The DOI matches its Crossref record.
Decomposition of ozone in water in the presence of organic solutes acting as promoters and inhibitors of radical chain reactions
Abstract
The decomposition of aqueous ozone is generally due to a chain reaction involving ·OH radicals. Many organic solutes (impurities) can react with ·OH to yield ·O2- upon addition of O2. ·O2-transfers its electron to a further ozone molecule in a rather selective reaction. The ozonide anion (·O3-) formed immediately decomposes into a further ·OH radical. Compounds that convert ·OH radicals into ozone-selective ·O2-, therefore, act as promoters of the chain reaction. The efficiencies of different ·OH to ·O2- converters (e.g., formic acid, primary and secondary alcohols (including sugars), glyoxylic acid, and humic acids) are tested in the presence of other ·OH radical scavengers that do not primarily produce ·O2- (carbonate, aliphatic alkyl compounds, and tert-butyl alcohol). The derived reaction kinetics allows one to qualitatively interpret the variation of the lifetime of O3 found in model solutions and even in natural waters and during drinking water treatment.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Advanced Oxidation Processes for Wastewater Treatment: Formation of Hydroxyl Radical and Application
WANG, J. L., & XU, L. J. (2012) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643389.2010.507698 · Cited by 1,586
Microbiological Aspects of Ozone Applications in Food: A Review
Khadre, M. A., Yousef, A. E., & Kim, J. ‐. (2001) · Journal of Food Science · doi:10.1111/j.1365-2621.2001.tb15196.x · Cited by 837
Fate of antibiotics during municipal water recycling treatment processes
Le-Minh, N., Khan, S. J., Drewes, J. E., & Stuetz, R. M. (2010) · Water Research · doi:10.1016/j.watres.2010.06.020 · Cited by 778
A review of imperative technologies for wastewater treatment II: hybrid methods
Gogate, P. R., & Pandit, A. B. (2004) · Advances in Environmental Research · doi:10.1016/s1093-0191(03)00031-5 · Cited by 769
Chemistry of Ozone in Water and Wastewater Treatment: From Basic Principles to Applications
von Sonntag, C., & von Gunten, U. (2012) · IWA Publishing eBooks · doi:10.2166/9781780400839 · Cited by 768
Hydroxyl Radical/Ozone Ratios During Ozonation Processes. I. The RctConcept
Elovitz, M. S., & von Gunten, U. (1999) · Ozone: Science & Engineering · doi:10.1080/01919519908547239 · Cited by 744
von Gunten, U., & Hoigne, J. (1994) · Environmental Science & Technology · doi:10.1021/es00056a009 · Cited by 586
Self-citationOxidative treatment of pharmaceuticals in water
Zwiener, C. (2000) · Water Research · doi:10.1016/s0043-1354(99)00338-3 · Cited by 517
Westerhoff, P., Aiken, G., Amy, G., & Debroux, J. (1999) · Water Research · doi:10.1016/s0043-1354(98)00447-3 · Cited by 469
Pesticide chemical oxidation: state-of-the-art
Chiron, S. (2000) · Water Research · doi:10.1016/s0043-1354(99)00173-6 · Cited by 465
Application of ozonation for pharmaceuticals and personal care products removal from water
Gomes, J., Costa, R., Quinta-Ferreira, R. M., & Martins, R. C. (2017) · Science of The Total Environment · doi:10.1016/j.scitotenv.2017.01.216 · Cited by 429
Hoigné, J. (1998) · The Handbook of Environmental Chemistry · doi:10.1007/978-3-540-68089-5_5 · Cited by 388
Fenton chemistry at aqueous interfaces
Enami, S., Sakamoto, Y., & Colussi, A. J. (2014) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1314885111 · Cited by 349
Rate constants for direct reactions of ozone with several drinking water contaminants
David Yao, C. C., & Haag, W. R. (1991) · Water Research · doi:10.1016/0043-1354(91)90155-j · Cited by 338
Goldstone, J. V., Pullin, M. J., Bertilsson, S., & Voelker, B. M. (2002) · Environmental Science & Technology · doi:10.1021/es0109646 · Cited by 318
Hydroxyl radicals in anodic oxidation systems: generation, identification and quantification
Xie, J., Zhang, C., & Waite, T. D. (2022) · Water Research · doi:10.1016/j.watres.2022.118425 · Cited by 303
Wende, K., Williams, P., Dalluge, J., Van Gaens, W., Aboubakr, H., Bischof, J., von Woedtke, T., Goyal, S. M., Weltmann, K.-D., Bogaerts, A., et al. (2015) · Biointerphases · doi:10.1116/1.4919710 · Cited by 279
Ozonolysis: An advantageous pretreatment for lignocellulosic biomass revisited
Travaini, R., Martín-Juárez, J., Lorenzo-Hernando, A., & Bolado-Rodríguez, S. (2016) · Bioresource Technology · doi:10.1016/j.biortech.2015.08.143 · Cited by 277
Activated Carbon and Carbon Black Catalyzed Transformation of Aqueous Ozone into OH-Radicals
Jans, U., & Hoigné, J. (1998) · Ozone: Science & Engineering · doi:10.1080/01919519808547291 · Cited by 276
Decolorization and detoxification of textile wastewater by ozonation and coagulation processes
Selcuk, H. (2005) · Dyes and Pigments · doi:10.1016/j.dyepig.2004.03.020 · Cited by 273
Iron type catalysts for the ozonation of oxalic acid in water
Beltrán, F. J., Rivas, F. J., & Montero-de-Espinosa, R. (2005) · Water Research · doi:10.1016/j.watres.2005.06.018 · Cited by 273
Sevimli, M. F., & Sarikaya, H. Z. (2002) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.644 · Cited by 195
Ozone-induced changes of antioxidant capacity of fresh-cut tropical fruits
Alothman, M., Kaur, B., Fazilah, A., Bhat, R., & Karim, A. A. (2010) · Innovative Food Science & Emerging Technologies · doi:10.1016/j.ifset.2010.08.008 · Cited by 194
Destruction of humic acid in water by UV lightâcatalyzed oxidation with hydrogen peroxide
Wang, G. (2000) · Water Research · doi:10.1016/s0043-1354(00)00120-2 · Cited by 159
Treatment of Textile Wastewater Using Advanced Oxidation Processes—A Critical Review
Zhang, Y., Shaad, K., Vollmer, D., & Ma, C. (2021) · Water · doi:10.3390/w13243515 · Cited by 147
Lu, X., Zhao, J., Wang, Q., Wang, D., Xu, H., Ma, J., Qiu, W., & Hu, T. (2019) · Water Research · doi:10.1016/j.watres.2019.114969 · Cited by 85
Satyro, S., Race, M., Marotta, R., Dezotti, M., Spasiano, D., Mancini, G., & Fabbricino, M. (2014) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2014.08.017 · Cited by 39
Metadata
- Authors
- Staehelin, J., & Hoigne, J.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 1985-12
- Volume
- 19
- Issue
- 12
- Pages
- 1206-1213
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W1989598523
- Cited by
- 1,192
- References
- 0
- FWCI
- 21.14
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
