Polymeric Surfactants: Synthesis, Properties, and Links to Applications

Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer: The RAFT Process

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New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations

Hawker, C. J., Bosman, A. W., & Harth, E. (2001) · Chemical Reviews · doi:10.1021/cr990119u · Cited by 3,850

Surfactants and Polymers in Aqueous Solution

Holmberg, K., Jönsson, B., Kronberg, B., & Lindman, B. (2002) · Wiley eBooks · doi:10.1002/0470856424 · Cited by 3,009

Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives

Matyjaszewski, K. (2012) · Macromolecules · doi:10.1021/ma3001719 · Cited by 2,606

Stimuli-reponsive polymers and their bioconjugates

GIL, E., & HUDSON, S. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.08.003 · Cited by 2,385

Micellization of block copolymers

Riess, G. (2003) · Progress in Polymer Science · doi:10.1016/s0079-6700(03)00015-7 · Cited by 1,953

Structure and design of polymeric surfactant-based drug delivery systems

Torchilin, V. P. (2001) · Journal of Controlled Release · doi:10.1016/s0168-3659(01)00299-1 · Cited by 1,822

Self-assembled block copolymer aggregates: From micelles to vesicles and their biological applications

Blanazs, A., Armes, S. P., & Ryan, A. J. (2009) · Macromolecular Rapid Communications · doi:10.1002/marc.200800713 · Cited by 1,500

DISPERSION PHENOMENA IN HIGH VISCOSITY IMMISCIBLE FLUID SYSTEMS AND APPLICATION OF STATIC MIXERS AS DISPERSION DEVICES IN SUCH SYSTEMS

GRACE†, H. P. (1982) · Chemical Engineering Communications · doi:10.1080/00986448208911047 · Cited by 1,497

Polymers with Complex Architecture by Living Anionic Polymerization

Hadjichristidis, N., Pitsikalis, M., Pispas, S., & Iatrou, H. (2001) · Chemical Reviews · doi:10.1021/cr9901337 · Cited by 1,330

Pluronic block copolymers: evolution of drug delivery concept from inert nanocarriers to biological response modifiers

Batrakova, E. V., & Kabanov, A. V. (2008) · Journal of Controlled Release · doi:10.1016/j.jconrel.2008.04.013 · Cited by 1,278

Multiple Morphologies and Characteristics of “Crew-Cut” Micelle-like Aggregates of Polystyrene-b-poly(acrylic acid) Diblock Copolymers in Aqueous Solutions

Zhang, L., & Eisenberg, A. (1996) · Journal of the American Chemical Society · doi:10.1021/ja953709s · Cited by 1,262

Polymerization of oligo(ethylene glycol) (meth)acrylates: Toward new generations of smart biocompatible materials

Lutz, J. (2008) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.22706 · Cited by 1,245

On the origins of morphological complexity in block copolymer surfactants

Jain, S., & Bates, F. S. (2003) · Science · doi:10.1126/science.1082193 · Cited by 1,217

Enhanced Oil Recovery: An Update Review

Alvarado, V., & Manrique, E. J. (2010) · Energies · doi:10.3390/en3091529 · Cited by 1,151

Amphiphilic block copolymers for drug delivery

Adams, M. L., Lavasanifar, A., & Kwon, G. S. (2003) · Journal of Pharmaceutical Sciences · doi:10.1002/jps.10397 · Cited by 1,078

Principles of emulsion formation

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Enhanced Oil Recovery - An Overview

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Synthesis and Solution Properties of Zwitterionic Polymers

Lowe, A. B., & McCormick, C. L. (2002) · Chemical Reviews · doi:10.1021/cr020371t · Cited by 917

A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: The raft process

Chong, ). Y. K., Le, T. P. T., Moad, G., Rizzardo, E., & Thang, S. H. (1999) · Macromolecules · doi:10.1021/ma981472p · Cited by 850

Living Radical Polymerization by the RAFT Process—A First Update

Moad, G., Rizzardo, E., & Thang, S. H. (2006) · Australian Journal of Chemistry · doi:10.1071/ch06250 · Cited by 848

Self-Condensing Vinyl Polymerization: An Approach to Dendritic Materials

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Block copolymer micelles as long-circulating drug vehicles

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Synthesis of functional polymers with controlled architecture by CRP of monomers in the presence of cross-linkers: From stars to gels

Gao, H., & Matyjaszewski, K. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.01.001 · Cited by 799

Toward ‘smart’ nano-objects by self-assembly of block copolymers in solution

RODRIGUEZHERNANDEZ, J., CHECOT, F., GNANOU, Y., & LECOMMANDOUX, S. (2005) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2005.04.002 · Cited by 795

Thermosensitive water-soluble copolymers with doubly responsive reversibly interacting entities

Dimitrov, I., Trzebicka, B., Müller, A. H. E., Dworak, A., & Tsvetanov, C. B. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.07.001 · Cited by 750

Conjugated Polyelectrolytes: Synthesis, Photophysics, and Applications

Jiang, H., Taranekar, P., Reynolds, J. R., & Schanze, K. S. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200805456 · Cited by 734

Water-Soluble Polymers. 81. Direct Synthesis of Hydrophilic Styrenic-Based Homopolymers and Block Copolymers in Aqueous Solution via RAFT

Mitsukami, Y., Donovan, M. S., Lowe, A. B., & McCormick, C. L. (2001) · Macromolecules · doi:10.1021/ma0018087 · Cited by 720

Reversible addition–fragmentation chain transfer (RAFT) radical polymerization and the synthesis of water-soluble (co)polymers under homogeneous conditions in organic and aqueous media

Lowe, A. B., & McCormick, C. L. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.003 · Cited by 711

pH-Responsive polymers: synthesis, properties and applications

Dai, S., Ravi, P., & Tam, K. C. (2008) · Soft Matter · doi:10.1039/b714741d · Cited by 693

Reversible Inside−Out Micellization of pH-responsive and Water-Soluble Vesicles Based on Polypeptide Diblock Copolymers

Rodríguez-Hernández, J., & Lecommandoux, S. (2005) · Journal of the American Chemical Society · doi:10.1021/ja043920g · Cited by 678

Ab Initio Emulsion Polymerization by RAFT-Controlled Self-Assembly

Ferguson, C. J., Hughes, R. J., Nguyen, D., Pham, B. T. T., Gilbert, R. G., Serelis, A. K., Such, C. H., & Hawkett, B. S. (2005) · Macromolecules · doi:10.1021/ma048787r · Cited by 645

Synthesis and aqueous solution properties of near-monodisperse tertiary amine methacrylate homopolymers and diblock copolymers

Bütün, V, Armes, S. P., & Billingham, N. C. (2001) · Polymer · doi:10.1016/s0032-3861(01)00066-0 · Cited by 615

pH-Sensitive Vesicles Based on a Biocompatible Zwitterionic Diblock Copolymer

Du, J., Tang, Y., Lewis, A. L., & Armes, S. P. (2005) · Journal of the American Chemical Society · doi:10.1021/ja056514l · Cited by 603

Critical micellization phenomena in block polyelectrolyte solutions

Astafieva, I., Zhong, X. F., & Eisenberg, A. (1993) · Macromolecules · doi:10.1021/ma00078a034 · Cited by 578

Switching the Inside and the Outside of Aggregates of Water-Soluble Block Copolymers with Double Thermoresponsivity

Arotçaréna, M., Heise, B., Ishaya, S., & Laschewsky, A. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012167d · Cited by 557

Block Copolymer Micelles

Gohy, J.-F. (2005) · Advances in Polymer Science · doi:10.1007/12_048 · Cited by 542

Applied Surfactants: Principles and Applications

Tadros, T. F. (2005) · Wiley eBooks · doi:10.1002/3527604812 · Cited by 503

Block Copolymers in Solution: Fundamentals and Applications

Hamley, I. (2005) · doi:10.1002/9780470016985 · Cited by 479

Formation of crew‐cut aggregates of various morphologies from amphiphilic block copolymers in solution

Zhang, L., & Eisenberg, A. (1998) · Polymers for Advanced Technologies · doi:10.1002/(sici)1099-1581(1998100)9:10/11<677::aid-pat845>3.0.co;2-# · Cited by 470

Bilayer Morphologies of Self-Assembled Crew-Cut Aggregates of Amphiphilic PS-b-PEO Diblock Copolymers in Solution

Yu, K., & Eisenberg, A. (1998) · Macromolecules · doi:10.1021/ma971419l · Cited by 463

Associative polymers in aqueous solution

Winnik, M. A., & Yekta, A. (1997) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(97)80088-x · Cited by 462

Morphogenic Effect of Solvent on Crew-Cut Aggregates of Apmphiphilic Diblock Copolymers

Yu, Y., Zhang, L., & Eisenberg, A. (1998) · Macromolecules · doi:10.1021/ma971254g · Cited by 439

Effective ab Initio Emulsion Polymerization under RAFT Control

Ferguson, C. J., Hughes, R. J., Pham, B. T. T., Hawkett, B. S., Gilbert, R. G., Serelis, A. K., & Such, C. H. (2002) · Macromolecules · doi:10.1021/ma025626j · Cited by 437

Core cross-linked star polymers via controlled radical polymerisation

Blencowe, A., Tan, J. F., Goh, T. K., & Qiao, G. G. (2009) · Polymer · doi:10.1016/j.polymer.2008.09.049 · Cited by 433

Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk

HADJICHRISTIDIS, N., IATROU, H., PITSIKALIS, M., PISPAS, S., & AVGEROPOULOS, A. (2005) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2005.04.001 · Cited by 428

Complex coacervate core micelles

Voets, I. K., de Keizer, A., & Cohen Stuart, M. A. (2009) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2008.09.012 · Cited by 427

Thermodynamic vs Kinetic Aspects in the Formation and Morphological Transitions of Crew-Cut Aggregates Produced by Self-Assembly of Polystyrene-b-poly(acrylic acid) Block Copolymers in Dilute Solution

Zhang, L., & Eisenberg, A. (1999) · Macromolecules · doi:10.1021/ma981039f · Cited by 426

Block copolymer nanostructures

Smart, T., Lomas, H., Massignani, M., Flores-Merino, M. V., Perez, L. R., & Battaglia, G. (2008) · Nano Today · doi:10.1016/s1748-0132(08)70043-4 · Cited by 422

Supramolecular assemblies of block copolymers in aqueous media as nanocontainers relevant to biological applications

Harada, A., & Kataoka, K. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.09.004 · Cited by 411

Stimuli-responsive amphiphilic (co)polymers via RAFT polymerization

Smith, A. E., Xu, X., & McCormick, C. L. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.11.005 · Cited by 410

Morphogenic Effect of Added Ions on Crew-Cut Aggregates of Polystyrene-b-poly(acrylic acid) Block Copolymers in Solutions

Zhang, L., & Eisenberg, A. (1996) · Macromolecules · doi:10.1021/ma961376t · Cited by 404

Nitroxide-Mediated Radical Polymerization: Limitations and Versatility

Grubbs, R. B. (2011) · Polymer Reviews · doi:10.1080/15583724.2011.566405 · Cited by 398

Amphiphilic Janus Micelles with Polystyrene and Poly(methacrylic acid) Hemispheres

Erhardt, R., Zhang, M., Böker, A., Zettl, H., Abetz, C., Frederik, P., Krausch, G., Abetz, V., & Müller, A. H. E. (2003) · Journal of the American Chemical Society · doi:10.1021/ja028982q · Cited by 359

Synthesis of Acrylate and Methacrylate Block Copolymers Using Atom Transfer Radical Polymerization

Shipp, D. A., Wang, J.-L., & Matyjaszewski, K. (1998) · Macromolecules · doi:10.1021/ma981033q · Cited by 351

Advances in the synthesis of amphiphilic block copolymers via RAFT polymerization: Stimuli-responsive drug and gene delivery☆

YORK, A., KIRKLAND, S., & MCCORMICK, C. (2008) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2008.02.006 · Cited by 349

Control of Morphology through Polymer−Solvent Interactions in Crew-Cut Aggregates of Amphiphilic Block Copolymers

Yu, Y., & Eisenberg, A. (1997) · Journal of the American Chemical Society · doi:10.1021/ja9709740 · Cited by 348

Amphiphilic copolymers and their applications

Alexandridis, P. (1996) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(96)80118-x · Cited by 331

Natural surfactants

Holmberg, K. (2001) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(01)00074-7 · Cited by 331

Miktoarm star polymers: advances in synthesis, self-assembly, and applications

Khanna, K., Varshney, S., & Kakkar, A. (2010) · Polymer Chemistry · doi:10.1039/c0py00082e · Cited by 329

Relationship between pluronic block copolymer structure, critical micellization concentration and partitioning coefficients of low molecular mass solutes

Kozlov, M. Y., Melik-Nubarov, N. S., Batrakova, E. V., & Kabanov, A. V. (2000) · Macromolecules · doi:10.1021/ma991634x · Cited by 322

First Nitroxide-Mediated Controlled Free-Radical Polymerization of Acrylic Acid

Couvreur, L., Lefay, C., Belleney, J., Charleux, B., Guerret, O., & Magnet, S. (2003) · Macromolecules · doi:10.1021/ma035043p · Cited by 309

Polymeric Surfactants for the New Millennium: A pH-Responsive, Zwitterionic, Schizophrenic Diblock Copolymer

Liu, S., & Armes, S. P. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020415)41:8<1413::aid-anie1413>3.0.co;2-k · Cited by 309

Atom Transfer Polymerization of Methyl Methacrylate Mediated by Alkylpyridylmethanimine Type Ligands, Copper(I) Bromide, and Alkyl Halides in Hydrocarbon Solution

Haddleton, D. M., Crossman, M. C., Dana, B. H., Duncalf, D. J., Heming, A. M., Kukulj, D., & Shooter, A. J. (1999) · Macromolecules · doi:10.1021/ma981670g · Cited by 299

Atom Transfer Radical Polymerization of tert-Butyl Acrylate and Preparation of Block Copolymers

Davis, K. A., & Matyjaszewski, K. (2000) · Macromolecules · doi:10.1021/ma991826s · Cited by 297

Micellization of Ionic Block Copolymers

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Supramolecular self-assembly of amphiphilic hyperbranched polymers at all scales and dimensions: progress, characteristics and perspectives

Zhou, Y., & Yan, D. (2009) · Chemical Communications · doi:10.1039/b814560c · Cited by 287

Fluorescence Studies of Associating Polymers in Water: Determination of the Chain end Aggregation Number and a Model for the Association Process

Yekta, A., Xu, B., Duhamel, J., Adiwidjaja, H., & Winnik, M. A. (1995) · Macromolecules · doi:10.1021/ma00108a025 · Cited by 284

Multiple pH-Induced Morphological Changes in Aggregates of Polystyrene-block-poly(4-vinylpyridine) in DMF/H2O Mixtures

Shen, H., Zhang, L., & Eisenberg, A. (1999) · Journal of the American Chemical Society · doi:10.1021/ja983712m · Cited by 274

SOME PHYSICOCHEMICAL ASPECTS OF MICROEMULSION FLOODING: A REVIEW

Reed, R. L., & Healy, R. N. (1977) · Improved Oil Recovery by Surfactant and Polymer Flooding · doi:10.1016/b978-0-12-641750-0.50017-7 · Cited by 271

Associating behaviour of polyacrylamides hydrophobically modified with dihexylacrylamide

Volpert, E., Selb, J., & Candau, F. (1998) · Polymer · doi:10.1016/s0032-3861(97)00393-5 · Cited by 268

Rheology of associative polymer solutions

Chassenieux, C., Nicolai, T., & Benyahia, L. (2011) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2010.07.007 · Cited by 257

ATRP Synthesis of Amphiphilic Random, Gradient, and Block Copolymers of 2-(Dimethylamino)ethyl Methacrylate and n-Butyl Methacrylate in Aqueous Media

Lee, S. B., Russell, A. J., & Matyjaszewski, K. (2003) · Biomacromolecules · doi:10.1021/bm034126a · Cited by 254

A Giant Surfactant of Polystyrene−(Carboxylic Acid-Functionalized Polyhedral Oligomeric Silsesquioxane) Amphiphile with Highly Stretched Polystyrene Tails in Micellar Assemblies

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A brief review of ‘schizophrenic’ block copolymers

Bütün, V., Liu, S., Weaver, J. V. M., Bories-Azeau, X., Cai, Y., & Armes, S. P. (2006) · Reactive and Functional Polymers · doi:10.1016/j.reactfunctpolym.2005.07.021 · Cited by 248

Synthesis and Aqueous Solution Properties of Novel Sugar Methacrylate-Based Homopolymers and Block Copolymers

Narain, R., & Armes, S. P. (2003) · Biomacromolecules · doi:10.1021/bm034166e · Cited by 245

Ion-Sensitive “Isothermal” Responsive Polymers Prepared in Water

Magnusson, J. P., Khan, A., Pasparakis, G., Saeed, A. O., Wang, W., & Alexander, C. (2008) · Journal of the American Chemical Society · doi:10.1021/ja802609r · Cited by 242

A Schizophrenic Water-Soluble Diblock Copolymer

Liu, S., Billingham, N. C., & Armes, S. P. (2001) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20010618)40:12<2328::aid-anie2328>3.0.co;2-m · Cited by 241

Phase Separation Behavior and Crew-Cut Micelle Formation of Polystyrene-b-poly(acrylic acid) Copolymers in Solutions

Zhang, L., Shen, H., & Eisenberg, A. (1997) · Macromolecules · doi:10.1021/ma961413g · Cited by 240

Stimuli responsive amphiphilic block copolymers for aqueous media synthesised via reversible addition fragmentation chain transfer polymerisation (RAFT)

Mertoglu, M., Garnier, S., Laschewsky, A., Skrabania, K., & Storsberg, J. (2005) · Polymer · doi:10.1016/j.polymer.2005.03.101 · Cited by 239

A model of micellization for block copolymers in solutions

Gao, Z., & Eisenberg, A. (1993) · Macromolecules · doi:10.1021/ma00078a035 · Cited by 239

Multiple Morphologies of PAA-b-PSt Assemblies throughout RAFT Dispersion Polymerization of Styrene with PAA Macro-CTA

He, W.-D., Sun, X.-L., Wan, W.-M., & Pan, C.-Y. (2011) · Macromolecules · doi:10.1021/ma2000674 · Cited by 233

Block Copolymer "Crew-Cut" Micelles in Water

Gao, Z., Varshney, S. K., Wong, S., & Eisenberg, A. (1994) · Macromolecules · doi:10.1021/ma00104a058 · Cited by 233

The preparation of t‐butyl acrylate, methyl acrylate, and styrene block copolymers by atom transfer radical polymerization: Precursors to amphiphilic and hydrophilic block copolymers and conversion to complex nanostructured materials

Ma, Q., & Wooley, K. L. (2000) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/1099-0518(200012)38:1+<4805::aid-pola180>3.0.co;2-o · Cited by 227

Atom Transfer Radical Polymerization of 4-Vinylpyridine

Xia, J., Zhang, X., & Matyjaszewski, K. (1999) · Macromolecules · doi:10.1021/ma9816968 · Cited by 223

Unusual Aggregation Behavior of a Novel Tertiary Amine Methacrylate-Based Diblock Copolymer: Formation of Micelles and Reverse Micelles in Aqueous Solution

Bütün, V., Billingham, N. C., & Armes, S. P. (1998) · Journal of the American Chemical Society · doi:10.1021/ja982295a · Cited by 222

Self-assembled polyelectrolyte systems

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Polymer vesicles in various media

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Responsive hydrophobically associating polymers: a review of structure and properties

Tonge, S. R., & Tighe, B. J. (2001) · Advanced Drug Delivery Reviews · doi:10.1016/s0169-409x(01)00223-x · Cited by 213

Controlled/“Living” Radical Polymerization of 2-(Dimethylamino)ethyl Methacrylate

Zhang, X., Xia, J., & Matyjaszewski, K. (1998) · Macromolecules · doi:10.1021/ma980477j · Cited by 211

Synthesis of Block Copolymers

Hadjichristidis, N., Pitsikalis, M., & Iatrou, H. (2005) · Advances in Polymer Science · doi:10.1007/12_005 · Cited by 209

Micelles based on HPMA copolymers☆

Talelli, M., Rijcken, C. J. F., van Nostrum, C. F., Storm, G., & Hennink, W. E. (2010) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2009.11.029 · Cited by 208

Well-Defined Biocompatible Block Copolymers via Atom Transfer Radical Polymerization of 2-Methacryloyloxyethyl Phosphorylcholine in Protic Media

Ma, Y., Tang, Y., Billingham, N. C., Armes, S. P., Lewis, A. L., Lloyd, A. W., & Salvage, J. P. (2003) · Macromolecules · doi:10.1021/ma021762c · Cited by 207

Controlled Radical Polymerization of Acrylic Acid in Protic Media

Ladavière, C., Dörr, N., & Claverie, J. P. (2001) · Macromolecules · doi:10.1021/ma010358v · Cited by 202

RAFT-synthesized diblock and triblock copolymers: thermally-induced supramolecular assembly in aqueous media

McCormick, C. L., Sumerlin, B. S., Lokitz, B. S., & Stempka, J. E. (2008) · Soft Matter · doi:10.1039/b719577j · Cited by 201

Stimulus responsive core-shell nanoparticles: synthesis and applications of polymer based aqueous systems

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Synthesis of Well-Defined Amphiphilic Block Copolymers Having Phospholipid Polymer Sequences as a Novel Biocompatible Polymer Micelle Reagent

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Effect of Poly(acrylic acid) Block Length Distribution on Polystyrene-b-Poly(acrylic acid) Aggregates in Solution. 1. Vesicles

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Diblock, ABC triblock, and random methacrylic polyampholytes: synthesis by group transfer polymerization and solution behavior

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Amphipols: polymeric surfactants for membrane biology research

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Polymeric surfactants in disperse systems

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Facile Synthesis of Well-Defined, Biocompatible Phosphorylcholine-Based Methacrylate Copolymers via Atom Transfer Radical Polymerization at 20 °C

Lobb, E. J., Ma, I., Billingham, N. C., Armes, S. P., & Lewis, A. L. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003906d · Cited by 191

Interfacial behavior of block polyelectrolytes. 1. Evidence for novel surface micelle formation

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Block Copolymers in Emulsion and Dispersion Polymerization

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Aggregates Formed by Amphoteric Diblock Copolymers in Water

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Polystyrene-poly(methacrylic acid) block copolymer micelles

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“Schizophrenic” Self-Assembly of Block Copolymers Synthesized via Aqueous RAFT Polymerization: From Micelles to Vesicles†Paper number 143 in a series on Water-Soluble Polymers.

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