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Saturation Vapor Pressures and Transition Enthalpies of Low-Volatility Organic Molecules of Atmospheric Relevance: From Dicarboxylic Acids to Complex Mixtures
Open accessAbstract
Aerosol particles are important constituents of the atmosphere. They impact modern society through their effects on visibility, human health and global climate. Despite this great importance, they continue to represent a challenge to scientists due to their complexity.\nAtmospheric aerosols have both natural and anthropogenic sources and consist of both organic and inorganic molecules. Organic compounds constitute 20-90% of the atmospheric aerosol mass, depending on location. The term primary aerosol particle is used to describe particles that are emitted directly into the atmosphere as particles. These primary particles are transformed in the atmosphere through the continuous exchange between the gas and particle phases via evaporation and condensation. Of the organic fraction of particulate mass, much results from condensation of vapors that are produced by chemical reactions and is termed secondary organic aerosol (SOA). To predict the temporal and spatial distribution of aerosols, particularly SOA, it is necessary to understand the fundamental parameters that govern the distribution of organic compounds between the gas and particle phases. Key thermodynamic properties\ndescribing the gas-particle partitioning of organic compounds are the vapor pressures6 and the enthalpies of vaporization and sublimation.
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Metadata
- Authors
- Bilde, M., Barsanti, K., Booth, M., Cappa, C. D., Donahue, N. M., Emanuelsson, E. U., McFiggans, G., Krieger, U. K., Marcolli, C., Topping, D., Ziemann, P., Barley, M., Clegg, S., Dennis-Smither, B., Hallquist, M., Hallquist, Å. M., Khlystov, A., Kulmala, M., Mogensen, D., Percival, C. J., Pope, F., Reid, J. P., Ribeiro da Silva, M. A. V., Rosenoern, T., Salo, K., Soonsin, V. P., Yli-Juuti, T., Prisle, N. L., Pagels, J., Rarey, J., Zardini, A. A., & Riipinen, I.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-05-01
- Volume
- 115
- Issue
- 10
- Pages
- 4115-4156
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W1988320097
- Cited by
- 265
- References
- 122
- FWCI
- 1.61
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
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Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.