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Phosphorus-Doped Ordered Mesoporous Carbons with Different Lengths as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction in Alkaline Media
Abstract
Phosphorus-doped ordered mesoporous carbons (POMCs) with different lengths were synthesized using a metal-free nanocasting method of SBA-15 mesoporous silica with different sizes as template and triphenylphosphine and phenol as phosphorus and carbon sources, respectively. The resultant POMC with a small amount of P doping is demonstrated as a metal-free electrode with excellent electrocatalytic activity for oxygen reduction reaction (ORR), coupled with much enhanced stability and alcohol tolerance compared to those of platinum via four-electron pathway in alkaline medium. Interestingly, the POMC with short channel length is found to have superior electrochemical performances compared to those with longer sizes.
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Metadata
- Authors
- Yang, D.-S., Bhattacharjya, D., Inamdar, S., Park, J., & Yu, J.-S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-09-19
- Volume
- 134
- Issue
- 39
- Pages
- 16127-16130
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2012176181
- Cited by
- 927
- References
- 33
- FWCI
- 28.18
- Type
- journal article
- Language
- en
- Open access
- closed
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