
- Issue
- 5
- Pages
- 5183-5193
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2991569662
- Cited by
- 322
- References
- 56
- FWCI
- 30.26
- Type
- journal article
- Language
- en
- Open access
- green
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