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Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn2+ Coordination Sites
Abstract
Use of the tritopic bridging ligand 1,3,5-benzenetristetrazolate (BTT3-) enables formation of [Mn(DMF)6]3[(Mn4Cl)3(BTT)8(H2O)12]2.42DMF.11H2O.20CH3OH, featuring a porous metal-organic framework with a previously unknown cubic topology. Crystals of the compound remain intact upon desolvation and show a total H2 uptake of 6.9 wt % at 77 K and 90 bar, which at 60 g H2/L provides a storage density 85% of that of liquid hydrogen. The material exhibits a maximum isosteric heat of adsorption of 10.1 kJ/mol, the highest yet observed for a metal-organic framework. Neutron powder diffraction data demonstrate that this is directly related to H2 binding at coordinatively unsaturated Mn2+ centers within the framework.
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Metadata
- Authors
- Dincǎ, M., Dailly, A., Liu, Y., Brown, C. M., Neumann, D. A., & Long, J. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-12-01
- Volume
- 128
- Issue
- 51
- Pages
- 16876-16883
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2106259156
- Cited by
- 1,137
- References
- 0
- FWCI
- 61.22
- Type
- journal article
- Language
- en
- Open access
- closed
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